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Citation: ZHANG Wei, TAO Hong-Xiu, WANG Qiu-Shi, ZHANG Li-Na, WANG Gui-Qiang. Preparation of Hollow Cu2ZnSnS4 Spheres via Solvothermal Method[J]. Chinese Journal of Inorganic Chemistry, ;2015, (12): 2411-2417. doi: 10.11862/CJIC.2015.288 shu

Preparation of Hollow Cu2ZnSnS4 Spheres via Solvothermal Method

  • 1.

    College of New Energy, Bohai University, Jinzhou, Liaoning 121013, China

  • Corresponding author: WANG Gui-Qiang, 
  • Received Date: 15 July 2015
    Available Online: 14 September 2015

    Fund Project: 国家自然科学基金(No.61474009,11504028) (No.61474009,11504028)辽宁省教育厅科学技术研究项目(No.L2014448)资助。 (No.L2014448)

  • Hollow Cu2ZnSnS4 spheres were synthesized by a poly(ethylene glycol) (PEG) assisted solvothermal route, employing copper chloride, zinc nitrate, stannous chloride, and thiourea as precursors. The polyethylene glycol (PEG) acting as the template coordination agent plays an important role in the formation of the final product. The formation mechanism of the hollow Cu2ZnSnS4 spheres was also discussed. The microstructure and optical properties of the hollow spheres were characterized by X-ray diffraction (XRD), Raman spectrometer, field-emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), energy dispersive X-ray (EDX), X-ray photoelectron spectroscopy (XPS), selected area electron diffraction spectroscopy (SAED), and UV-Vis absorption spectroscopy. The results reveal that the hollow Cu2ZnSnS4 spheres are crystallized in the tetragonal structure with about 600 nm in size. The optical absorption data show band-gap energy (Eg) of 1.52 eV which is optimal for photovoltaic applications.
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    1. [1]

      [1] Wadia C, Alivisatos A P, Kammen D M. Environ. Sci. Technol., 2009,43:2072-2077

    2. [2]

      [2] Fernandes P A, Salome P M P, Cunha A F. J. Alloys Compd., 2011,509:7600-7606

    3. [3]

      [3] Guo Q, Ford G M, Yang W C, et al. J. Am. Chem. Soc., 2010,132:17384-17386

    4. [4]

      [4] Moholkar A V, Shinde S S, Babar A R, et al. J. Alloys Compd., 2011,509:7439-7446

    5. [5]

      [5] Chan C P, Lam H, Surya C. Sol. Energy Mater. Sol. Cells, 2010,94:207-211

    6. [6]

      [6] Fischereder A, Rath T, Haas W, et al. Chem. Mater., 2010,22:3399-3406

    7. [7]

      [7] WANG Xin-Chun(王信春), WANG Guang-Jun(王广君), PANG Shan(庞山), et al. Chinese J. Inorg. Chem. (无机化 学学报), 2011,27(12):2437-2442

    8. [8]

      [8] Repinsl I, Contreras M A, Egaas B, et al. Prog. Photovolt.: Res. Appl., 2008,16:235-239

    9. [9]

      [9] DUAN Xue-Chen(段学臣), JIANG Bo(蒋波), CHENG Ya- Juan(程亚娟), et al. Chinese J. Inorg. Chem. (无机化学学 报), 2011,27(2):293-297

    10. [10]

      [10] Scragg J J, Dale P J, Peter L M, et al. Phys. Stat. Sol. (B), 2008,245:1772-1778

    11. [11]

      [11] Zhang W, Zhang L N, Lu X D, et al. Chin. Auto. Congr., 2013 Chinese Automation Congress. Changsha:IEEE, 2013: 795-800

    12. [12]

      [12] Liu F Y, Zhang K, Wang B, et al. Sol. Energy Mater. Sol. Cells, 2010,94:2431-2434

    13. [13]

      [13] Oishi K, Saito G, Ebina K, et al. Thin Solid Films, 2008,517:1449-1452

    14. [14]

      [14] Pawar S M, Pawar B S, Moholkar A V, et al. Electrochim. Acta, 2010,55:4057-4061

    15. [15]

      [15] Kamoun N, Bouzouita H, Rezig B. Thin Solid Films, 2007,515:5949-5952

    16. [16]

      [16] Hillhouse H W, Beard M C. Colloid Interface Sci., 2009,14: 245-259

    17. [17]

      [17] Wu C H, Chen F, Lin S H, et al. J. Alloys Compd., 2011, 509:5783-5788

    18. [18]

      [18] Shi L, Pei C J, Xu Y M, et al. J. Am. Chem. Soc., 2011, 133:10328-10331

    19. [19]

      [19] ZHOU Chao(周超), ANG Dan(王丹), GAO Yan-Min (高延敏), Chinese J. Inorg. Chem. (无机化学学报), 2013, 29(11):2382-2386

    20. [20]

      [20] Shavel A, Arbiol J, Cabot A. J. Am. Chem. Soc., 2010,132: 4514-4515

    21. [21]

      [21] Zou C, Zhang L J, Lin D S, et al. Cryst. Eng. Comn., 2011,13:3310-3313

    22. [22]

      [22] Steinhagen C, Panthani M G, Akhavan V, et al. J. Am. Chem. Soc., 2009,131:12554-12555

    23. [23]

      [23] Chen H Y, Yu S M, Shin D W, et al. Nanoscale Res. Lett., 2010,5:217-223

    24. [24]

      [24] Wang Y, Gong H. J. Alloys Compd., 2011,509:9627-9630

    25. [25]

      [25] ZENG Xiao-Wei(曾小巍), ZHANG Yu-Hong(张玉红), LUO Cheng-cai(骆成才), et al. Chinese J. Inorg. Chem. (无机化 学学报), 2005,21(10):1515-1519

    26. [26]

      [26] Song X F, Gao L. J. Phys. Chem. C, 2008,112:15229-15305

    27. [27]

      [27] Yang X F, Fu J X, Jin C J, et al. J. Am. Chem. Soc., 2010,132:14279-14287

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