Citation: WU Qi, LIU Hong-Ming, JINANG Fang-Chao, MENG Xiang-Gao, CHEN Xing-Guo, YANG Lei, HU Zhang-Gui, QIN Jin-Gui. KBi₄F₁₃: An Infrared Nonlinear Optical Material with High Laser Damage Threshold[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(9): 1875-1880. doi: 10.11862/CJIC.2015.238 shu

KBi₄F₁₃: An Infrared Nonlinear Optical Material with High Laser Damage Threshold

1.
1. Department of Chemistry, Wuhan University, Wuhan 430072, China;
2.
2. College of Chemistry, Central China Normal University, Wuhan 430079, China;
3.
3. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China

Corresponding author: QIN Jin-Gui,
Received Date: 1 June 2015
Available Online: 23 July 2015
Fund Project: 国家自然科学基金重大研究计划重点支持项目(No.91022036) (No.91022036)国家重点基础研究计划(973计划)(No.2010CB630701)资助项目。 (973计划)(No.2010CB630701)

KBi₄F₁₃ was synthesized by hydrothermal reaction of KF and Bi₂O₃ in aqueous solution of HF. Its crystal structure was determined by X-ray diffraction on the single crystal for the first time. Its potential as a new mid-IR nonlinear optical (NLO) material has been investigated. Its powders exhibit a phase-matchable second harmonic generation (SHG) effect as strong as a half of KDP. The laser damage threshold (LDT) value of its powders is measured to be 120 MW·cm^-2, which is much higher than that of the currently commercialized IR NLO material AgGaS₂ (5 MW·cm^-2, measured in the same condition). Its powders show the transparent window in infrared region up to 20 μm, and it is thermally stable up to 220℃. These results indicate that KBi₄F₁₃ is a potentially useful new mid-IR NLO material with a high LDT.
- bismuth halide;single crystal structure;nonlinear optical material;laser damage threshold;mid-infrared region
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KBi₄F₁₃: An Infrared Nonlinear Optical Material with High Laser Damage Threshold