Citation: ZHOU Lian, TIE Sheng-Nian, WANG Zhi-Guo. Syntheses, Crystal Structures and Properties of Coordination Polymers Built from a Semi-rigid Tripod Carboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1480-1488. doi: 10.11862/CJIC.2015.221 shu

Syntheses, Crystal Structures and Properties of Coordination Polymers Built from a Semi-rigid Tripod Carboxylic Acid

1.
New Energy(Photovoltaic) Industry Research Center, Qinghai University, Xining 810006, China

Corresponding author: ZHOU Lian,
Received Date: 26 March 2015
Available Online: 9 June 2015
Fund Project: 国家自然科学基金项目(No.51463019) (No.51463019)青海省重点实验室发展专项资金(No.2014-Z-Y31) (No.2014-Z-Y31)

By using a semi-rigid multidentate carboxylate linker 3,3',3"-(((2,4,6-trimethylbenzene-1,3,5-triyl)tris(methylene))tris(oxy))tribenzoic acid (H₃L), four coordination polymers, namely, {[Cd₃(L)₂(H₂O)₂]·5DMF·6H₂O}_n (1), {[Co₃(L)₂(H₂O)₂]·2DMF·6H₂O}_n (2), {[Mn₃(L)₂(H₂O)₂]·3DMF·6H₂O}_n (3), {[Zn₃(L)₂(H₂O)₂]·5DMA·5H₂O}_n (4) were obtained and characterized by single crystal X-ray diffraction, thermogravimetric, elemental analysis, thermal analyses, IR spectra and fluorescence. Four compounds are isostructural with hourglass M₃ clusters and L^3- ligands as secondary building units (SBUs) to form a pumpkin-shaped metalorganic nanocage, and possess a three-connected node (3,3,6)-connected 3D network. Compounds 1 and 4 exhibited strong photoluminescent emissions at room temperature with a peak at 385 nm, owing to a ligand-centered excited state. The emission intensities of the compound 1 varied upon contact with different solvents or analytes, exhibiting selective emission quenching responses towards nitroaromatics. CCDC: 1041419, 1; 1041420, 2; 1041421, 2; 1041422, 4.
- coordination polymer;semi-rigid carboxylate linker;crystal structure;luminescence
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沈阳化工大学材料科学与工程学院沈阳 110142