Citation: ZHANG Su-Wei, ZHANG Bo-Ping, LI Shun, ZHU Li-Feng, ZHANG Yu-Qiao. Theoretical Study of the Optical Properties of Noble Metal Nano-Particles Dispersed Composite Films[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2135-2142. doi: 10.11862/CJIC.2015.280 shu

Theoretical Study of the Optical Properties of Noble Metal Nano-Particles Dispersed Composite Films

1.
School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China

Corresponding author: ZHANG Bo-Ping,
Received Date: 3 April 2015
Available Online: 6 September 2015
Fund Project: 国家自然科学基金(No.51472026,51272023) (No.51472026,51272023)高等学校博士学科点专项科研基金(No.20130006110006)资助项目。 (No.20130006110006)

The optical absorption spectra of the nano-composite films dispersed by Ag, Au and Cu nano-particles were simulated by the classical Mie theory. It was found that the optical absorption spectra exhibit surface plasmon resonance (SPR) absorption peaks in visible region. The positions and intensities of the SPR absorption peaks are strongly affected by the real part (ε_m1) and imaginary part (ε_m2) of dielectric constant of metal and refractive index (n_s) of dielectric. The SPRabsorption position in visible region of the composite film is strongly dependent on n_s rather than ε_m1 and ε_m2. The simulated optical absorption spectra of the composite films dispersed by Ag, Au and Cu by Mie theory in this study are in good agreement with the reported experiment results, especially showing a close SPR peak positions to each other.
- Mie theory;nano-composite film;surface plasmon resonance;refractive index
1. [1]
  [1] ZHAO Cui-Hua(赵翠华), ZHANG Bo-Ping(张波萍), CHEN Can(陈灿), et al. Rare Metal Mater. Eng.(稀有金属材料与工程), 2009,38(2):647-649
2. [2]
  [2] Wang W T, Yang G, Chen Z H, et al. J. Appl. Phys., 2002, 92(12):7242-7245
3. [3]
  [3] YAN Li-Ping(严丽平), ZHANG Bo-Ping(张波萍), WANG Shi-Jing(王士京), et al. Acta Metall. Sin.(金属学报), 2011, 47(2):203-208
4. [4]
  [4] Zhao C H, Zhang B P, Shang P P. Chin. Phys. B, 2009,18 (12):5539-5543
5. [5]
  [5] Yang P F, Cu Y, Gong Q H. Chin. Phys. B, 2008,17(10): 3880-3893
6. [6]
  [6] Gangopadhyay P, Kesavamoorthy R, Nair K G M, et al. J. Appl. Phys., 2000,88(9):4975-4979
7. [7]
  [7] Okumu J, Dahmen C, Sprafke A N, et al. J. Appl. Phys., 2005,97:094305(6 pages)
8. [8]
  [8] Celep G, Cottancin E, Lermé J, et al. Phys. Rev. B, 2004,70: 165409(10 pages)
9. [9]
  [9] Yu B L, Zhu C S, Gan F X. J. Appl. Phys., 1997,82(9):4532-4537
10. [10]
  [10] Zhou P, You G J, Li YG, et al. Appl. Phys. Lett., 2003,83 (19):3876-3878
11. [11]
  [11] Wang S J, Zhang B P. Appl. Catal. A-Gen., 2013,463:585- 592
12. [12]
  [12] Wang S J, Zhang B P, Zhao C H, et al. Appl. Surf. Sci., 2011,257:3358-3362
13. [13]
  [13] Li Y, Zhang B P, Zhao J X. J. Alloys Compd., 2014,586(15): 663-668
14. [14]
  [14] YAN Li-Ping(严丽平), ZHANG Bo-Ping(张波萍), ZHAO Cui-Hua(赵翠华), et al. Chinese J. Inorg. Chem.(无机化学学报), 2011,27(6):1105-1110
15. [15]
  [15] Kreibig U, Vollmer M. Optical Properties of Metal Clusters. Berlin: Springer, 1995:30
16. [16]
  [16] Feldheim D L. Absorption and Scattering of Light by Small Particles. New York: John Wiley & Sons Inc, 1983:130
17. [17]
  [17] Maxwell Garnett J C. Philos. Trans. R. Soc. London. Ser. A, 1904,203:385-420
18. [18]
  [18] JIANG Chang-Zhong(蒋昌忠), SONG Liang(宋亮), REN Feng(任峰), et al. J. Wuhan Univ. Technol.(武汉大学学报), 2004,50(1):043-046
19. [19]
  [19] Johnson P B, Christy R W. Phys. Rev. B, 1972,6(12):4370- 4379
20. [20]
  [20] Tanahashi I, Manabe Y, Tohda T. J. App. Phys., 1996,79(3): 1244-1249
21. [21]
  [21] Babapour A, Akhavan O, Moshfegh A Z, et al. Thin Solid Films, 2006,515:771-774
22. [22]
  [22] Liao H B, Wen W J, Wong G K L. J. Appl. Phys., 2003,93 (8):4485-4488
23. [23]
  [23] Palik E D. Handbook of Optical Constants of Solids. San Diego: Academic Press, 1985:735
24. [24]
  [24] Yang Y, Shi J L, Huang W M, et al. Mater. Lett., 2002,56: 1048-1052
25. [25]
  [25] Bredas J L, Adant C, Tackx P, et al. Chem. Rev., 1994,94: 243-278
26. [26]
  [26] Powell R J, Spicer W E. Phys. Rev. B, 1970,2(6):2182-2193
27. [27]
  [27] Li Y, Zhang B P, Zhao C H, et al. J. Mater. Res., 2012,27 (24):3141-3146
28. [28]
  [28] Zhao C H, Zhang B P, Wang S J, et al. Mater. Des., 2011, 32:947-950
29. [29]
  [29] Zhao C H, Zhang B P, Wang S J, et al. Int. J. Min. Met. Mater., 2011,18(1):115-120
30. [30]
  [30] Epifani M, Giannini C, Tapfer L, et al. J. Am. Ceram. Soc., 2000,83(10):2385-2393
31. [31]
  [31] Qian Y, Ila D, Zimmerman R L, et al. Nucl. Instrum. Methods B, 1997,127(128):524-527
32. [32]
  [32] Ko Y H, Yu J S. Phys. Status Solidi A, 2011,208(12):2778-2782
33. [33]
  [33] Liu J W, Sun Y, Li Z H. CrystEngComm, 2012,14:1473-1478
34. [34]
  [34] Yang G, Wang W T, Zhou Y L, et al. Appl. Phys. Lett., 2002,81(21):3969-3971
35. [35]
  [35] Li J T, Cushing S K, Bright J, et al. ACS Catal., 2013,3:47- 51
36. [36]
  [36] ZHANG Yun(张芸), ZHANG Bo-Ping(张波萍), JIAO Li-Shi (焦力实), et al. Acta Phys. Sin.(物理学报), 2006,55(7):3737-3735
37. [37]
  [37] Ueda A, Mu R, Tung Y S, et al. Nucl. Instrum. Methods B, 1998,141:261-267
38. [38]
  [38] Zimmerman R L, Ila D, Williams E K. Nucl. Instrum. Methods B, 1998,141:308-311
39. [39]
  [39] WANG Wei-Tian(王伟田), YANG Guang(杨光), CHEN Zheng-Hao(陈正豪), et al. Chin. Phys.(中国物理学), 2002, 11(12):1324-1327
40. [40]
  [40] Zhang L, Blom D A, Wang H. Chem. Mater., 2011,23:4587- 4598
41. [41]
  [41] Fu M, Li Y L, Wu S W, et al. Appl. Surf. Sci., 2011,258: 1587-1591
42. [42]
  [42] Guo M L, Du J L. Physica B, 2012,407:1003-1007
1. [1]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
2. [2]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
3. [3]
  Yingran Liang , Fei Wang , Jiabao Sun , Hongtao Zheng , Zhenli Zhu . Construction and Application of a New Experimental Device for Determination of Alkaline Metal Elements by Plasma Atomic Emission Spectrometry Based on Solution Cathode Glow Discharge: An Alternative Approach for Fundamental Teaching Experiments in Emission Spectroscopy. University Chemistry, 2024, 39(5): 380-387. doi: 10.3866/PKU.DXHX202312024
4. [4]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
5. [5]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
6. [6]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
7. [7]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
8. [8]
  Jie Ren , Hao Zong , Yaqun Han , Tianyi Liu , Shufen Zhang , Qiang Xu , Suli Wu . Visual identification of silver ornament by the structural color based on Mie scattering of ZnO spheres. Chinese Chemical Letters, 2024, 35(9): 109350-. doi: 10.1016/j.cclet.2023.109350
9. [9]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
10. [10]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
11. [11]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
12. [12]
  Hua Hou , Baoshan Wang . Course Ideology and Politics Education in Theoretical and Computational Chemistry. University Chemistry, 2024, 39(2): 307-313. doi: 10.3866/PKU.DXHX202309045
13. [13]
  Jia Yao , Xiaogang Peng . Theory of Macroscopic Molecular Systems: Theoretical Framework of the Physical Chemistry Course in the Chemistry “101 Plan”. University Chemistry, 2024, 39(10): 27-37. doi: 10.12461/PKU.DXHX202408117
14. [14]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
15. [15]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
16. [16]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
17. [17]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
18. [18]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
19. [19]
  Keweiyang Zhang , Zihan Fan , Liyuan Xiao , Haitao Long , Jing Jing . Unveiling Crystal Field Theory: Preparation, Characterization, and Performance Assessment of Nickel Macrocyclic Complexes. University Chemistry, 2024, 39(5): 163-171. doi: 10.3866/PKU.DXHX202310084
20. [20]
  Qiang Xu , Rong Zhang , Liyan Zhang , Jinxuan Liu , Shuo Wu , Rongwen Lv . Exploration and Practice of Ideological and Political Education Construction in the Course of Practical Instrument Analysis Theory. University Chemistry, 2024, 39(6): 132-136. doi: 10.3866/PKU.DXHX202311018

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(286)
HTML views(68)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142