Citation:
WU Qi, LIU Hong-Ming, JINANG Fang-Chao, MENG Xiang-Gao, CHEN Xing-Guo, YANG Lei, HU Zhang-Gui, QIN Jin-Gui. KBi4F13: An Infrared Nonlinear Optical Material with High Laser Damage Threshold[J]. Chinese Journal of Inorganic Chemistry,
;2015, 31(9): 1875-1880.
doi:
10.11862/CJIC.2015.238
-
KBi4F13 was synthesized by hydrothermal reaction of KF and Bi2O3 in aqueous solution of HF. Its crystal structure was determined by X-ray diffraction on the single crystal for the first time. Its potential as a new mid-IR nonlinear optical (NLO) material has been investigated. Its powders exhibit a phase-matchable second harmonic generation (SHG) effect as strong as a half of KDP. The laser damage threshold (LDT) value of its powders is measured to be 120 MW·cm-2, which is much higher than that of the currently commercialized IR NLO material AgGaS2 (5 MW·cm-2, measured in the same condition). Its powders show the transparent window in infrared region up to 20 μm, and it is thermally stable up to 220℃. These results indicate that KBi4F13 is a potentially useful new mid-IR NLO material with a high LDT.
-
-
-
[1]
[1] (a)Okorogu O, Mirov S B, Lee W, et al. Opt. Commun., 1998, 155:307-312
-
[2]
(b)Chemla D S, Kopecks P J, Robertson D S, et al. Opt. Commun., 1971,3:29-31
-
[3]
[2] Boyd G D, Kasper H M, McFee J H, et al. IEEE J. Quantum Electron., 1972,8:900-908
-
[4]
[3] Boyd G D, Buehler E, Storz F G. Appl. Phys. Lett., 1971,18:301-304
-
[5]
[4] Halasyamani P S. Chem. Mater., 2004,16:3586-3592
-
[6]
[5] Halasyamani P S, Poeppelmeier K R. Chem. Mater., 1998, 10:2753-2769
-
[7]
[6] Ok K M, Halasyamani P S, Casanova D, et al. Inorg. Chem., 2006,18:3176-3183
-
[8]
[7] Marvel M R, Lesage J, Baek J, et al. J. Am. Chem. Soc., 2007, 129:13963-13969
-
[9]
[8] Halasyamani P S, Poeppelmeier K R. Inorg. Chem., 2008, 47:8427-8428
-
[10]
[9] Mao J G, Jiang H L, Kong F. Inorg. Chem., 2008,47:8498-8510
-
[11]
[10] ZHANG Jun-Jie(张俊杰), ZHANG Zhong-Han(张中晗), TAO Xu-Tang(陶绪堂). J. Shandong Univ.:Nat. Sci.(山东大学学报:理学版), 2011,46(10):99-120
-
[12]
[11] Zhang G, Qin J, Liu T, et al. Appl. Phys. Lett., 2009,95:2611041-2611043
-
[13]
[12] Zhang Gang(张刚). Thesis for the Doctorate of Wuhan University(武汉大学博士学位论文). 2008.
-
[14]
[13] Huang Yin(黄印). Thesis for the Doctorate of Wuhan University(武汉大学博士学位论文). 2014.
-
[15]
[14] Zimina G V, Spiridonov F M, Zamanskaya A Y, et al. Russ. J. Inorg. Chem., 1980,25:791-793
-
[16]
[15] Phanon D, Gautier-Luneau I. Angew. Chem. Int. Ed., 2007, 46:8488-8491
-
[17]
[16] Sheldrick G M. Acta Cryst., 2008,A64:112-122
-
[18]
[17] Kurtz S K, Perry T T. J. Appl. Phys., 1968,39:3798-4013
-
[1]
-
-
-
[1]
Zhaodong WANG . In situ synthesis, crystal structure, and magnetic characterization of a trinuclear copper complex based on a multi-substituted imidazo[1,5-a]pyrazine scaffold. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 597-604. doi: 10.11862/CJIC.20240268
-
[2]
Zhiwen HUANG , Qi LIU , Jianping LANG . W/Cu/S cluster-based supramolecular macrocycles and their third-order nonlinear optical responses. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 79-87. doi: 10.11862/CJIC.20240184
-
[3]
Jiahui CHEN , Tingting ZHENG , Xiuyun ZHANG , Wei LÜ . Research progress of near-infrared absorption inorganic nanomaterials in photothermal and photodynamic therapy of tumors. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2396-2414. doi: 10.11862/CJIC.20240106
-
[4]
Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . 卤化物钙钛矿的单双向离子迁移. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-. doi: 10.3866/PKU.WHXB202311011
-
[5]
Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050
-
[6]
Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
-
[7]
Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl0.08Mn1.92O4 single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
-
[8]
Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
-
[9]
Yinyin Qian , Rui Xu . Utilizing VESTA Software in the Context of Material Chemistry: Analyzing Twin Crystal Nanostructures in Indium Antimonide. University Chemistry, 2024, 39(3): 103-107. doi: 10.3866/PKU.DXHX202307051
-
[10]
Qi Wang , Yicong Gao , Feng Lu , Quli Fan . Preparation and Performance Characterization of the Second Near-Infrared Phototheranostic Probe: A New Design and Teaching Practice of Polymer Chemistry Comprehensive Experiment. University Chemistry, 2024, 39(11): 342-349. doi: 10.12461/PKU.DXHX202404141
-
[11]
Yunxin Xu , Wenbo Zhang , Jing Yan , Wangchang Geng , Yi Yan . A Fascinating Saga of “Energetic Materials”. University Chemistry, 2024, 39(9): 266-272. doi: 10.3866/PKU.DXHX202307008
-
[12]
Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au11(dppf)4Cl2 nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
-
[13]
Dongju Zhang . Exploring the Descriptions and Connotations of Basic Concepts of Teaching Crystal Structures. University Chemistry, 2024, 39(3): 18-22. doi: 10.3866/PKU.DXHX202304003
-
[14]
Yanxin Wang , Hongjuan Wang , Yuren Shi , Yunxia Yang . Application of Python for Visualizing in Structural Chemistry Teaching. University Chemistry, 2024, 39(3): 108-117. doi: 10.3866/PKU.DXHX202306005
-
[15]
Jin Jia , Shangda Jiang . Is the z Axis Special in Atomic Structure?. University Chemistry, 2024, 39(6): 400-404. doi: 10.12461/PKU.DXHX202403091
-
[16]
Xianggui Kong , Wenying Shi . Comprehensive Chemical Experimental Design of Optically Encrypted Materials. University Chemistry, 2025, 40(3): 355-362. doi: 10.12461/PKU.DXHX202406067
-
[17]
Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . 钠离子电池中铁基异质结构负极材料的最新研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-. doi: 10.3866/PKU.WHXB202311015
-
[18]
Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407
-
[19]
Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi2O3 pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
-
[20]
Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two LnⅢ3 complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(475)
- HTML views(64)