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Citation: WU Qi, LIU Hong-Ming, JINANG Fang-Chao, MENG Xiang-Gao, CHEN Xing-Guo, YANG Lei, HU Zhang-Gui, QIN Jin-Gui. KBi4F13: An Infrared Nonlinear Optical Material with High Laser Damage Threshold[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(9): 1875-1880. doi: 10.11862/CJIC.2015.238 shu

KBi4F13: An Infrared Nonlinear Optical Material with High Laser Damage Threshold

  • 1.

    1. Department of Chemistry, Wuhan University, Wuhan 430072, China;

  • 2.

    2. College of Chemistry, Central China Normal University, Wuhan 430079, China;

  • 3.

    3. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China

  • Corresponding author: QIN Jin-Gui, 
  • Received Date: 1 June 2015
    Available Online: 23 July 2015

    Fund Project: 国家自然科学基金重大研究计划重点支持项目(No.91022036) (No.91022036)国家重点基础研究计划(973计划)(No.2010CB630701)资助项目。 (973计划)(No.2010CB630701)

  • KBi4F13 was synthesized by hydrothermal reaction of KF and Bi2O3 in aqueous solution of HF. Its crystal structure was determined by X-ray diffraction on the single crystal for the first time. Its potential as a new mid-IR nonlinear optical (NLO) material has been investigated. Its powders exhibit a phase-matchable second harmonic generation (SHG) effect as strong as a half of KDP. The laser damage threshold (LDT) value of its powders is measured to be 120 MW·cm-2, which is much higher than that of the currently commercialized IR NLO material AgGaS2 (5 MW·cm-2, measured in the same condition). Its powders show the transparent window in infrared region up to 20 μm, and it is thermally stable up to 220℃. These results indicate that KBi4F13 is a potentially useful new mid-IR NLO material with a high LDT.
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    1. [1]

      [1] (a)Okorogu O, Mirov S B, Lee W, et al. Opt. Commun., 1998, 155:307-312

    2. [2]

      (b)Chemla D S, Kopecks P J, Robertson D S, et al. Opt. Commun., 1971,3:29-31

    3. [3]

      [2] Boyd G D, Kasper H M, McFee J H, et al. IEEE J. Quantum Electron., 1972,8:900-908

    4. [4]

      [3] Boyd G D, Buehler E, Storz F G. Appl. Phys. Lett., 1971,18:301-304

    5. [5]

      [4] Halasyamani P S. Chem. Mater., 2004,16:3586-3592

    6. [6]

      [5] Halasyamani P S, Poeppelmeier K R. Chem. Mater., 1998, 10:2753-2769

    7. [7]

      [6] Ok K M, Halasyamani P S, Casanova D, et al. Inorg. Chem., 2006,18:3176-3183

    8. [8]

      [7] Marvel M R, Lesage J, Baek J, et al. J. Am. Chem. Soc., 2007, 129:13963-13969

    9. [9]

      [8] Halasyamani P S, Poeppelmeier K R. Inorg. Chem., 2008, 47:8427-8428

    10. [10]

      [9] Mao J G, Jiang H L, Kong F. Inorg. Chem., 2008,47:8498-8510

    11. [11]

      [10] ZHANG Jun-Jie(张俊杰), ZHANG Zhong-Han(张中晗), TAO Xu-Tang(陶绪堂). J. Shandong Univ.:Nat. Sci.(山东大学学报:理学版), 2011,46(10):99-120

    12. [12]

      [11] Zhang G, Qin J, Liu T, et al. Appl. Phys. Lett., 2009,95:2611041-2611043

    13. [13]

      [12] Zhang Gang(张刚). Thesis for the Doctorate of Wuhan University(武汉大学博士学位论文). 2008.

    14. [14]

      [13] Huang Yin(黄印). Thesis for the Doctorate of Wuhan University(武汉大学博士学位论文). 2014.

    15. [15]

      [14] Zimina G V, Spiridonov F M, Zamanskaya A Y, et al. Russ. J. Inorg. Chem., 1980,25:791-793

    16. [16]

      [15] Phanon D, Gautier-Luneau I. Angew. Chem. Int. Ed., 2007, 46:8488-8491

    17. [17]

      [16] Sheldrick G M. Acta Cryst., 2008,A64:112-122

    18. [18]

      [17] Kurtz S K, Perry T T. J. Appl. Phys., 1968,39:3798-4013

  • 加载中
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