Citation: LAN Tu, LIU Zhan-Xiang, LI Xing-Liang, LIAO Jia-Li, LUO Shun-Zhong, YANG Yuan-You, CHAI Zhi-Fang, LIU Ning, WANG Dong-Qi. Effect of Low-Enriched Uranium Targets Irradiation on Major Fission Elements and Uranium Speciation[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(9): 1774-1784. doi: 10.11862/CJIC.2015.245 shu

Effect of Low-Enriched Uranium Targets Irradiation on Major Fission Elements and Uranium Speciation

1.
1. Key Laboratory of Radiation Physics and Technology(Sichuan University), Ministry of Education;Institute of Nuclear Science and Technology, Sichuan University, Chengdu 610064, China;
2.
2. CAS Key Laboratory of Nuclear Radiation and Nuclear Techniques, Multidisciplinary Initiative Center, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China;
3.
3. Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang, Sichuan 621900, China;
4.
4. School of Radiation Medicine and Interdisciplinary Sciences(RAD-X), Soochow University, Suzhou, Jiangsu 215123, China

Corresponding author: LIAO Jia-Li, WANG Dong-Qi,
Received Date: 10 April 2015
Available Online: 21 June 2015
Fund Project: 国家自然科学基金委员会和中国工程物理研究院联合基金(NSAF,No.U1330125) (NSAF,No.U1330125)特殊学科点资助项目(No.J1210004) (No.J1210004)国家自然科学基金委员会(No.91026000) (No.91026000)中国科学院百人计划(No.Y2291810S3)资助项目。 (No.Y2291810S3)

The speciation of uranium and effect of major fission products after low-enriched uranium targets being irradiated and solvated were analyzed using the geochemical program CHEMSPEC. The results indicate that the speciation of uranium in water is determined by pH value and the concentration of uranyl, and polynuclear complexes may be generated at high concentration of uranyl. Nitrate anion in the solution may interact with uranyl, and at high concentration of nitrate, uranyl exists as UO₂²⁺ and UO₂NO₃⁺. The presence of CO₂ at low concentrations of uranium brings substantial distribution uranyl carbonate, while this is negligible at high concentration of uranyl due to heavy hydrolysis and aggregation of uranyl. The calculations also show that the major fission products, Tc, I, and Mo, do not affect the speciation of uranium when their concentrations are below 0.01 mol·L^-1 and when they exist as TcO₄^-, I^-, MoO₄^2-.
- speciation;CHEMSPEC;uranium;fission element;irradiation
1. [1]
  [1] Travelli A. Proceeding of the 19th International Meeting on Reduced Enrichment for Research and Test Reactors. Seoul, Korea, 1996:4-8
2. [2]
  [2] Matos J E. Proceeding of the 25th International Meeting on Reduced Enrichment for Research and Test Reactors, RERTR-2003. Chicago, Illinois, 2003:1-8
3. [3]
  [3] Yanagisawa K, Fujishiro T. J. Nucl. Sci. Technol., 1995,32(10):981-988
4. [4]
  [4] Keilser D, Robinson A, Jue J. F, et al. J. Nucl. Mater., 2009, 393(2):311-320
5. [5]
  [5] Izhutov A L, Alexandrov V V, Novosyolov A Y, et al. Proceedings of International Meeting on RERTR-2010. Lisbon, Portugal, 2010:10-15
6. [6]
  [6] Moore G A, Rabin B H, Jue J F, et al. Proceedings of International Meeting on RERTR-2010. Lisbon, Portugal, 2010:1-5
7. [7]
  [7] SUN Rong-Xian(孙荣先), XIE Huai-Ying(解怀英). At. Energ. Sci. Technol.(原子能科学技术), 2011,45(7):847-851
8. [8]
  [8] KANG Ya-Lun(唐亚伦). At. Energ. Sci. Technol.(原子能科学技术), 2003,37(Suppl.):21-23
9. [9]
  [9] Omar H, Ghazi N, Hainoun A. Prog. Nucl. Energy, 2012,60:140-145
10. [10]
  [10] Bokhari I, Pervez S. Nucl. Eng. Des., 2010,240:123-128
11. [11]
  [11] Albarhoum M. Prog. Nucl. Energy, 2010,52:809-812
12. [12]
  [12] Albarhoum M. Ann. Nucl. Energ., 2010,37:1351-1355
13. [13]
  [13] Albarhoum M. Prog. Nucl. Energy, 2010,52:536-540
14. [14]
  [14] Mahmaood T, Pervez S, Iqbal M. Ann. Nucl. Energ., 2008, 35:1440-1446
15. [15]
  [15] Bokhari I. Ann. Nucl. Energ., 2004,31:1265-1273
16. [16]
  [16] KANG Ya-Lun(唐亚伦), ZHANG Ai-Min(张爱民), ZHANG Ying-Chao(张应超). At. Energ. Sci. Technol.(原子能科学技术), 2005,39(Suppl.):99-103
17. [17]
  [17] Omar H, Ghazi N, Hainoun A. Prog. Nucl. Energy, 2012,60:140-145
18. [18]
  [18] Youker A J, Chung P L, Tkac P, et al. Proceedings of the 1st Annual Mo-99 Topical Meeting. Santa Fe, New Mexico, 2011:1-12
19. [19]
  [19] Leonard R A, Chen L, Mertz C J, et al. Proceeding of the 19th International Enrichment for Research and Testing Reactors Meeting. Seoul, Korea, 1996:6-10
20. [20]
  [20] Mahmood T, Iqbal M. Ann. Nucl. Energ., 2012,42:175-178
21. [21]
  [21] Vandegrift G F, Conner C, Aase S, et al. Proceedings of the 6th International Topical Meeting, Research Reactor Fuel Management (RRFM). Ghent, Belgium, 2002:11-17
22. [22]
  [22] Steven C, Arjan J, Kevin E. Eur. J. Nucl. Med. Mol., 2010, 37:1817-1820
23. [23]
  [23] Vandegrift G, Conner C, Hofman G. et al. Ind. Eng. Chem. Res., 2000,39:3140-3145
24. [24]
  [24] Matthews K, Bowyer T, Saey P, et al. J. Environ. Radioact., 2012,110:1-6
25. [25]
  [25] WANG Xiang-Yun(王祥云), CHEN Tao(陈涛), LIU Chun-Li (刘春立). Sci. China:Ser. B.(中国科学B辑:化学), 2009, 39(11):1551-1562
26. [26]
  [26] ZHU Jian-Bo(朱建波), WANG Xiang-Yun(王祥云), CHEN Tao(陈涛), et al. Sci. China:Chem.(中国科学:化学), 2012, 42(6):856-864
27. [27]
  [27] CHEN Tao(陈涛), WANG Xiang-Yun(王祥云), TIAN Wen-Yu(田文宇), et al. Acta Phys.-Chim. Sin.(物理化学学报), 2010,26(4):811-816
28. [28]
  [28] Korichi S, Bensmaili A. J. Hazard. Mater., 2009,169(1):780-793
29. [29]
  [29] Markich S. Sci. World J., 2002,2:707-729
30. [30]
  [30] Clark D, Conradson S, Donohoe R, et al. Inorg. Chem., 1999, 38(7):1456-1466
31. [31]
  [31] Priyadarshini N, Sampath M, Kumar S, et al. J. Radioanal. Nucl. Chem., 2013,298(3):1923-1931
32. [32]
  [32] Zanonato P, Di Bernardo, Grenthe I. Dalton Trans., 2014,43(6):2378-2383
33. [33]
  [33] Li B, Matveev A, Krüger S, et al. Comput. Theo. Chem., 2015, 1051:151-160
34. [34]
  [34] Vallet V, Wahlgren U, Grenthe I. J. Phys. Chem. A, 2012, 116(50):12373-12380
35. [35]
  [35] Chien W, Anbalagan V, Zandler M, et al. J. Am. Soc. Mass Spectr., 2004,15(6):777-783
36. [36]
  [36] Rios D, Michelini M, Lucena A, et al. Inorg. Chem., 2012, 51(12):6603-6614
37. [37]
  [37] Tsushima S, Reich T. Chem. Phys. Lett., 2001,347(1):127-132
38. [38]
  [38] McGrail B, Pianowski L, Burns P. J. Am. Chem. Soc., 2014, 136(13):4797-4800
39. [39]
  [39] Suleimenov O, Seward T, Hovey J. J. Solution Chem., 2007, 36(9):1093-1102
40. [40]
  [40] Sieffert N, Wipff G. Dalton Trans., 2015,44:2623-2638
41. [41]
  [41] Kumar N, Seminario J. J. Phys. Chem. A, 2015,119(4):689-703
42. [42]
  [42] KANG Ming-Liang(康明亮), JIANG Mei-Ling(蒋美玲), YANG Zhuan-Wei(杨颛维), et al. J. Nucl. Radiochem.(核化学与放射化学), 2013,35(3):160-166
43. [43]
  [43] Balboni E, Morrison J, Wang Z, et al. Geochim. Cosmochim. Acta, 2015,151:133-149
44. [44]
  [44] Pan H, Liao W, Wai C, et al. Dalton Trans., 2014,43(28):10713-10718
1. [1]
  Xiangli Wang , Yuanfu Deng . Teaching Design of Elemental Chemistry from the Perspective of “Curriculum Ideology and Politics”: Taking Arsenic as an Example. University Chemistry, 2024, 39(2): 270-279. doi: 10.3866/PKU.DXHX202308092
2. [2]
  Haiping Wang . A Streamlined Method for Drawing Lewis Structures Using the Valence State of Outer Atoms. University Chemistry, 2024, 39(8): 383-388. doi: 10.12461/PKU.DXHX202401073
3. [3]
  Yonghui Wang , Weilin Chen , Yangguang Li . Knowledge Construction of “Solubility of Inorganic Substances” in Elemental Chemistry Teaching. University Chemistry, 2024, 39(4): 261-267. doi: 10.3866/PKU.DXHX202312102
4. [4]
  Huan Zhang , Linyu Pu , Wei Wang , Yatang Dai , Xu Huang . Curriculum Development and Blended Teaching Practice in the Graduate Course on Elemental Inorganic Chemistry. University Chemistry, 2024, 39(6): 166-173. doi: 10.3866/PKU.DXHX202402010
5. [5]
  Zhengli Hu , Jia Wang , Yi-Lun Ying , Shaochuang Liu , Hui Ma , Wenwei Zhang , Jianrong Zhang , Yi-Tao Long . Exploration of Ideological and Political Elements in the Development History of Nanopore Electrochemistry. University Chemistry, 2024, 39(8): 344-350. doi: 10.3866/PKU.DXHX202401072
6. [6]
  Yang Lv , Yingping Jia , Yanhua Li , Hexiang Zhong , Xinping Wang . Integrating the Ideological Elements with the “Chemical Reaction Heat” Teaching. University Chemistry, 2024, 39(11): 44-51. doi: 10.12461/PKU.DXHX202402059
7. [7]
  Yajun Jian , Quanguo Zhai , Quan Gu , Shengli Gao . Reconstruction and Practice of the Teaching Content of “Carbon Group Elements” in Inorganic Chemistry to Reflect Comprehensive Education Function. University Chemistry, 2024, 39(11): 96-107. doi: 10.12461/PKU.DXHX202403006
8. [8]
  Siyao Zhan , Yajiao Wang , Zhihuan Cai , Ayizhada Maimaitiyumier , Tilan Duan , Xiangfeng Wei , Qi Wang , Jiehua Liu , Xianghua Kong . Exploration of the Chemical Elements across Time and Space. University Chemistry, 2024, 39(9): 5-10. doi: 10.12461/PKU.DXHX202403071
9. [9]
  Yanhui Sun , Junmin Nan , Guozheng Ma , Xiaoxi Zuo , Guoliang Li , Xiaoming Lin . Exploration and Teaching Practice of Ideological and Political Elements in Interface Physical Chemistry: Taking “Additional Pressure on Curved Surfaces” as an Teaching Example. University Chemistry, 2024, 39(11): 20-27. doi: 10.3866/PKU.DXHX202402023
10. [10]
  Yingran Liang , Fei Wang , Jiabao Sun , Hongtao Zheng , Zhenli Zhu . Construction and Application of a New Experimental Device for Determination of Alkaline Metal Elements by Plasma Atomic Emission Spectrometry Based on Solution Cathode Glow Discharge: An Alternative Approach for Fundamental Teaching Experiments in Emission Spectroscopy. University Chemistry, 2024, 39(5): 380-387. doi: 10.3866/PKU.DXHX202312024
11. [11]
  Yan Li , Xinze Wang , Xue Yao , Shouyun Yu . Kinetic Resolution Enabled by Photoexcited Chiral Copper Complex-Mediated Alkene E→Z Isomerization: A Comprehensive Chemistry Experiment for Undergraduate Students. University Chemistry, 2024, 39(5): 1-10. doi: 10.3866/PKU.DXHX202309053
12. [12]
  Linhan Tian , Changsheng Lu . Discussion on Sextuple Bonding in Diatomic Motifs of Chromium Family Elements. University Chemistry, 2024, 39(8): 395-402. doi: 10.3866/PKU.DXHX202401056
13. [13]
  Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
14. [14]
  Yan Li , Fei Ding , Jing Wang , Jing Nan , Yijun Li , Xiaohang Qiu . Give a Man a Fish, and Teach a Man to Fish: Self-Designed Instrumental Analysis Experiments and Integration of Ideological and Political Elements. University Chemistry, 2024, 39(2): 208-213. doi: 10.3866/PKU.DXHX202310097
15. [15]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
16. [16]
  Hongwei Ma , Hui Li . Three Methods for Structure Determination from Powder Diffraction Data. University Chemistry, 2024, 39(3): 94-102. doi: 10.3866/PKU.DXHX202310035
17. [17]
  Pingping Zhu , Yongjun Xie , Yuanping Yi , Yu Huang , Qiang Zhou , Shiyan Xiao , Haiyang Yang , Pingsheng He . Excavation and Extraction of Ideological and Political Elements for the Virtual Simulation Experiments at Molecular Level: Taking the Project “the Simulation and Computation of Conformation, Morphology and Dimensions of Polymer Chains” as an Example. University Chemistry, 2024, 39(2): 83-88. doi: 10.3866/PKU.DXHX202309063
18. [18]
  Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
19. [19]
  Juan Yuan , Bin Zhang , Jinping Wu , Mengfan Wang . Design of a Comprehensive Experiment on Preparation and Characterization of Cu₂(Salen)₂ Nanomaterials with Two Distinct Morphologies. University Chemistry, 2024, 39(10): 420-425. doi: 10.3866/PKU.DXHX202402014
20. [20]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(326)
HTML views(50)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142