Citation: WANG Zhao-Dong. Syntheses and Structural Characterization of Copper Complexes with Thioether-Containing Pyridylalkylamide Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2243-2248. doi: 10.11862/CJIC.2015.283
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Thioether-containing pyridylalkylamide ligands 2-(methylsulfanyl)-N-[2-(pyridine-2-yl)methyl]acetamide (HL1) and 2-(methylsulfanyl)-N-[2-(pyridine-2-yl)ethyl]acetamide (HL2) were synthesized and fully characterized. Three copper complexes {[Cu(L1)(CH3OH)](OTf)}n (1), (OTf=triflate), {[Cu(L2)(OTf)]·CH3OH}n (2) and [Cu(HL2)(CH3OH)Cl] (3) were synthesized and characterized with X-ray diffraction methods. The single-crystal X-ray analyses indicate that complex 1 and 2 form 1Dcoordination polymers, while complex 3 is a mononuclear copper complex. The coordination modes of the copper ion are analyzed and the reasons are interpreted.
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