Citation: WU Qi, LIU Hong-Ming, JINANG Fang-Chao, MENG Xiang-Gao, CHEN Xing-Guo, YANG Lei, HU Zhang-Gui, QIN Jin-Gui. KBi4F13: An Infrared Nonlinear Optical Material with High Laser Damage Threshold[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(9): 1875-1880. doi: 10.11862/CJIC.2015.238
-
KBi4F13 was synthesized by hydrothermal reaction of KF and Bi2O3 in aqueous solution of HF. Its crystal structure was determined by X-ray diffraction on the single crystal for the first time. Its potential as a new mid-IR nonlinear optical (NLO) material has been investigated. Its powders exhibit a phase-matchable second harmonic generation (SHG) effect as strong as a half of KDP. The laser damage threshold (LDT) value of its powders is measured to be 120 MW·cm-2, which is much higher than that of the currently commercialized IR NLO material AgGaS2 (5 MW·cm-2, measured in the same condition). Its powders show the transparent window in infrared region up to 20 μm, and it is thermally stable up to 220℃. These results indicate that KBi4F13 is a potentially useful new mid-IR NLO material with a high LDT.
-
-
[1]
[1] (a)Okorogu O, Mirov S B, Lee W, et al. Opt. Commun., 1998, 155:307-312
-
[2]
(b)Chemla D S, Kopecks P J, Robertson D S, et al. Opt. Commun., 1971,3:29-31
-
[3]
[2] Boyd G D, Kasper H M, McFee J H, et al. IEEE J. Quantum Electron., 1972,8:900-908
-
[4]
[3] Boyd G D, Buehler E, Storz F G. Appl. Phys. Lett., 1971,18:301-304
-
[5]
[4] Halasyamani P S. Chem. Mater., 2004,16:3586-3592
-
[6]
[5] Halasyamani P S, Poeppelmeier K R. Chem. Mater., 1998, 10:2753-2769
-
[7]
[6] Ok K M, Halasyamani P S, Casanova D, et al. Inorg. Chem., 2006,18:3176-3183
-
[8]
[7] Marvel M R, Lesage J, Baek J, et al. J. Am. Chem. Soc., 2007, 129:13963-13969
-
[9]
[8] Halasyamani P S, Poeppelmeier K R. Inorg. Chem., 2008, 47:8427-8428
-
[10]
[9] Mao J G, Jiang H L, Kong F. Inorg. Chem., 2008,47:8498-8510
-
[11]
[10] ZHANG Jun-Jie(张俊杰), ZHANG Zhong-Han(张中晗), TAO Xu-Tang(陶绪堂). J. Shandong Univ.:Nat. Sci.(山东大学学报:理学版), 2011,46(10):99-120
-
[12]
[11] Zhang G, Qin J, Liu T, et al. Appl. Phys. Lett., 2009,95:2611041-2611043
-
[13]
[12] Zhang Gang(张刚). Thesis for the Doctorate of Wuhan University(武汉大学博士学位论文). 2008.
-
[14]
[13] Huang Yin(黄印). Thesis for the Doctorate of Wuhan University(武汉大学博士学位论文). 2014.
-
[15]
[14] Zimina G V, Spiridonov F M, Zamanskaya A Y, et al. Russ. J. Inorg. Chem., 1980,25:791-793
-
[16]
[15] Phanon D, Gautier-Luneau I. Angew. Chem. Int. Ed., 2007, 46:8488-8491
-
[17]
[16] Sheldrick G M. Acta Cryst., 2008,A64:112-122
-
[18]
[17] Kurtz S K, Perry T T. J. Appl. Phys., 1968,39:3798-4013
-
[1]
-
-
[1]
Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . 卤化物钙钛矿的单双向离子迁移. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-. doi: 10.3866/PKU.WHXB202311011
-
[2]
Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050
-
[3]
Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl0.08Mn1.92O4 single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
-
[4]
Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
-
[5]
Yinyin Qian , Rui Xu . Utilizing VESTA Software in the Context of Material Chemistry: Analyzing Twin Crystal Nanostructures in Indium Antimonide. University Chemistry, 2024, 39(3): 103-107. doi: 10.3866/PKU.DXHX202307051
-
[6]
Qi Wang , Yicong Gao , Feng Lu , Quli Fan . Preparation and Performance Characterization of the Second Near-Infrared Phototheranostic Probe: A New Design and Teaching Practice of Polymer Chemistry Comprehensive Experiment. University Chemistry, 2024, 39(11): 342-349. doi: 10.12461/PKU.DXHX202404141
-
[7]
Yunxin Xu , Wenbo Zhang , Jing Yan , Wangchang Geng , Yi Yan . A Fascinating Saga of “Energetic Materials”. University Chemistry, 2024, 39(9): 266-272. doi: 10.3866/PKU.DXHX202307008
-
[8]
Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au11(dppf)4Cl2 nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
-
[9]
Dongju Zhang . Exploring the Descriptions and Connotations of Basic Concepts of Teaching Crystal Structures. University Chemistry, 2024, 39(3): 18-22. doi: 10.3866/PKU.DXHX202304003
-
[10]
Yanxin Wang , Hongjuan Wang , Yuren Shi , Yunxia Yang . Application of Python for Visualizing in Structural Chemistry Teaching. University Chemistry, 2024, 39(3): 108-117. doi: 10.3866/PKU.DXHX202306005
-
[11]
Jin Jia , Shangda Jiang . Is the z Axis Special in Atomic Structure?. University Chemistry, 2024, 39(6): 400-404. doi: 10.12461/PKU.DXHX202403091
-
[12]
Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two LnⅢ3 complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
-
[13]
Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
-
[14]
Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
-
[15]
Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
-
[16]
Zian Lin , Yingxue Jin . Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry (MALDI-MS) for Disease Marker Screening and Identification: A Comprehensive Experiment Teaching Reform in Instrumental Analysis. University Chemistry, 2024, 39(11): 327-334. doi: 10.12461/PKU.DXHX202403066
-
[17]
Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb2 complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
-
[18]
Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
-
[19]
Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
-
[20]
Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(371)
- HTML views(57)