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Citation: LIU Quan, CHEN Qiu-Fang, YU Hong, ZHAO Xin, ZHANG Wen-Hua, LANG Jian-Ping. Two One-Dimensional [MS4Cu4]-Supported Coordination Polymers: Assembly and Crystal Structures of {[MS4Cu4(bpe)2(ani)2I2]·3.5ani}n (M=Mo, W; ani=aniline)[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(9): 1805-1810. doi: 10.11862/CJIC.2015.237 shu

Two One-Dimensional [MS4Cu4]-Supported Coordination Polymers: Assembly and Crystal Structures of {[MS4Cu4(bpe)2(ani)2I2]·3.5ani}n (M=Mo, W; ani=aniline)

  • 1.

    1. College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China;

  • 2.

    2. College of Chemistry and Chemical Engineering, Nantong University, Nantong, Jiangsu 226019, China

  • Corresponding author: LANG Jian-Ping, 
  • Received Date: 24 May 2015
    Available Online: 4 June 2015

    Fund Project: 国家自然科学基金(No.21373142,21371126)资助项目。 (No.21373142,21371126)

  • Reactions of the preformed cluster precursors [Et4N]4[MS4Cu4I6] (M=Mo (1a); W (1b)) with a ditopic bridging ligand 1, 2-bis(4-pyridyl)ethane (bpe) in aniline solutions gave rise to two analogous one-dimensional cluster-supported coordination polymers {[MS4Cu4(bpe)2(ani)2I2]·3.5ani}n (M=Mo (2), W (3); ani=aniline). Both 2 and 3 are characterized by elemental analysis, IR spectra, and single crystal X-ray diffraction. X-ray analyses revealed that the pentanuclear saddle-shaped [MS4Cu4] cores in 1a and 1b are retained in 2 and 3. The adjacent [MS4Cu4] cores are interconnected by double bpe bridges to afford one-dimensional zigzag chains extending along the [111] direction.
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