Citation: YANG Xiao-Xun, LENG Ji-Dong, LIU Jun-Liang, JIA Jian-Hua, TONG Ming-Liang. Synthesis, Structures and Magnetic Properties of Two Tetranuclear and Decanuclear Manganese Clusters Bearing the Multidentate Schiff-Base Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(9): 1831-1838. doi: 10.11862/CJIC.2015.260 shu

Synthesis, Structures and Magnetic Properties of Two Tetranuclear and Decanuclear Manganese Clusters Bearing the Multidentate Schiff-Base Ligands

  • Corresponding author: JIA Jian-Hua, 
  • Received Date: 29 May 2015
    Available Online: 13 July 2015

    Fund Project: 国家重点基础研究发展规划("973计划",No.2014CB845602,2012CB821704) ("973计划",No.2014CB845602,2012CB821704)国家自然科学基金(No.21301197,91122032,21371183,91422302) (No.21301197,91122032,21371183,91422302)广东省自然科学基金(S2013020013002) (S2013020013002)以及中央高校基本科研业务费专项资金(14lgpy10)资助项目。 (14lgpy10)

  • A multidentate salicylaldehyde Schiff-base ligand with {NO4} donor set, 3, 5-di-tert-butylsalicylaldehyde-trihydroxymethylaminomethane (H4L), has been synthesized for the first time and characterized by elemental analysis, IR and 1H NMR. Solution reactions of Mn(ClO4)2 or MnCl2·4H2O with H4L in air generated a tetranuclear complex [MnIII4(HL)2(H2L)2(MeCN)4](ClO4)2·2MeCN (1) and a decanuclear complex [MnIII6MnII4(bz)10(L)4(H2O)2]·10MeCN (2), respectively. X-ray studies reveal that complex 1 crystallizes in triclinic space group P1, while complex 2 crystallizes in orthorhombic space group Aba2. Magnetism data in the temperature range 2~300 K have been carried out, indicating the presence of the antiferromagnetic interaction within 2.
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