Citation: WANG Cui-Juan, MAO Kai-Li, DAI Hai-Yu, LIU Xiao-Lei, MENG Tao, ZHANG Zhi-Bin, ZHOU Xian-Li, WANG Yao-Yu. Structural Diversity of Two Cadmium(Ⅱ) Polymers Based on Pyrazine Derivative Ligand: Syntheses, Crystal Structures and Bioactivities[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2221-2228. doi: 10.11862/CJIC.2015.267 shu

Structural Diversity of Two Cadmium(Ⅱ) Polymers Based on Pyrazine Derivative Ligand: Syntheses, Crystal Structures and Bioactivities

1.
1 Department of Chemistry and Chemical Engineering, School of Life Science and engineering, Southwest Jiaotong University, Chengdu 610031, China;
2.
2 Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Department of Chemistry, Northwest University, Xi'an 710069, China

Corresponding author: WANG Cui-Juan,
Received Date: 9 February 2015
Available Online: 15 July 2015
Fund Project: 国家自然科学基金(No.21401151) (No.21401151)四川省科技支撑计划(No.2015GZ0233) (No.2015GZ0233)中央高校基本科研业务费专项资金(No.SWJTU12CX049)资助项目。 (No.SWJTU12CX049)

Under same conditions, ligand derived from Pyrazine was selected and reacted with different Cadmium(Ⅱ) salts, producing two novel coordination compounds [Cd(L)₂]_n (1) and [Cd₂(L)₂(CH₃COO)₂(H₂O)₂] (2) (HL=4-((3-(pyrazin-2-yl)-1H-pyrazol-1-yl)methyl) benzoic acid), which were characterized by element analysis, TGA, fluorescence spectrum and single X-ray crystal diffraction. Compound 1 crystallizes in the triclinic system with P1 space group, and each Cd(Ⅱ) trigonal bipyramidal are connected to each other to form an infinite 2D sandwich structure. Compound 2 adopts binuclear structure with space group triclinic. Two carboxylate groups coordinated to Cd(Ⅱ) adopt a bidentate chelating mode fashion, which are different from coordination mode of 1. Structural discrepancy in compounds 1 and 2 can be assigned to different chelating modes of carboxylate groups of ligand, as well as ions effect. Superoxide dismutase (SOD) mimetic activity of compound 1 and 2 has been investigated by the modified Marklund method.
- cadmium(Ⅱ);pyrazine derivative ligand;carboxylate groups;fluorescence properties;SOD-like activity
1. [1]
  [1] Yaghi O M, Li H, Davis C, et al. Acc. Chem. Res., 1998,31: 474-484
2. [2]
  [2] Yaghi O M, M O' Keeffe, Ockwig N W, et al. Nature, 2003, 423:705-714
3. [3]
  [3] Chen Y, Han S Y, Li X, et al. Inorg. Chem., 2014,53:10006- 10008
4. [4]
  [4] Wang K C, Feng D W, Liu T F, et al. J. Am. Chem. Soc., 2014,136:13983-13986
5. [5]
  [5] Kong G Q, Ou S, Zou C Z, et al. J. Am. Chem. Soc., 2012, 134:19851-19857
6. [6]
  [6] (a)Yaghi O M, O' Keeffe M, Ockwig N W, et al. Nature, 2003, 423:705-714
7. [7]
  (b)Batten S R, Robson R. Angew. Chem. Int. Ed., 1998,37: 1460-1494
8. [8]
  [7] Li D S, Fu F, Zhao J, et al. Dalton Trans., 2010,39:11522- 11525
9. [9]
  [8] Wibowo A C, Smith M D, Zurloye H C. Cryst. Growth Des., 2011,11:4449-4457
10. [10]
  [9] Zhang B J, Wang C J, Qiu G M, et al. Inorg. Chem. Acta, 2013,397:48-59
11. [11]
  [10] Qiu G M, Wang C J, Zhang Y J, et al. Bull. Korean Chem. Soc., 2012,33:2603-2608
12. [12]
  [11] (a)Geldard J F, Lions F. J. Org. Chem., 1965,30:318-319
13. [13]
  (b)Case F H. J. Org. Chem., 1965,30:931-933
14. [14]
  [12] Sheldrick G M. SHELXS-97, Program for Crystal Structure Determination, University of Göttingen, Germany, 1997.
15. [15]
  [13] Sheldrick G M. SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Germany, 1997.
16. [16]
  [14] Sinha S, Srivastava A K, Tripathi C M, et al. Bioorg. Chem. App., 2007,2007:87918-87927
17. [17]
  [15] Luan X J, Cai X H, Wang Y Y, et al. Chem. Eur. J., 2006, 12:6281-6289
18. [18]
  [16] (a)Son S U, Park K H, Kim B Y, et al. Cryst. Growth Des., 2003,3:507-512
19. [19]
  (b)LIU Xiao-Lei(刘晓雷), WANG Cui-Juan(王萃娟), MAO Kai-Li(毛凯力), et al. Chinese J. Inorg. Chem.(无机化学学报), 2014,30:1983-1946
20. [20]
  [17] Barszcz B, Masternaka J, Sawka-Dobrowolska W. Dalton Trans., 2013,42:5960-5963
21. [21]
  [18] Wang X L, Qin C, Wang E B, et al. Angew. Chem., 2004, 116:5146-5150
22. [22]
  [19] Zhao X X, Ma J P, Dong Y B, et al. Cryst. Growth Des., 2007,7:1058-1068
23. [23]
  [20] Wang C J, Wang Y Y, Liu J Q, et al. Inorg. Chem. Acta, 2009,362:543-550
24. [24]
  [21] Seitz M, Kaiser A, Stempfhuber S, et al. Inorg. Chem., 2005, 44:4630-4636
25. [25]
  [22] Lamann-Glees A, Ruschewitz U. Cryst. Growth Des., 2012, 12:854-861
26. [26]
  [23] Du M, Zhang Z H, Zhao X J, et al. Cryst. Growth Des., 2006,6:114-121
27. [27]
  [24] Liu Y Y, Ma J F., Su Z M, et al. Inorg. Chem., 2007,46: 3027-3037
28. [28]
  [25] (a)Zhang L Y, Liu G F, Zheng S L, et al. Eur. J. Inorg. Chem., 2003,16:2965-2971
29. [29]
  (b)Bunz U H F. Chem. Rev., 2000,100:1605-1644
30. [30]
  [26] Wu S Z, Zeng F, Zhu H P, et al. J. Am. Chem. Soc., 2005, 127:2048-2049
1. [1]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
2. [2]
  Aili Feng , Xin Lu , Peng Liu , Dongju Zhang . Computational Chemistry Study of Acid-Catalyzed Esterification Reactions between Carboxylic Acids and Alcohols. University Chemistry, 2025, 40(3): 92-99. doi: 10.12461/PKU.DXHX202405072
3. [3]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
4. [4]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
5. [5]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
6. [6]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
7. [7]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
8. [8]
  Wenjie SHI , Fan LU , Mengwei CHEN , Jin WANG , Yingfeng HAN . Synthesis and host-guest properties of imidazolium-functionalized zirconium metal-organic cage. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 105-113. doi: 10.11862/CJIC.20240360
9. [9]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
10. [10]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
11. [11]
  Long TANG , Yaxin BIAN , Luyuan CHEN , Xiangyang HOU , Xiao WANG , Jijiang WANG . Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1975-1985. doi: 10.11862/CJIC.20240180
12. [12]
  Peipei CUI , Xin LI , Yilin CHEN , Zhilin CHENG , Feiyan GAO , Xu GUO , Wenning YAN , Yuchen DENG . Transition metal coordination polymers with flexible dicarboxylate ligand: Synthesis, characterization, and photoluminescence property. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2221-2231. doi: 10.11862/CJIC.20240234
13. [13]
  Jianfeng Yan , Yating Xiao , Xin Zuo , Caixia Lin , Yaofeng Yuan . Comprehensive Chemistry Experimental Design of Ferrocenylphenyl Derivatives. University Chemistry, 2024, 39(4): 329-337. doi: 10.3866/PKU.DXHX202310005
14. [14]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
15. [15]
  Zitong Chen , Zipei Su , Jiangfeng Qian . Aromatic Alkali Metal Reagents: Structures, Properties and Applications. University Chemistry, 2024, 39(8): 149-162. doi: 10.3866/PKU.DXHX202311054
16. [16]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
17. [17]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
18. [18]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
19. [19]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
20. [20]
  Ping Ye , Lingshuang Qin , Mengyao He , Fangfang Wu , Zengye Chen , Mingxing Liang , Libo Deng . 荷叶衍生多孔碳的零电荷电位调节实现废水中电化学捕集镉离子. Acta Physico-Chimica Sinica, 2025, 41(3): 2311032-. doi: 10.3866/PKU.WHXB202311032

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(490)
HTML views(80)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142