Citation: ZHANG Hai-Ming, ZHANG Hao-Ran, LIU Ying-Liang, DONG Han-Wu, HUANG Jia-Feng, CHEN Shu-Yi, LEI Bing-Fu. Temperature Dependence of Silica Coated CaAl₁₂O₁₉:Mn⁴⁺ Phosphor[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1489-1494. doi: 10.11862/CJIC.2015.224 shu

Temperature Dependence of Silica Coated CaAl₁₂O₁₉:Mn⁴⁺ Phosphor

1.
Department of Materials Science and Engineering, College of Materials and Energy, Guangdong Provincial Engineering Technology Research Center for Optical Agriculture, South China Agricultural University, Guangzhou 510642, China

Corresponding author: LIU Ying-Liang, LEI Bing-Fu,
Received Date: 22 September 2014
Available Online: 9 July 2015
Fund Project: 国家自然科学基金项目(No.21171071,21371062) (No.21171071,21371062)广东省自然科学基金团队项目(No.S2013030012842)资助。 (No.S2013030012842)

The CaAl₁₂O₁₉:Mn⁴⁺ phosphors coated with amorphous SiO₂ were prepared by means of sol-gel method and were characterized by XRD, TEM, EDS, FTIR and photoluminescence spectra. The X-ray diffraction results showed that the as-prepared powders appeared an amorphous silica feature wide peak around 22° which showing increasing intensity with increasing amount of coated SiO₂. FTIR analysis found obvious Si-O-Si band of coated samples. The TEM demonstrated that the particle size was about 3~6 μm. After coated, the intensity of excitation and emission spectrum were reduced. It showed that the photostability of the 10% silica coated sample can be effectively improved with minimum loss of emission intensity. The temperature-dependent emission spectra of 50% silica coated and the uncoated samples were investigated from 80 to 400 K, the results found that an anti-quenching phenomenon that the emission intensities increased then decreased at increased temperature, and the coated samples has higher thermal activation energy compared with uncoated sample.
- sol-gel method;silica coated;CaAl₁₂O₁₉:Mn⁴⁺;temperature dependence
1. [1]
  [1] WANG Sheng-Xue(王声学), WU Guang-Ning(吴广宁), JIANG Wei(蒋伟), et al. Light and Lighting(灯与照明), 2006,30(4):32-35
2. [2]
  [2] ZHANG Kai(张凯), LIU He-Zhou(刘河洲). Mater. Rev.(材料导报), 2005,19(9):50-53
3. [3]
  [3] JING Yan-Jun(井艳军), ZHU Xian-Zhong(朱宪忠), WANG Hai-Bo(王海波), et al. Adv. Mater. Ind.(新材料产业), 2007(2):67-70
4. [4]
  [4] YIN Yan(印琰), YANG Bao-Dong(杨宝东), ZHU Yue-Hua (朱月华), et al. China Light and Lighting(中国照明电器), 2009(3):6-10
5. [5]
  [5] ZENG Qi-Hua(曾琦华), ZHANG Xin-Guo(张信果), LIANG Hong-Bin(梁宏斌), et al. J. Chinese Rare Earth Soc.(中国稀土学报), 2011,29(1):8-17
6. [6]
  [6] HAN Jun-Yi(韩俊义), DUAN Qing-Wen(段庆文). Mater. China(中国材料进展), 2011,30(3):36-46
7. [7]
  [7] Bergstein A, White W B. J. Electrochem. Soc., 1971,118(7):1166-1171
8. [8]
  [8] Murata T, Tanoue T, Iwasaki M, et al. J. Lumin., 2005,114(34):207-212
9. [9]
  [9] Pan Y X, Liu G K. Opt. Lett., 2008,33(16):1816-1818
10. [10]
  [10] YU Sheng-Fei(喻胜飞), PI Pei-Hui(皮丕辉), WEN Xiu-Fang(文秀芳), et al. Rare Metal Mater. Eng.(稀有金属材料与工程), 2008,10:1876-1880
11. [11]
  [11] CHU Ming-Hui(褚明辉), LIU Xue-Yan(刘学彦), WU Qing (吴庆), et al. Chinese J. Inorg. Chem.(无机化学学报), 2010,26(2):183-189
12. [12]
  [12] LIAO Hui-Wei(廖辉伟). New Technol. New Proc.(新技术新工艺), 2004(4):45-47
13. [13]
  [13] Gaudet M, Camart J, Buchaillot L, et al. Appl. Phys. Lett., 2006,88(2):0241071-0241073
14. [14]
  [14] Jung I, Cho Y, Lee S, et al. Appl. Phys. Lett., 2005,87(19):1919081-1919083
15. [15]
  [15] SU Qiang(苏锵). Rare Earth Chemistry(稀土化学). Zhengzhou:Henan Science and Technology Press, 1993:13-28
16. [16]
  [16] Kim J, Park Y, Kim S, et al. Solid State Commun., 2005, 133:445-448
1. [1]
  Yan ZHAO , Jiaxu WANG , Zhonghu LI , Changli LIU , Xingsheng ZHAO , Hengwei ZHOU , Xiaokang JIANG . Gd³⁺-doped Sc₂W3O₁₂: Eu³⁺ red phosphor: Preparation and luminescence performance. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 461-468. doi: 10.11862/CJIC.20240316
2. [2]
  Ruifeng CHEN , Chao XU , Jianting JIANG , Tianshe YANG . Gold nanorod/zinc oxide/mesoporous silica nanoplatform: A triple-modal platform for synergistic anticancer therapy. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2272-2282. doi: 10.11862/CJIC.20250117
3. [3]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
4. [4]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
5. [5]
  Qiang Zhang , Yuanbiao Huang , Rong Cao . Imidazolium-Based Materials for CO₂ Electroreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306040-0. doi: 10.3866/PKU.WHXB202306040
6. [6]
  Yanhui Guo , Li Wei , Zhonglin Wen , Chaorong Qi , Huanfeng Jiang . Recent Progress on Conversion of Carbon Dioxide into Carbamates. Acta Physico-Chimica Sinica, 2024, 40(4): 2307004-0. doi: 10.3866/PKU.WHXB202307004
7. [7]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029
8. [8]
  Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398
9. [9]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
10. [10]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
11. [11]
  Jianan Hong , Chenyu Xu , Yan Liu , Changqi Li , Menglin Wang , Yanwei Zhang . Decoding the interfacial competition between hydrogen evolution and CO₂ reduction via edge-active-site modulation in photothermal catalysis. Acta Physico-Chimica Sinica, 2025, 41(9): 100099-0. doi: 10.1016/j.actphy.2025.100099
12. [12]
  Bizhu Shao , Huijun Dong , Yunnan Gong , Jianhua Mei , Fengshi Cai , Jinbiao Liu , Dichang Zhong , Tongbu Lu . Metal-Organic Framework-Derived Nickel Nanoparticles for Efficient CO₂ Electroreduction in Wide Potential Windows. Acta Physico-Chimica Sinica, 2024, 40(4): 2305026-0. doi: 10.3866/PKU.WHXB202305026
13. [13]
  Yan Kong , Wei Wei , Lekai Xu , Chen Chen . Electrochemical Synthesis of Organonitrogen Compounds from N-integrated CO₂ Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2307049-0. doi: 10.3866/PKU.WHXB202307049
14. [14]
  Xiaofei Liu , He Wang , Li Tao , Weimin Ren , Xiaobing Lu , Wenzhen Zhang . Electrocarboxylation of Benzylic Phosphates and Phosphinates with Carbon Dioxide. Acta Physico-Chimica Sinica, 2024, 40(9): 2307008-0. doi: 10.3866/PKU.WHXB202307008
15. [15]
  Jiayin Hu , Yafei Guo , Long Li , Tianlong Deng . Teaching Innovation of Salt-Water System Phase Diagrams under the “Dual Carbon” Background: Introducing the Pressurized CO₂ Carbonization Phase Equilibria. University Chemistry, 2025, 40(11): 31-36. doi: 10.12461/PKU.DXHX202412031
16. [16]
  Débora Ferreira dos Santos Morais , José Luis Tirado , Carlos Pérez-Vicente , Fabiana Villela da Motta , Pedro Lavela , Mauricio Bomio , Sergio Lavela . Unlocking the performance of sodium-ion batteries by coating Na₃V₂(PO₄)₃ with Nb₂O₅. Acta Physico-Chimica Sinica, 2026, 42(2): 100180-0. doi: 10.1016/j.actphy.2025.100180
17. [17]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
18. [18]
  Wei HE , Jing XI , Tianpei HE , Na CHEN , Quan YUAN . Application of solar-driven inorganic semiconductor-microbe hybrids in carbon dioxide fixation and biomanufacturing. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 35-44. doi: 10.11862/CJIC.20240364
19. [19]
  Hui-Ying Chen , Hao-Lin Zhu , Pei-Qin Liao , Xiao-Ming Chen . Integration of Ru(Ⅱ)-Bipyridyl and Zinc(Ⅱ)-Porphyrin Moieties in a Metal-Organic Framework for Efficient Overall CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306046-0. doi: 10.3866/PKU.WHXB202306046
20. [20]
  Haoran Zhang , Yaxin Jin , Peng Kang , Sheng Zhang . The Convergence and Innovative Application of Artificial Intelligence in Scientific Research: A Case Study of Electrocatalytic Carbon Dioxide Reduction in the Context of the Dual-Carbon Strategy. University Chemistry, 2025, 40(9): 148-155. doi: 10.12461/PKU.DXHX202412099

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(590)
HTML views(91)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Temperature Dependence of Silica Coated CaAl12O19:Mn4+ Phosphor

Metrics

通讯作者: 陈斌, bchen63@163.com

Temperature Dependence of Silica Coated CaAl₁₂O₁₉:Mn⁴⁺ Phosphor