Citation: ZHAO Ning-Ning, HE Cui-Cui, WANG Tong, AN Ting, ZHAO Feng-Qi, HU Rong-Zu, MA Hai-Xia. Nano-WO₃: Preparation, Characterization and Effect on Thermal Decomposition of Hexanitrohexaazaisowurtzitane[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(10): 1959-1965. doi: 10.11862/CJIC.2015.263 shu

Nano-WO₃: Preparation, Characterization and Effect on Thermal Decomposition of Hexanitrohexaazaisowurtzitane

1.
1 School of Chemical Engineering, Northwest University, Xi'an 710069;
2.
2 Science and Technology on Combustion and Explosion Laboratory, Xi'an Modern Chemistry Research Institute, Xi'an 710065

Corresponding author: MA Hai-Xia,
Received Date: 13 January 2015
Available Online: 16 July 2015
Fund Project: 国家自然科学基金(No.21073141,21373161) (No.21073141,21373161)教育部新世纪优秀人才支持计划基金(No.12-1047) (No.12-1047)高等学校博士学科点专项科研基金(No.20126101110009) (No.20126101110009)燃烧与爆炸技术重点实验室基金(No.9140C3501041001)资助项目。 (No.9140C3501041001)

The cuboid-shaped WO₃ nanoparticles were prepared by the hydrothermal method with controlling the amount of reactant and reaction time, then the as-prepared particles were characterized by X-ray powder diffraction (XRD), transmission electron microscope (TEM), and scanning electron microscope-energy dispersive spectrometry (SEM-EDS). The Effects of WO₃ powders on the thermal decomposition of hexanitrohexaazaisowur-tzitane (CL-20) were investigated by differential scanning calorimetry (DSC). The results show that the peak temperature of the decomposition and the activation energy of WO₃/CL-20 have 2.95℃ and 7.74 kJ·mol^-1 lower than that of CL-20, indicating that nano-WO₃ could accelerate the thermal decomposition of CL-20.
- nanosized tungsten trioxide;hexanitrohexaazaisowurtzitane;hydrothermal method;thermal decomposition
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Nano-WO3: Preparation, Characterization and Effect on Thermal Decomposition of Hexanitrohexaazaisowurtzitane

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Nano-WO₃: Preparation, Characterization and Effect on Thermal Decomposition of Hexanitrohexaazaisowurtzitane