Citation: WANG Cui-Juan, MAO Kai-Li, DAI Hai-Yu, LIU Xiao-Lei, MENG Tao, ZHANG Zhi-Bin, ZHOU Xian-Li, WANG Yao-Yu. Structural Diversity of Two Cadmium(Ⅱ) Polymers Based on Pyrazine Derivative Ligand: Syntheses, Crystal Structures and Bioactivities[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2221-2228. doi: 10.11862/CJIC.2015.267 shu

Structural Diversity of Two Cadmium(Ⅱ) Polymers Based on Pyrazine Derivative Ligand: Syntheses, Crystal Structures and Bioactivities

1.
1 Department of Chemistry and Chemical Engineering, School of Life Science and engineering, Southwest Jiaotong University, Chengdu 610031, China;
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2 Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Department of Chemistry, Northwest University, Xi'an 710069, China

Corresponding author: WANG Cui-Juan,
Received Date: 9 February 2015
Available Online: 15 July 2015
Fund Project: 国家自然科学基金(No.21401151) (No.21401151)四川省科技支撑计划(No.2015GZ0233) (No.2015GZ0233)中央高校基本科研业务费专项资金(No.SWJTU12CX049)资助项目。 (No.SWJTU12CX049)

Under same conditions, ligand derived from Pyrazine was selected and reacted with different Cadmium(Ⅱ) salts, producing two novel coordination compounds [Cd(L)₂]_n (1) and [Cd₂(L)₂(CH₃COO)₂(H₂O)₂] (2) (HL=4-((3-(pyrazin-2-yl)-1H-pyrazol-1-yl)methyl) benzoic acid), which were characterized by element analysis, TGA, fluorescence spectrum and single X-ray crystal diffraction. Compound 1 crystallizes in the triclinic system with P1 space group, and each Cd(Ⅱ) trigonal bipyramidal are connected to each other to form an infinite 2D sandwich structure. Compound 2 adopts binuclear structure with space group triclinic. Two carboxylate groups coordinated to Cd(Ⅱ) adopt a bidentate chelating mode fashion, which are different from coordination mode of 1. Structural discrepancy in compounds 1 and 2 can be assigned to different chelating modes of carboxylate groups of ligand, as well as ions effect. Superoxide dismutase (SOD) mimetic activity of compound 1 and 2 has been investigated by the modified Marklund method.
- cadmium(Ⅱ);pyrazine derivative ligand;carboxylate groups;fluorescence properties;SOD-like activity
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