Citation: LI Han SONG, Fen SHI, Wei MA, CHENG Peng. Cryogenic Magnetic Refrigeration Properties of Heterometallic {LnCu₃} Cluster Family[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(9): 1860-1866. doi: 10.11862/CJIC.2015.248 shu

Cryogenic Magnetic Refrigeration Properties of Heterometallic {LnCu₃} Cluster Family

1.
Department of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry(MOE), and Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Nankai University, Tianjin 300071 China

Corresponding author: CHENG Peng,
Received Date: 1 June 2015
Available Online: 14 July 2015
Fund Project: 国家基金委创新团队(No.21421001) (No.21421001)教育部创新团队(IRT13022和13R30) (IRT13022和13R30)111引智计划(B12015) (B12015)天津市自然科学基金(13JCZDJC32200)资助项目。 (13JCZDJC32200)

Based on the survey of Gd-Cu complexes in literatures, a family of {LnCu₃} clusters (Ln=Gd (1), Tb (2), Dy (3)) were selected to study the magnetocaloric effect (MCE) at low temperature due to their isolated Gd-Cu arrangement as well as the pure intramolecular ferromagnetic coupling. A modified one-pot synthetic method based on the reported result was developed to simplify the reaction procedure. Elementary analyses, IR, single crystal/powder X-ray diffraction measurements were carried out to determine the isomorphism and phase purity. Studies of MCEs indicate that complexes 1~3 have a maximum magnetic entropy change (-ΔS_m) of 16.1 (2 K), 6.9 (5 K) and 8.1 (5 K) J·kg^-1·k^-1 for ΔH=0~7 T, respectively. Comparison of the MCE for {GdCu₃} with the reported Gd-Cu clusters emphasizes the importance of weak ferromagnetic interactions in designing of 3d-4f molecular coolers.
- cryogenic magnetic refrigeration;magnetocaloric effect;magnetic entropy change;ferromagnetic interaction
1. [1]
  [1] Zheng Y Z, Zhou G J, Zheng Z, et al. Chem. Soc. Rev., 2014, 43(5):1462-1475
2. [2]
  [2] Liu J L, Chen Y C, Guo F S, et al. Coord. Chem. Rev., 2014,281:26-49
3. [3]
  [3] SHI Peng-Fei (时鹏飞), XIONG Gang (熊刚), ZHANG Zhan-Yun (张战运), et al. Sci. China-Chem., 2013,43(10):1262-1271
4. [4]
  [4] Cremades E, Gómez-Coca S, Aravena D, et al. J. Am. Chem. Soc., 2012,134(25):10532-10542
5. [5]
  [5] Chang L X, Xiong G, Wang L, et al. Chem. Commun., 2013, 49(11):1055-1057
6. [6]
  [6] Hou Y L, Xiong G, Shi P-F, et al. Chem. Commun., 2013,49(54):6066-6068
7. [7]
  [7] Shi P F, Zheng Y Z, Zhao X Q, et al. Chem.-Eur. J., 2012,18(47):15086-15091
8. [8]
  [8] Bing Y, Xu N, Shi W, et al. Chem.-Asian J., 2013,8(7):1412-1418
9. [9]
  [9] Li H, Shi W, Niu Z, et al. Dalton Trans., 2015,44(2):468-471
10. [10]
  [10] Chen Y C, Qin L, Meng Z S, et al. J. Mater. Chem. A, 2014, 2(25):9851-9858
11. [11]
  [11] Lorusso G, Sharples J W, Palacios E, et al. Adv. Mater., 2013,25(33):4653-4656
12. [12]
  [12] Zhang S, Duan E, Cheng P. J. Mater. Chem. A, 2015,3(13):7157-7162
13. [13]
  [13] Tishin A M, Spichkin Y I. The Magnetocaloric Effect and its Application. Bristol and Philadelphia:IOP Publishing, 2003.
14. [14]
  [14] Langley S K, Chilton N F, Moubaraki B, et al. Chem. Sci., 2011,2(6):1166-1169
15. [15]
  [15] Liu J L, Lin W Q, Chen Y C, et al. Inorg. Chem., 2013,52(1):457-463
16. [16]
  [16] Zhang H, Zhuang G L, Kong X J, et al. Cryst. Growth Des., 2013,13(6):2493-2498
17. [17]
  [17] Kettles F J, Milway V A, Tuna F, et al. Inorg. Chem., 2014,53(17):8970-8978
18. [18]
  [18] Andruh M, Ramade I, Codjovi E, et al. J. Am. Chem. Soc., 1993,115(5):1822-1829
19. [19]
  [19] Hooper T N, Schnack J, Piligkos S, et al. Angew. Chem. Int. Ed., 2012,51(19):4633-4636
20. [20]
  [20] Liu J L, Chen Y C, Li Q W, et al. Chem. Commun., 2013, 49(58):6549-6551
21. [21]
  [21] Xiong G, Xu H, Cui J Z, et al. Dalton Trans., 2014,43(15):5639-5642
22. [22]
  [22] Hooper T N, Inglis R, Palacios M A, et al. Chem. Commun., 2014,50(26):3498-3500
23. [23]
  [23] Xue S, Guo Y N, Zhao L, et al. Inorg. Chem., 2014,53(15):8165-8171
24. [24]
  [24] Dermitzaki D, Lorusso G, Raptopoulou C P, et al. Inorg. Chem., 2013,52(18):10235-10237
25. [25]
  [25] Liu J L, Lin W Q, Chen Y C, et al. Chem.-Eur. J., 2013,19(51):17567-17577
26. [26]
  [26] Li Z Y, Wang Y X, Zhu J, et al. Cryst. Growth Des., 2013, 13(8):3429-3437
27. [27]
  [27] Leng J D, Liu J L, Tong M L. Chem. Commun., 2012,48(43):5286-5288
1. [1]
  Jiaxun Wu , Mingde Li , Li Dang . The R eaction of Metal Selenium Complexes with Olefins as a Tutorial Case Study for Analyzing Molecular Orbital Interaction Modes. University Chemistry, 2025, 40(3): 108-115. doi: 10.12461/PKU.DXHX202405098
2. [2]
  Huiying Xu , Minghui Liang , Zhi Zhou , Hui Gao , Wei Yi . Application of Quantum Chemistry Computation and Visual Analysis in Teaching of Weak Interactions. University Chemistry, 2025, 40(3): 199-205. doi: 10.12461/PKU.DXHX202407011
3. [3]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
4. [4]
  Qingcui Yang , Wen Liu , Li Cao , Chen Tang , Bing Xu , Jie Zhao . For Entropy Hurts: Life Thrives on Negative Entropy. University Chemistry, 2024, 39(9): 151-156. doi: 10.12461/PKU.DXHX202402029
5. [5]
  Jiahe LIU , Gan TANG , Kai CHEN , Mingda ZHANG . Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 719-728. doi: 10.11862/CJIC.20250023
6. [6]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
7. [7]
  Xiyuan Su , Zhenlin Hu , Ye Fan , Xianyuan Liu , Xianyong Lu . Change as You Want: Multi-Responsive Superhydrophobic Intelligent Actuation Material. University Chemistry, 2024, 39(5): 228-237. doi: 10.3866/PKU.DXHX202311059
8. [8]
  Lili Wang , Chunxia Chen , Lina Jia , Li Guo , Jingjing Cao . Exploration and Practice in Innovative and Interesting Scientific Research Skills Training for Wood Magnetization. University Chemistry, 2024, 39(6): 246-252. doi: 10.3866/PKU.DXHX202310088
9. [9]
  Hong Zheng , Xin Peng , Chunwang Yi . The Tale of Caprolactam Cyclic Oligomers: The Ever-changing Life of “Princess Cyclo”. University Chemistry, 2024, 39(9): 40-47. doi: 10.12461/PKU.DXHX202403058
10. [10]
  Yuping Wei , Yiting Wang , Jialiang Jiang , Jinxuan Deng , Hong Zhang , Xiaofei Ma , Junjie Li . Interdisciplinary Teaching Practice——Flexible Wearable Electronic Skin for Low-Temperature Environments. University Chemistry, 2024, 39(10): 261-270. doi: 10.12461/PKU.DXHX202404007
11. [11]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 100033-. doi: 10.3866/PKU.WHXB202404023
12. [12]
  Shipeng WANG , Shangyu XIE , Luxian LIANG , Xuehong WANG , Jie WEI , Deqiang WANG . Piezoelectric effect of Mn, Bi co-doped sodium niobate for promoting cell proliferation and bacteriostasis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1919-1931. doi: 10.11862/CJIC.20240094
13. [13]
  Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, 2024, 39(8): 403-410. doi: 10.3866/PKU.DXHX202311093
14. [14]
  YanYuan Jia , Rong Rong , Jie Liu , Jing Guo , GuoYu Jiang , Shuo Guo . Unity is Strength, and Independence Shines: A Science Popularization Experiment on AIE and ACQ Effects. University Chemistry, 2024, 39(9): 349-358. doi: 10.12461/PKU.DXHX202402035
15. [15]
  Xingyuan Lu , Yutao Yao , Junjing Gu , Peifeng Su . Energy Decomposition Analysis and Its Application in the Many-Body Effect of Water Clusters. University Chemistry, 2025, 40(3): 100-107. doi: 10.12461/PKU.DXHX202405074
16. [16]
  Supin Zhao , Jing Xie . Understanding the Vibrational Stark Effect of Water Molecules Using Quantum Chemistry Calculations. University Chemistry, 2025, 40(3): 178-185. doi: 10.12461/PKU.DXHX202406024
17. [17]
  Yaqin Zheng , Lian Zhuo , Meng Li , Chunying Rong . Enhancing Understanding of the Electronic Effect of Substituents on Benzene Rings Using Quantum Chemistry Calculations. University Chemistry, 2025, 40(3): 193-198. doi: 10.12461/PKU.DXHX202406119
18. [18]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
19. [19]
  Ying Zhang , Fang Ge , Zhimin Luo . AI-Driven Biochemical Teaching Research: Predicting the Functional Effects of Gene Mutations. University Chemistry, 2025, 40(3): 277-284. doi: 10.12461/PKU.DXHX202412104
20. [20]
  Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(628)
HTML views(99)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Cryogenic Magnetic Refrigeration Properties of Heterometallic {LnCu3} Cluster Family

Metrics

通讯作者: 陈斌, bchen63@163.com

Cryogenic Magnetic Refrigeration Properties of Heterometallic {LnCu₃} Cluster Family