Citation: LI Xiao-Jing, CAI Hong-Xin, WU Wei-Na, HOU Ying, WANG Zhen. Cu(Ⅱ) and Zn(Ⅱ) Complexes with an Acylhydrazone Derived from 4-Methyl Salicylic Hydrazide and PMBP: Crystal Structures and Fluorescence Property of Zn(Ⅱ) Complex[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1661-1666. doi: 10.11862/CJIC.2015.228 shu

Cu(Ⅱ) and Zn(Ⅱ) Complexes with an Acylhydrazone Derived from 4-Methyl Salicylic Hydrazide and PMBP: Crystal Structures and Fluorescence Property of Zn(Ⅱ) Complex

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Department of Physics and Chemistry, Henan Polytechnic University, Jiaozuo, Henan 454000, China

Corresponding author: CAI Hong-Xin, WU Wei-Na,
Received Date: 10 April 2015
Available Online: 2 June 2015
Fund Project: 国家自然科学基金(No.21001040, 21404033, 21401046) (No.21001040, 21404033, 21401046) 河南省教育厅自然科学基金(No.12B150011, 14B150029)资助。 (No.12B150011, 14B150029)

Two complexes [(Cu)(L)(Cl)]·0.5EtOH·1.5H₂O and {[Zn(L)(NO₃)]·2CH₃CN}_n (HL is the acylhydrazone ligand derived from 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone (PMBP) and 4-methyl salicylic hydrazide) have been synthesized and characterized by single-crystal X-ray diffraction, elemental analysis and IR spectroscopy. X-ray diffraction analysis results show that the coordination geometry of the Cu(Ⅱ) ion in 1 is a distorted square planar geometry with nitrogen and two oxygen atoms provided by the enolizated ligand L^-1 and one chloride anion. However, in complex 2, the Zn(Ⅱ) ion with a distorted trigonal biyramid coordination geometry is five-coordinated, involving one nitrate anion, one NO₂ donor set of an enolizated ligand L^- and one pyrazoline nitrogen atom from another adjacent acylhydrazone ligand, thus forming one dimension chain-like framework along b axis. When excited at 310 nm, complex 2 exhibits two strong emissions at 434 and 459 nm, while the ligand shows relatively weak emission at 521 nm. In addition, luminescent decay data show that the mean lifetime τ are 7.352 8 and 7.755 6 μs for HL and complex 2, respectively. CCDC: 1058420, HL·0.5EtOH; 1058421, 1; 1058422, 2.
- hydrazone;Zn(Ⅱ) complex;Cu(Ⅱ) complex;fluorescence;crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142