Advanced Search

Citation: ZHANG Wei, TAO Hong-Xiu, WANG Qiu-Shi, ZHANG Li-Na, WANG Gui-Qiang. Preparation of Hollow Cu2ZnSnS4 Spheres via Solvothermal Method[J]. Chinese Journal of Inorganic Chemistry, ;2015, (12): 2411-2417. doi: 10.11862/CJIC.2015.288 shu

Preparation of Hollow Cu2ZnSnS4 Spheres via Solvothermal Method

  • 1.

    College of New Energy, Bohai University, Jinzhou, Liaoning 121013, China

  • Corresponding author: WANG Gui-Qiang, 
  • Received Date: 15 July 2015
    Available Online: 14 September 2015

    Fund Project: 国家自然科学基金(No.61474009,11504028) (No.61474009,11504028)辽宁省教育厅科学技术研究项目(No.L2014448)资助。 (No.L2014448)

  • Hollow Cu2ZnSnS4 spheres were synthesized by a poly(ethylene glycol) (PEG) assisted solvothermal route, employing copper chloride, zinc nitrate, stannous chloride, and thiourea as precursors. The polyethylene glycol (PEG) acting as the template coordination agent plays an important role in the formation of the final product. The formation mechanism of the hollow Cu2ZnSnS4 spheres was also discussed. The microstructure and optical properties of the hollow spheres were characterized by X-ray diffraction (XRD), Raman spectrometer, field-emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), energy dispersive X-ray (EDX), X-ray photoelectron spectroscopy (XPS), selected area electron diffraction spectroscopy (SAED), and UV-Vis absorption spectroscopy. The results reveal that the hollow Cu2ZnSnS4 spheres are crystallized in the tetragonal structure with about 600 nm in size. The optical absorption data show band-gap energy (Eg) of 1.52 eV which is optimal for photovoltaic applications.
  • 加载中
    1. [1]

      [1] Wadia C, Alivisatos A P, Kammen D M. Environ. Sci. Technol., 2009,43:2072-2077

    2. [2]

      [2] Fernandes P A, Salome P M P, Cunha A F. J. Alloys Compd., 2011,509:7600-7606

    3. [3]

      [3] Guo Q, Ford G M, Yang W C, et al. J. Am. Chem. Soc., 2010,132:17384-17386

    4. [4]

      [4] Moholkar A V, Shinde S S, Babar A R, et al. J. Alloys Compd., 2011,509:7439-7446

    5. [5]

      [5] Chan C P, Lam H, Surya C. Sol. Energy Mater. Sol. Cells, 2010,94:207-211

    6. [6]

      [6] Fischereder A, Rath T, Haas W, et al. Chem. Mater., 2010,22:3399-3406

    7. [7]

      [7] WANG Xin-Chun(王信春), WANG Guang-Jun(王广君), PANG Shan(庞山), et al. Chinese J. Inorg. Chem. (无机化 学学报), 2011,27(12):2437-2442

    8. [8]

      [8] Repinsl I, Contreras M A, Egaas B, et al. Prog. Photovolt.: Res. Appl., 2008,16:235-239

    9. [9]

      [9] DUAN Xue-Chen(段学臣), JIANG Bo(蒋波), CHENG Ya- Juan(程亚娟), et al. Chinese J. Inorg. Chem. (无机化学学 报), 2011,27(2):293-297

    10. [10]

      [10] Scragg J J, Dale P J, Peter L M, et al. Phys. Stat. Sol. (B), 2008,245:1772-1778

    11. [11]

      [11] Zhang W, Zhang L N, Lu X D, et al. Chin. Auto. Congr., 2013 Chinese Automation Congress. Changsha:IEEE, 2013: 795-800

    12. [12]

      [12] Liu F Y, Zhang K, Wang B, et al. Sol. Energy Mater. Sol. Cells, 2010,94:2431-2434

    13. [13]

      [13] Oishi K, Saito G, Ebina K, et al. Thin Solid Films, 2008,517:1449-1452

    14. [14]

      [14] Pawar S M, Pawar B S, Moholkar A V, et al. Electrochim. Acta, 2010,55:4057-4061

    15. [15]

      [15] Kamoun N, Bouzouita H, Rezig B. Thin Solid Films, 2007,515:5949-5952

    16. [16]

      [16] Hillhouse H W, Beard M C. Colloid Interface Sci., 2009,14: 245-259

    17. [17]

      [17] Wu C H, Chen F, Lin S H, et al. J. Alloys Compd., 2011, 509:5783-5788

    18. [18]

      [18] Shi L, Pei C J, Xu Y M, et al. J. Am. Chem. Soc., 2011, 133:10328-10331

    19. [19]

      [19] ZHOU Chao(周超), ANG Dan(王丹), GAO Yan-Min (高延敏), Chinese J. Inorg. Chem. (无机化学学报), 2013, 29(11):2382-2386

    20. [20]

      [20] Shavel A, Arbiol J, Cabot A. J. Am. Chem. Soc., 2010,132: 4514-4515

    21. [21]

      [21] Zou C, Zhang L J, Lin D S, et al. Cryst. Eng. Comn., 2011,13:3310-3313

    22. [22]

      [22] Steinhagen C, Panthani M G, Akhavan V, et al. J. Am. Chem. Soc., 2009,131:12554-12555

    23. [23]

      [23] Chen H Y, Yu S M, Shin D W, et al. Nanoscale Res. Lett., 2010,5:217-223

    24. [24]

      [24] Wang Y, Gong H. J. Alloys Compd., 2011,509:9627-9630

    25. [25]

      [25] ZENG Xiao-Wei(曾小巍), ZHANG Yu-Hong(张玉红), LUO Cheng-cai(骆成才), et al. Chinese J. Inorg. Chem. (无机化 学学报), 2005,21(10):1515-1519

    26. [26]

      [26] Song X F, Gao L. J. Phys. Chem. C, 2008,112:15229-15305

    27. [27]

      [27] Yang X F, Fu J X, Jin C J, et al. J. Am. Chem. Soc., 2010,132:14279-14287

  • 加载中
    1. [1]

      Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO2 reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037

    2. [2]

      Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO2-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067

    3. [3]

      Xiutao Xu ,  Chunfeng Shao ,  Jinfeng Zhang ,  Zhongliao Wang ,  Kai Dai . Rational Design of S-Scheme CeO2/Bi2MoO6 Microsphere Heterojunction for Efficient Photocatalytic CO2 Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031

    4. [4]

      Zhen Shi ,  Wei Jin ,  Yuhang Sun ,  Xu Li ,  Liang Mao ,  Xiaoyan Cai ,  Zaizhu Lou . Interface charge separation in Cu2CoSnS4/ZnIn2S4 heterojunction for boosting photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2023, 42(12): 100201-100201. doi: 10.1016/j.cjsc.2023.100201

    5. [5]

      Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293

    6. [6]

      Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au11(dppf)4Cl2 nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047

    7. [7]

      Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312

    8. [8]

      Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO2 reduction performance of Z-scheme Ag-Cu2O/BiVO4 photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434

    9. [9]

      Qiuyang LUO , Xiaoning TANG , Shu XIA , Junnan LIU , Xingfu YANG , Jie LEI . Application of a densely hydrophobic copper metal layer in-situ prepared with organic solvents for protecting zinc anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1243-1253. doi: 10.11862/CJIC.20240110

    10. [10]

      Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922

    11. [11]

      Ping Wang ,  Tianbao Zhang ,  Zhenxing Li . Reconstruction mechanism of Cu surface in CO2 reduction process. Chinese Journal of Structural Chemistry, 2024, 43(8): 100328-100328. doi: 10.1016/j.cjsc.2024.100328

    12. [12]

      Wenhao Chen , Muxuan Wu , Han Chen , Lue Mo , Yirong Zhu . Cu2Se@C thin film with three-dimensional braided structure as a cathode material for enhanced Cu2+ storage. Chinese Chemical Letters, 2024, 35(5): 108698-. doi: 10.1016/j.cclet.2023.108698

    13. [13]

      Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu2O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001

    14. [14]

      Yufei Jia ,  Fei Li ,  Ke Fan . Surface reconstruction of Cu-based bimetallic catalysts for electrochemical CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100255-100255. doi: 10.1016/j.cjsc.2024.100255

    15. [15]

      Xingmin Chen , Yunyun Wu , Yao Tang , Peishen Li , Shuai Gao , Qiang Wang , Wen Liu , Sihui Zhan . Construction of Z-scheme Cu-CeO2/BiOBr heterojunction for enhanced photocatalytic degradation of sulfathiazole. Chinese Chemical Letters, 2024, 35(7): 109245-. doi: 10.1016/j.cclet.2023.109245

    16. [16]

      Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu2+. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150

    17. [17]

      Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu2O/Bi2MoO6 Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435

    18. [18]

      Kaihui Huang ,  Boning Feng ,  Xinghua Wen ,  Lei Hao ,  Difa Xu ,  Guijie Liang ,  Rongchen Shen ,  Xin Li . Effective photocatalytic hydrogen evolution by Ti3C2-modified CdS synergized with N-doped C-coated Cu2O in S-scheme heterojunctions. Chinese Journal of Structural Chemistry, 2023, 42(12): 100204-100204. doi: 10.1016/j.cjsc.2023.100204

    19. [19]

      Ying Li , Long-Jie Wang , Yong-Kang Zhou , Jun Liang , Bin Xiao , Ji-Shen Zheng . An improved installation of 2-hydroxy-4-methoxybenzyl (iHmb) method for chemical protein synthesis. Chinese Chemical Letters, 2024, 35(5): 109033-. doi: 10.1016/j.cclet.2023.109033

    20. [20]

      Zhixiang Li , Zhirong Yang , Chang Yao , Bin Wu , Gang Qian , Xuezhi Duan , Xinggui Zhou , Jing Zhang . Efficient continuous synthesis of 2-hydroxycarbazole and 4-hydroxycarbazole in a millimeter scale photoreactor. Chinese Chemical Letters, 2024, 35(4): 108893-. doi: 10.1016/j.cclet.2023.108893

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(170)
  • HTML views(27)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return