Citation: WU Jian-Feng, ZHANG Hai-Xia, ZHANG Peng, ZHAO Lang, TANG Jin-Kui. Magnetic Relaxation in 1D and 2D Dysprosium(Ⅲ) Coordination Polymers[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(9): 1847-1854. doi: 10.11862/CJIC.2015.236 shu

Magnetic Relaxation in 1D and 2D Dysprosium(Ⅲ) Coordination Polymers

1.
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Corresponding author: TANG Jin-Kui,
Received Date: 29 May 2015
Available Online: 13 July 2015
Fund Project: 国家自然科学基金(No.21371166)资助项目。 (No.21371166)

Two dysprosium complexes, [Dy₂(OAc)₆H₂O]_n (1) and {[DyL(H₂O)₄]ClO₄·H₂O}_n (2) (L=2, 2'-dithiobis(3-pyridinecarboxylic acid)), were synthesized and structurally and magnetically characterized. Complex 1 is a 1D dysprosium chain, in which the dysprosium ions are bridged by OAc^- anions, exhibiting slow magnetic relaxation behavior with an energy barrier of 2 K. Complex 2 is a 2D dysprosium network, in which the carboxylato-bridged dysprosium chains are linked by disulfide bonds, showing ferromagnetic interaction and slow magnetic relaxation.
- slow magnetic relaxation;ferromagnetic interaction;disulphide bond
1. [1]
  [1] Zhang P, Guo Y N, Tang J. Coord. Chem. Rev., 2013,257:1728-1763
2. [2]
  [2] Gatteschi D, Sessoli R, Villain J. Molecular Nanomagnets. Oxford:Oxford University Press, 2006.
3. [3]
  [3] Zhang P, Zhang L, Tang J. Dalton Trans., 2015,44:3923-3929
4. [4]
  [4] Stipe B C, Strand T C, Poon C C, et al. Nat. Photonics, 2010,4:484-488
5. [5]
  [5] Zhang P, Tang J. Lanthanide Single Molecule Magnets. Heidelberg:Springer, 2015.
6. [6]
  [6] LIN Shuang-Yan(林双燕), GUO Yun-Nan(郭云南), TANG Jin-Kui(唐金魁), et al. Chinese J. Appl. Chem.(应用化学), 2010,27(12):1365-1371
7. [7]
  [7] Blagg R J, Muryn C A, McInnes E J, et al. Angew. Chem. Int. Ed., 2011,50:6530-6533
8. [8]
  [8] Blagg R J, Ungur L, Tuna F, et al. Nat. Chem., 2013,5:673-678
9. [9]
  [9] Liu J L, Wu J Y, Chen Y C, et al. Angew. Chem. Int. Ed., 2014,53:12966-12970
10. [10]
  [10] Lin S Y, Wernsdorfer W, Ungur L, et al. Angew. Chem. Int. Ed., 2012,51:12767-12771
11. [11]
  [11] Tang J, Hewitt I, Madhu N T, et al. Angew. Chem. Int. Ed., 2006,45:1729-1733
12. [12]
  [12] Guo Y N, Xu G F, Wernsdorfer W, et al. J. Am. Chem. Soc., 2011,133:11948-11951
13. [13]
  [13] Zhang P, Zhang L, Wang C, et al. J. Am. Chem. Soc., 2014, 136:4484-4487
14. [14]
  [14] Guo Y N, Ungur L, Granroth G E, et al. Sci. Rep., 2014,4:5471
15. [15]
  [15] Rinehart J D, Fang M, Evans W J, et al. J. Am. Chem. Soc., 2011,133:14236-14239
16. [16]
  [16] Joseph M Z, Dianne J X, Mihail Atanasov, et al. Nat. Chem., 2013,5:577-581
17. [17]
  [17] Rinehart J D, Fang M, Evans W J, et al. Nat. Chem., 2011,3:538-542
18. [18]
  [18] Ishikawa N, Sugita M, Ishikawa T, et al. J. Am. Chem. Soc., 2003,125:8694-8695
19. [19]
  [19] Ganivet C R, Ballesteros B, de la Torre G, et al. Chem. Eur. J., 2013,19:1457-1465
20. [20]
  [20] Woodruff D N, Winpenny R E P, Layfield R A. Chem. Rev., 2013,113:5110-5148
21. [21]
  [21] Dechambenoit P, Long J R. Chem. Soc. Rev., 2011,40:3249-3265
22. [22]
  [22] Bogani L, Sangregorio C, Sessoli R, Gatteschi D. Angew. Chem. Int. Ed., 2005,44:5817-5821
23. [23]
  [23] Jia L, Chen Q, Meng Y S, et al. Chem. Commun., 2014,50:6052-6055
24. [24]
  [24] Pejo C, Guedes G P, Novak M A, et al. Chem. Eur. J., 2015,21:8696-8700
25. [25]
  [25] Shao D, Zhang S L, Zhao X H, et al. Chem. Commun., 2015, 51:4360-4363
26. [26]
  [26] Caneschi A, Gatteschi D, Lalioti N, et al. Angew. Chem. Int. Ed., 2001,40:1760-1763
27. [27]
  [27] Norio I, Yoshitomo O, Susumu C, et al. J. Am. Chem. Soc., 2008,130:24-25
28. [28]
  [28] Feng X, Harris T D, Long J R. Chem. Sci., 2011,2:1688-1694
29. [29]
  [29] Zhang Y Z, Zhao H H, Funck E, et al. Angew. Chem. Int. Ed., 2015,54:5583-5587
30. [30]
  [30] Sheldrick G M. SHELXS-97, Program for Crystal Structure Solution, University of Göttingen:Germany, 1997.
31. [31]
  [31] Boudreaux E A, Mulay L N. Theory and Applications of Molecular Paramagnetism. New York:John Wiley & Sons, 1976.
32. [32]
  [32] Kahn O. Molecular Magnetism. New York:VCH, 1993.
33. [33]
  [33] Xu G F, Wang Q L, Gamez P, et al. Chem. Commun., 2010, 46:1506-1508
34. [34]
  [34] Leuenberger M N, Loss D. Nature, 2001,410:789-793
35. [35]
  [35] Plokhov D I, Popov A I, Zvezdin A K. Phys. Rev. B, 2011, 84:224436
36. [36]
  [36] Wernsdorfer W, Sessoli R. Science, 1999,284:133-135
37. [37]
  [37] Bartolomé J, Filoti G, Kuncser V, et al. Phys. Rev. B, 2009, 80:014430
38. [38]
  [38] Lin S Y, Xu G F, Zhao L, et al. Dalton Trans., 2011,40:8213-8217
1. [1]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
2. [2]
  Linhan Tian , Changsheng Lu . Discussion on Sextuple Bonding in Diatomic Motifs of Chromium Family Elements. University Chemistry, 2024, 39(8): 395-402. doi: 10.3866/PKU.DXHX202401056
3. [3]
  Xiuyun Wang , Jiashuo Cheng , Yiming Wang , Haoyu Wu , Yan Su , Yuzhuo Gao , Xiaoyu Liu , Mingyu Zhao , Chunyan Wang , Miao Cui , Wenfeng Jiang . Improvement of Sodium Ferric Ethylenediaminetetraacetate (NaFeEDTA) Iron Supplement Preparation Experiment. University Chemistry, 2024, 39(2): 340-346. doi: 10.3866/PKU.DXHX202308067
4. [4]
  Jianfeng Yan , Yating Xiao , Xin Zuo , Caixia Lin , Yaofeng Yuan . Comprehensive Chemistry Experimental Design of Ferrocenylphenyl Derivatives. University Chemistry, 2024, 39(4): 329-337. doi: 10.3866/PKU.DXHX202310005
5. [5]
  Baohua LÜ , Yuzhen LI . Anisotropic photoresponse of two-dimensional layered α-In₂Se₃(2H) ferroelectric materials. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1911-1918. doi: 10.11862/CJIC.20240105
6. [6]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
7. [7]
  Hongyao Li , Youyan Liu , Luwei Dai , Min Yang , Qihui Wang . The Blessing of Indium Sulfide：Confronting the Narrow Path with Uric Acid. University Chemistry, 2024, 39(5): 325-335. doi: 10.3866/PKU.DXHX202311104
8. [8]
  Rui Li , Jiayu Zhang , Anyang Li . Two Levels of Understanding of Chemical Bonds: a Case of the Bonding Model of Hypervalent Molecules. University Chemistry, 2024, 39(2): 392-398. doi: 10.3866/PKU.DXHX202308051
9. [9]
  Danqing Wu , Jiajun Liu , Tianyu Li , Dazhen Xu , Zhiwei Miao . Research Progress on the Simultaneous Construction of C—O and C—X Bonds via 1,2-Difunctionalization of Olefins through Radical Pathways. University Chemistry, 2024, 39(11): 146-157. doi: 10.12461/PKU.DXHX202403087
10. [10]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
11. [11]
  Jinyao Du , Xingchao Zang , Ningning Xu , Yongjun Liu , Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039
12. [12]
  Jiaqi AN , Yunle LIU , Jianxuan SHANG , Yan GUO , Ce LIU , Fanlong ZENG , Anyang LI , Wenyuan WANG . Reactivity of extremely bulky silylaminogermylene chloride and bonding analysis of a cubic tetragermylene. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1511-1518. doi: 10.11862/CJIC.20240072
13. [13]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
14. [14]
  Hong CAI , Jiewen WU , Jingyun LI , Lixian CHEN , Siqi XIAO , Dan LI . Synthesis of a zinc-cobalt bimetallic adenine metal-organic framework for the recognition of sulfur-containing amino acids. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 114-122. doi: 10.11862/CJIC.20240382
15. [15]
  Min LIU , Huapeng RUAN , Zhongtao FENG , Xue DONG , Haiyan CUI , Xinping WANG . Neutral boron-containing radical dimers. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 123-130. doi: 10.11862/CJIC.20240362
16. [16]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
17. [17]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
18. [18]
  Tong Zhou , Liyi Xie , Chuyu Liu , Xiyan Zheng , Bao Li . Between Sobriety and Intoxication: The Fascinating Journey of Sauce-Flavored Latte. University Chemistry, 2024, 39(9): 55-58. doi: 10.12461/PKU.DXHX202312048
19. [19]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
20. [20]
  Qingjun PAN , Zhongliang GONG , Yuwu ZHONG . Advances in modulation of the excited states of photofunctional iron complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 45-58. doi: 10.11862/CJIC.20240365

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(803)
HTML views(125)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142