Citation: WU Di, YU Zhu, GAO Da-Zhi, WANG Xin, SHEN Xuan, ZHU Dun-Ru. A Mixed-Bridged Linear Trinuclear Copper(Ⅱ) Complex Containing Both Square Pyramidal and Trigonal Bipyramidal Configuration[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1619-1625. doi: 10.11862/CJIC.2015.220
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A novel trinuclear copper(Ⅱ) complex, [Cu3L2(py)](ClO4)2·2THF (1) (H2L=(E)-3-[N,N-di(2-pyridylmethyl)aminomethyl]-2-hydroxyl-5-methylbenzaldehyde oxime, py=pyridine, THF=tetrahydrofuran), has been successfully synthesized and characterized. 1 crystallizes in monoclinic system with space group C2/c, a=2.969 0(7) nm, b=1.302 8(3) nm, c=2.057 4(9) nm, β=132.435(2)°, V=5.873(3) nm3, Z=4 with final R1=0.047 9. X-ray crystallography analysis reveals that 1 is a mixed-bridged (-N-O-/μ2-O-) linear tricopper(Ⅱ) complex with all the copper cations being five-coordinated by three N and two O atoms: the central Cu(Ⅱ) in a distorted trigonal bipyramidal configuration, whereas the peripheral Cu(Ⅱ) in a distorted square pyramidal arrangement. Magnetic susceptibility measurement indicates that there is a medium antiferromagnetic exchange coupling between the Cu(Ⅱ) ions with a J value of -33.3(5) cm-1. CCDC: 916132.
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-
[1]
[1] Rivera-Carrillo M, Chakraborty I, Mezei G, et al. Inorg. Chem., 2008,47:7644-7650
-
[2]
[2] Yang L, Powell D R, Klein E L, et al. Inorg. Chem., 2007, 46:6831-6833
-
[3]
[3] Ávila-Torres Y, López-Sandoval H, Mijangos E, et al. Poly-hedron, 2013,51:298-306
-
[4]
[4] Nicola C D, Garau F, Gazzano M, et al. Cryst. Growth Des., 2012,12:2890-2901
-
[5]
[5] Ferrer S, Lloret F, Pardo E, et al. Inorg. Chem., 2012,51:985-1001
-
[6]
[6] Nicola C D, Forlin E, Garau F, et al. J. Organomet. Chem., 2012,714:74-80
-
[7]
[7] Qin T, Gong J, Ma J, et al. Chem. Commun., 2014,50:15886-15889
-
[8]
[8] Hasenknopf B, Lehn J M, Baum G, et al. Proc. Natl. Acad. Sci., 1996,93:1397-1340
-
[9]
[9] Zhao L, Thompson L K, Xu Z, et al. J. Chem. Soc., Dalton Trans., 2001:1706-1710
-
[10]
[10] SeppäläP, Colacio E, Mota A J, et al. Dalton Trans., 2012, 41:2648-2658
-
[11]
[11] Biswas A, Drew M G B, Gómez-García C J, et al. Inorg. Chem., 2010,49:8155-8163
-
[12]
[12] Kannan S, Pillai M R A, Droege P A, et al. Inorg. Chim. Acta, 1997,254:397-400
-
[13]
[13] Dey S, Sarkar S, Mukherjee T, et al. Inorg. Chim. Acta, 2011, 376:129-135
-
[14]
[14] Singh J, Hundal G, Corbella M, et al. Polyhedron, 2007,26:3893-3903
-
[15]
[15] Nie F M, Dong Z Y, Lu F, et al. J. Coord. Chem., 2010,63:4259-4270
-
[16]
[16] Chen X, Zhan S, Hu C, et al. J. Chem. Soc. Dalton Trans., 1997:245-250
-
[17]
[17] Gehring S, Fleischhauer P, Paulus H, et al. Inorg. Chem., 1993,32:54-60
-
[18]
[18] Jiang J, Chu Z, Huang W. Inorg. Chim. Acta, 2009,362:2933-2936
-
[19]
[19] Chen L F, Cao X Y, Li Z J, et al. Inorg. Chem. Commun., 2008,11:961-964
-
[20]
[20] Luo W, Meng X G, Xiang J F, et al. Inorg. Chim. Acta, 2008, 361:2667-2676
-
[21]
[21] Botana L, Ruiz J, Seco J M, et al. Dalton Trans., 2011,40:12462-12471
-
[22]
[22] Zhu Q, Tian C, Shen C, et al. CrystEngComm, 2013,15:2120-2126
-
[23]
[23] Silva N M L, Pinheriro C B, Chacon E P, et al. J. Braz. Chem. Soc., 2011,22:660-668
-
[24]
[24] Sheldrick G M. Acta Crystallogr., 2008,A64:112-122
-
[25]
[25] Addison A W, Rao T N, Reedijk J, et al. J. Chem. Soc. Dalton Trans., 1984:1349-1356
-
[26]
[26] Lu W, Zhu D R, Xu Y, et al. Struct. Chem., 2010,21:237-244
-
[27]
[27] CHEN Lang(陈浪), CHEN Hui-Min(程慧敏), JIANG Jing-Jing(江静静), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28:381-385
-
[28]
[28] GAO Da-Zhi(高大志), WANG Ruo-Xu(王若徐), YE Fan(叶帆), et al. Chinese J. Inorg. Chem.(无机化学学报), 2013, 29:2438-2444
-
[29]
[29] Joel T, Georgina A Á, Elia P B, et al. Spectrochim. Acta A, 2007,66:879-883
-
[30]
[30] Wang X Z, Zhu D R, Xu Y, et al. Cryst. Growth Des., 2010, 10:887-894
-
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