Citation: YUE Cui-Min, GAO Dong-Zhao, WANG Xiu-Guang. Syntheses, Crystal Structures and Properties of a Series of Helical Complexes Constructed by Flexible N,N'-Bis(3-pyridylmethyl)amine[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1609-1618. doi: 10.11862/CJIC.2015.213 shu

Syntheses, Crystal Structures and Properties of a Series of Helical Complexes Constructed by Flexible N,N'-Bis(3-pyridylmethyl)amine

1.
Tianjin Key Laboratory of Structure and Performance for Functional Molecules;Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education;College of Chemistry, Tianjin Normal University, Tianjin 300387, China

Corresponding author: GAO Dong-Zhao,
Received Date: 13 April 2015
Available Online: 28 May 2015

Five helical coordination polymers {[Cu(Hbpma)(H₂O)₄]₂(SO₄)₃·3.5H₂O}_n (1), {[Ni(Hbpma)(H₂O)₄]₄(SO₄)₆·10.75H₂O}_n (2), {[Mn(Hbpma)(H₂O)4](SO₄)_1.5·3H₂O}_n (3), {[Zn(Hbpma)(H₂O)₄]₄(SO₄)₆·4H₂O·4CH₃OH}_n (4) and {[Cu(Hbpma)2(H₂O)₂](SO₄)2·9H₂O}_n (5) (bpma=N,N'-bis(3-pyridylmethyl)amine) were synthesized and structurally char-acterized. The single-crystal X-ray analyses indicate that complexes 1~4 crystallize in the one-dimensional chain structures and complex 5 shows the two-dimensional layer structure, in which the metal ions are bridged by the protonated bpma ligands. It is noted that the flexible bpma ligands with the trans-trans conformation lead to the pseudo-helical chains for complexes 1~2, the helical chains for complexes 3~4 and a helical layer for complex 5. The magnetic properties and the thermal behavior are investigated. CCDC: 966929, 1; 966932, 2; 966930, 3; 966931, 4; 1054736, 5.
- metal complex;N,N'-bis(3-pyridylmethyl)amine;helical structure;magnetic property;thermal behavior
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沈阳化工大学材料科学与工程学院沈阳 110142