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Citation: LIU Quan, CHEN Qiu-Fang, YU Hong, ZHAO Xin, ZHANG Wen-Hua, LANG Jian-Ping. Two One-Dimensional [MS4Cu4]-Supported Coordination Polymers: Assembly and Crystal Structures of {[MS4Cu4(bpe)2(ani)2I2]·3.5ani}n (M=Mo, W; ani=aniline)[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(9): 1805-1810. doi: 10.11862/CJIC.2015.237 shu

Two One-Dimensional [MS4Cu4]-Supported Coordination Polymers: Assembly and Crystal Structures of {[MS4Cu4(bpe)2(ani)2I2]·3.5ani}n (M=Mo, W; ani=aniline)

  • 1.

    1. College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China;

  • 2.

    2. College of Chemistry and Chemical Engineering, Nantong University, Nantong, Jiangsu 226019, China

  • Corresponding author: LANG Jian-Ping, 
  • Received Date: 24 May 2015
    Available Online: 4 June 2015

    Fund Project: 国家自然科学基金(No.21373142,21371126)资助项目。 (No.21373142,21371126)

  • Reactions of the preformed cluster precursors [Et4N]4[MS4Cu4I6] (M=Mo (1a); W (1b)) with a ditopic bridging ligand 1, 2-bis(4-pyridyl)ethane (bpe) in aniline solutions gave rise to two analogous one-dimensional cluster-supported coordination polymers {[MS4Cu4(bpe)2(ani)2I2]·3.5ani}n (M=Mo (2), W (3); ani=aniline). Both 2 and 3 are characterized by elemental analysis, IR spectra, and single crystal X-ray diffraction. X-ray analyses revealed that the pentanuclear saddle-shaped [MS4Cu4] cores in 1a and 1b are retained in 2 and 3. The adjacent [MS4Cu4] cores are interconnected by double bpe bridges to afford one-dimensional zigzag chains extending along the [111] direction.
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    1. [1]

      [1] Lee S C, Holm R H. Chem. Rev., 2004,104:1135-1158

    2. [2]

      [2] Ohki Y, Takikawa Y, Hatanaka T, Tatsumi K. Organometallics, 2006,25:3111-3113

    3. [3]

      [3] Lang J P, Ji S J, Xu Q F, et al. Coord. Chem. Rev., 2003, 241:47-60

    4. [4]

      [4] Zhang W H, Liu Q, Lang J P. Coord. Chem. Rev., 2015,293-294:187-210

    5. [5]

      [5] Lang J P, Xu Q F, Abrahams B F, et al. J. Am. Chem. Soc., 2003,125:12682-12683

    6. [6]

      [6] Berlinguette C P, Holm R H. J. Am. Chem. Soc., 2006,128:11993-12000

    7. [7]

      [7] Chen X, Li H X, Zhang Z Y, et al. Chem. Commun., 2012, 48:4480-4482

    8. [8]

      [8] Ohki Y, Sakamoto M, Tatsumi K. J. Am. Chem. Soc., 2008, 130:11610-11611

    9. [9]

      [9] Zhang W H, Song Y L, Zhang Y. Cryst. Growth Des., 2008, 8:253-258

    10. [10]

      [10] Hong M C, Cao R, Kawaguchi H, et al. Inorg. Chem., 2002, 41:4824-4833

    11. [11]

      [11] Song L, Li J R, Lin P, et al. Inorg. Chem., 2006,45:10155-10161

    12. [12]

      [12] Lang J P, Xu Q F, Abrahams B F, et al. Angew. Chem. Int. Ed., 2004,43:4741-4745

    13. [13]

      [13] Zhang W H, Song Y L, Ren Z G, et al. Inorg. Chem., 2007, 46:6647-6660

    14. [14]

      [14] Lang J P, Zhou W Y, Xin X Q, et al. J. Coord. Chem., 1993, 30:173-182

    15. [15]

      [15] Lang J P, Bian G Q, Cai, J H, et al. Transition Met. Chem., 1995,20:376-379

    16. [16]

      [16] Sheldrick G M. SHELXS-97 and SHELXL-97, Program for X-ray Crystal Structure Solution, University of Göttingen, Göttingen, Germany, 1997.

    17. [17]

      [17] Hou H W, Ang H G, Ang S G, et al. Inorg. Chim. Acta, 2000,299:147-154

    18. [18]

      [18] Zhou J L, Li Y Z, Zheng H G, et al. Transition Met. Chem., 2004,29:185

    19. [19]

      [19] Clegg W, Garner C D, Nichlson J R, et al. Acta Crystallogr., Sect. C, 1983,39:1007-1009

    20. [20]

      [20] Müller A, Bgge H, Schimanski U. Inorg. Chim. Acta, 1983, 69:5-16

    21. [21]

      [21] Hou H W, Fan Y T, Du C X, et al. Chem. Commun., 1999:647-648

    22. [22]

      [22] Müller A, Krickemeyer E, Hildebrand A, et al. Chem. Commun., 1991:1685-1687

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