Citation: LI Xiao-Jing, CAI Hong-Xin, WU Wei-Na, HOU Ying, WANG Zhen. Cu(Ⅱ) and Zn(Ⅱ) Complexes with an Acylhydrazone Derived from 4-Methyl Salicylic Hydrazide and PMBP: Crystal Structures and Fluorescence Property of Zn(Ⅱ) Complex[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1661-1666. doi: 10.11862/CJIC.2015.228 shu

Cu(Ⅱ) and Zn(Ⅱ) Complexes with an Acylhydrazone Derived from 4-Methyl Salicylic Hydrazide and PMBP: Crystal Structures and Fluorescence Property of Zn(Ⅱ) Complex

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Department of Physics and Chemistry, Henan Polytechnic University, Jiaozuo, Henan 454000, China

Corresponding author: CAI Hong-Xin, WU Wei-Na,
Received Date: 10 April 2015
Available Online: 2 June 2015
Fund Project: 国家自然科学基金(No.21001040, 21404033, 21401046) (No.21001040, 21404033, 21401046) 河南省教育厅自然科学基金(No.12B150011, 14B150029)资助。 (No.12B150011, 14B150029)

Two complexes [(Cu)(L)(Cl)]·0.5EtOH·1.5H₂O and {[Zn(L)(NO₃)]·2CH₃CN}_n (HL is the acylhydrazone ligand derived from 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone (PMBP) and 4-methyl salicylic hydrazide) have been synthesized and characterized by single-crystal X-ray diffraction, elemental analysis and IR spectroscopy. X-ray diffraction analysis results show that the coordination geometry of the Cu(Ⅱ) ion in 1 is a distorted square planar geometry with nitrogen and two oxygen atoms provided by the enolizated ligand L^-1 and one chloride anion. However, in complex 2, the Zn(Ⅱ) ion with a distorted trigonal biyramid coordination geometry is five-coordinated, involving one nitrate anion, one NO₂ donor set of an enolizated ligand L^- and one pyrazoline nitrogen atom from another adjacent acylhydrazone ligand, thus forming one dimension chain-like framework along b axis. When excited at 310 nm, complex 2 exhibits two strong emissions at 434 and 459 nm, while the ligand shows relatively weak emission at 521 nm. In addition, luminescent decay data show that the mean lifetime τ are 7.352 8 and 7.755 6 μs for HL and complex 2, respectively. CCDC: 1058420, HL·0.5EtOH; 1058421, 1; 1058422, 2.
- hydrazone;Zn(Ⅱ) complex;Cu(Ⅱ) complex;fluorescence;crystal structure
1. [1]
  [1] HUANG Chao(黄超), WU Juan(吴娟), CHEN Dong-Mei (陈冬梅), et al. Chinese J. Inorg. Chem. (无机化学学报), 2015,31:109-113
2. [2]
  [2] CHEN Yan-Min(陈延民), XIE Qin-Fan(解庆范), LIU Jin-Hua(刘金花), et al. Chinese J. Inorg. Chem. (无机化学学报), 2015,31:74-80
3. [3]
  [3] CHEN Yan-Min(陈延民), CHU Zhao-Hua(储召华), HAO Gui-Xia(郝桂霞), et al. Chinese J. Inorg. Chem. (无机化学学报), 2015,31:317-322
4. [4]
  [4] ZHUO Xin(卓馨), PAN Zhao-Rui (潘兆瑞), WANG Zuo-Wei (王作为), et al. Chinese J. Inorg. Chem. (无机化学学报), 2006,22:1847-1851
5. [5]
  [5] LI Shi-Xiong (李石雄), LIAO Bei-Ling(廖蓓玲), LUO Pei (罗培), et al. Chinese J. Inorg. Chem. (无机化学学报), 2015,31:291-296
6. [6]
  [6] Yang Z Y, Yang R D, Li F S, et al. Polyhedron, 2000,19:2599-2604
7. [7]
  [7] Yang Z Y, Wang B D, Li Y H. J. Organomet. Chem., 2006, 691:4159-4166
8. [8]
  [8] Wang Y, Yang Z Y. Transition Met. Chem., 2005,30:902-906
9. [9]
  [9] Wang Y, Yang Z Y. J. Lumin., 2008,128:373-376
10. [10]
  [10] ZHANG Shu-Ming (张姝明), LI Pei-Fan(李培凡), YU Ming (郁铭), et al. Chinese J. Inorg. Chem. (无机化学学报), 2004,20:439-443
11. [11]
  [11] Zhou X Y, Li P X, Shi Z H, et al. Inorg. Chem., 2012,51:9226-9231
12. [12]
  [12] Wu Z K, Chen Q Q, Yang G Q, et al. Sens. Actuators B., 2004,99:511-515
13. [13]
  [13] Zhang G Q, Yang G Q, Zhu L N, et al. Sens. Actuators B., 2006,114:995-1000
14. [14]
  [14] Sali S, Grabchev I, Chovelon J M, et al. Spectrochim. Acta A, 2006,65:591-597
15. [15]
  [15] Kulatilleke C P, Silva S A, Eliav Y. Polyhedron, 2006,25:2593-2596
16. [16]
  [16] Sheldrick G M. SADABS, University of Göttingen, Germany, 1996.
17. [17]
  [17] Sheldrick G M. SHELX-97, Program for the Solution and the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
18. [18]
  [18] Addison A W, Rao T N. J. Chem. Soc. Dalton Trans., 1984,1349-1356
19. [19]
  [19] CHENG Mei-Ling(程美令), CAO Xiang-Qian(曹向前), WANG Chun-Lan(王春兰), et al. Chinese J. Inorg. Chem. (无机化学学报), 2006,22:1222-1226
20. [20]
  [20] Vicente M, Bastida R, Lodeiro C, et al. Inorg. Chem., 2003,42:6768-6779
21. [21]
  [21] Buddhudu S, Morita M, Murakami S, et al. J. Lumin., 1999,83-84:199-203
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