Citation: CUI Peng, JING Xiao-Fei, REN Hao, YUAN Ye, ZHU Guang-Shan. Porous Aromatic Frameworks: Synthesis via Friedel-Crafts Alkylation Reaction and Gas Sorption Property[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(9): 1855-1859. doi: 10.11862/CJIC.2015.256 shu

Porous Aromatic Frameworks: Synthesis via Friedel-Crafts Alkylation Reaction and Gas Sorption Property

CUI Peng ¹ ,
JING Xiao-Fei ² ,
REN Hao ¹ ,
YUAN Ye ² ,
ZHU Guang-Shan ^1,,

1.
1. State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China;
2.
2. Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun 130024, China

Corresponding author: ZHU Guang-Shan,
Received Date: 31 May 2015
Available Online: 3 August 2015
Fund Project: 国家重点基础研究发展计划(973计划,No.2012CB821700,No.2014CB931804) (973计划,No.2012CB821700,No.2014CB931804)国家自然科学基金委重大国际(地区)合作研究项目(No.21120102034)资助项目。 (地区)合作研究项目(No.21120102034)

A porous aromatic framework, PAF-9 derived from tetraphenylgermane as basic building unit, was synthesized via Friedel-Crafts alkylation reaction. The microstructure and pore property were investigated by FTIR spectroscopy, powder X-ray diffraction, solid state NMR, thermogravimetric analysis and low temperature N₂ adsorption-desorption measurements. The characterizations reveal that PAF-9 possess high thermal and chemical stability as well as high BET surface area of 334 m²·g^-1. Additionally, the resulting PAF materials exhibit high CO₂ adsorption ability.
- Friedel-Crafts alkylation reaction;porous aromatic framework;gas sorption
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