Citation: ZHANG Yan-Ru, WANG Meng-Qin, CUI Yang-Zhe, LIU Min, LI Zhong-Feng, JIN Qiong-Hua. Syntheses and Characterization of Two Luminescent Silver(Ⅰ) Complexes Based on Mixed Phosphine Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(10): 2089-2094. doi: 10.11862/CJIC.2015.274 shu

Syntheses and Characterization of Two Luminescent Silver(Ⅰ) Complexes Based on Mixed Phosphine Ligands

1.
1 Department of Chemistry, Capital Normal University, Beijing 100048, China;
2.
2 College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China

Corresponding author: JIN Qiong-Hua,
Received Date: 28 June 2015
Available Online: 12 July 2015
Fund Project: 国家自然科学基金(No.21171119) (No.21171119)863国家高技术研究发展计划(No.2012AA063201) (No.2012AA063201)北京教育委员会基金(No.KM201210028020) (No.KM201210028020)北京市优秀人才项目(No.2010D005016000002) (No.2010D005016000002)北京市自然科学基金(No.7122015)资助项目。 (No.7122015)

Two novel silver(Ⅰ) complexes [Ag₂Br₂(DPEphos)₂(dppe)](1) and [Ag(DPEphos)(dppe)]NO₃(2) (DPEphos=bis[2-(diphenylphosphino)phenyl]ether, dppe=bis(diphenylphosphino)ethane) have been synthesized and characterized by IR, single-crystal X-ray diffraction, ¹H NMR, ³¹P NMR spectroscopy and fluorescence spectra. 1 is comprised of AgBr, DPEphos and dppe in 2:2:1 molar ratio generating a binuclear complex. The dppe ligand bridges two Ag atoms through two P atoms in 1. While, 2 is obtained by the reactions of AgNO₃, DPEphos and dppe in 1:1:1 molar ratio generating a sample mono-nuclear complex. The Ag(Ⅰ) atom is chelated by DPEphos and dppe ligand. In the ³¹P NMR spectra of 2, there are four splitting signals (doublets or triplets). The luminescent spectra show that the origin of these emissions all involves emissive state derived from ligand centered π-π^* transition. CCDC: 1043375, 1; 1043376, 2.
- bis[2-(diphenylphosphino)phenyl]ether;bis(diphenylphosphino)ethane;silver(Ⅰ);fluorescence
1. [1]
  [1] Kim E, Lee H, Noh T H, et al. Cryst. Growth Des., 2014,14:1888-1894
2. [2]
  [2] Yue C Y, Yan C F, Feng R, et al. Inorg. Chem., 2009,48:2873-2879
3. [3]
  [3] Rajput G, Yadav M K, Drew M G, et al. Inorg. Chem., 2015, 54:2572-2579
4. [4]
  [4] Nitsch J, Kleeberg C H, Fröhlich R, et al. Dalton Trans., 2015,44:6944-6960
5. [5]
  [5] Demas J N, Graff B A. Coord. Chem. Rev., 2001,211:317-351
6. [6]
  [6] Minaev B, Jansson E,Ågren H. J. Chem. Phys., 2006,125:234704/1-18
7. [7]
  [7] Tsubomura T, Sakai K. Coord. Chem. Rev., 1998,171:107-113
8. [8]
  [8] Wang X X, Liu Y G, Hecke K V, et al. Z. Anorg. Allg. Chem., 2015,641:903-910
9. [9]
  [9] Felder D, Nierengarten J F, Barigelletti F, et al. J. Am. Chem. Soc., 2001,123:6291-6299
10. [10]
  [10] Effendy, Nicola C, Pettinari C, et al. Inorg. Chim. Acta, 2006,359:64-80
11. [11]
  [11] Qiu Q M, Huang X, Zhao Y H, et al. Polyhedron, 2014,83:16-23
12. [12]
  [12] Cui L N, Li Z F, Jin Q H, et al. Inorg. Chem. Commun., 2012,20:126-130
13. [13]
  [13] Kranenburg M, Burgt Y, Kamer P, et al. Organometallics, 1995,14:3081-3089
14. [14]
  [14] Kuang S, Cuttell D G, McMillin D R, et al. Inorg. Chem., 2002,41:3313-3322
15. [15]
  [15] Kuang S M, Fanwick P E, Walton R A. Inorg. Chem., 2002,41:405-411
16. [16]
  [16] Venkateswaran R, Mague J T, Balakrishna M S. Inorg. Chem., 2007,46:809-817
17. [17]
  [17] Partyka D V, Updegraff Ⅲ J B, Zeller M, et al. Dalton Trans., 2010,39:5388-5397
18. [18]
  [18] Balakrishna M S, Venkateswaran R, Mobin S M. Inorg. Chim. Acta, 2009,362:271-276
19. [19]
  [19] Sheldrick G M. SHELXS-97 and SHELXL-97, University of Göttingen, Göttingen, Germany, 1997.
20. [20]
  [20] Gao S, Li Z F, Liu M, et al. Polyhedron, 2014,83:10-15
21. [21]
  [21] Balakrishna M S, Venkateswaran R, Mobin S M. Polyhedron, 2008,27:899-904
22. [22]
  [22] Freudenmann D, Feldmann C. Inorg. Chim. Acta, 2011, 375:311-313
23. [23]
  [23] Adrien K, Omar M, Gianluca A, et al. Eur. J. Inorg. Chem., 2014,2014:1345-1355
24. [24]
  [24] George C, Philip J C, Paraskevas A. Polyhedron, 2012,31:502-505
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