Citation: QUAN Wei-Lei, ZHANG Jin-Min, SHEN Jun-Hai, LI Liang-Chao, LI Jia-Jia. Hierarchical ZnO: Architecture, Morphological Control and Photocatalytic Activity[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1626-1636. doi: 10.11862/CJIC.2015.212 shu

Hierarchical ZnO: Architecture, Morphological Control and Photocatalytic Activity

1.
College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

Corresponding author: LI Liang-Chao,
Received Date: 21 April 2015
Available Online: 29 June 2015
Fund Project: 国家自然科学基金(No.21071125) (No.21071125)浙江省大学生科技创新计划(No.2014R404056)资助项目。 (No.2014R404056)

Under the green and mild conditions, the hierarchical ZnO was fabricated by the secondary deposition with mixed two zinc salts (zinc source), ionic liquid (surfactant). The composition, structure, morphology, photoluminescence properties and photocatalytic activity of samples were characterized by XRD, IR, SEM, UV-Vis and PL, respectively. The influential factors on sample morphology, such as surfactant, the kind of anion and temperature, were discussed. The results indicate that surfactant has a significant regulation on the morphologies of as-prepared ZnO samples. Furthermore, the anion and temperature also play a critical role in the crystal structure and morphology of ZnO. In addition, all of as-prepared hierarchical ZnO show an excellent photocatalytic activity on methyl orange under UV lamp, where the sample-1 is slightly better than others.
- ZnO;hierarchical structure;morphological control;photocatalysis
1. [1]
  [1] WANG Xin(汪信), LU Lu-De(陆路德). Chinese J. Inorg. Chem.(无机化学学报), 2000,16(2):213-217
2. [2]
  [2] Ren Y, Ma Z, Bruce P G. Chem. Soc. Rev., 2012,41(14):4909-4927
3. [3]
  [3] Lee K R, Lee J H, Yoo H I. J. Eur. Ceram. Soc., 2014,34(10):2363-2370
4. [4]
  [4] ZHENG Zhen-Miao(郑贞苗), TANG Xin-Cun(唐新村), WANG Yang(汪洋), et al. Chinese J. Inorg. Chem.(无机化学学报), 2015,31(4):731-738
5. [5]
  [5] Yuan C Z, Wu H B, Xie Y, et al. Angew. Chem. Int. Ed., 2014,53(6):1488-1504
6. [6]
  [6] XU De-Kang(徐德康), LIU Chu-Feng(刘楚枫), YAN Jia-Wei (阎佳薇), et al. Chinese J. Inorg. Chem.(无机化学学报), 2015,31(4):689-695
7. [7]
  [7] WANG Xin-Juan(王新娟), XIAO Yang(肖洋), XU Fei(徐斐), et al. Chinese J. Inorg. Chem.(无机化学学报), 2014,30(8):1821-1826
8. [8]
  [8] Sharma R K, Ghose R. Ceram. Int., 2015,41(1):967-975
9. [9]
  [9] Nevosad A, Hofstatter M, Supancic P, et al. J. Eur. Ceram. Soc., 2014,34(8):1963-1970
10. [10]
  [10] Qiu Z W, Yang X P, Han J, et al. J. Am. Ceram. Soc., 2014,97(7):2177-2184
11. [11]
  [11] Ma S S, Li P, Lu C P, et al. J. Hazard. Mater., 2011,192(2):730-740
12. [12]
  [12] Cho S, Kim S, Jung D W, et al. Nanoscale, 2011,3(9):3841-3848
13. [13]
  [13] Deng S Z, Fan H M, Wang M, et al. ACS Nano, 2010,4(1):495-505
14. [14]
  [14] Li H F, Huang Y H, Zhang Y, et al. Cryst. Growth Des., 2009,9(4):1863-1868
15. [15]
  [15] Shang T M, Sun J H, Zhou Q F, et al. Cryst. Res. Technol., 2007,42(10):1002-1006
16. [16]
  [16] Sangkhaprom N, Supaphol P, Pavarajarm V. Ceram. Int., 2010,36(1):357-363
17. [17]
  [17] Gao X F, Jiang L. Nature, 2004,432(7013):36-36
18. [18]
  [18] Lao J Y, Wen J G, Ren Z F. Nano Lett., 2002,2(11):1287-1291
19. [19]
  [19] Yang Y H, Wang B, Yang G W. Cryst. Growth Des., 2007,7(7):1242-1245
20. [20]
  [20] Liu H, Li M, Wei Y, et al. Mater. Lett., 2014,137:300-303
21. [21]
  [21] Huang Q, Cun T, Zuo W, et al. Appl. Surf. Sci., 2015,332:581-590
22. [22]
  [22] Shi R, Song X, Li J, et al. Mater. Chem. Phys., 2015,156:61-68
23. [23]
  [23] Chang G J, Lin S Y, Wu J J. Nanoscale, 2014,6(3):1329-1334
24. [24]
  [24] Kokotov M, Bar-Nachum S, Edri E, et al. J. Am. Chem. Soc., 2009,132(1):309-314
25. [25]
  [25] Mclaren A, Valdes-Solis T, Li G, et al. J. Am. Chem. Soc., 2009,131(35):12540-12541
26. [26]
  [26] Xu S, Wang Z L. Nano Res., 2011,4(11):1013-1098
27. [27]
  [27] Zhou X, Xie Z X, Jiang Z Y, et al. Chem. Commun., 2005, 44:5572-5574
28. [28]
  [28] Wang L, Chang L X, Wei L Q, et al. J. Mater. Chem., 2011, 21(39):15732-15740
29. [29]
  [29] SHEN Jun-Hai(沈俊海), LI Jia-Jia(李佳佳), LI Liang-Chao (李良超), et al. Chem. J. Chinese Universites(高等学校化学学报), 2014,35(6):1135-1141
30. [30]
  [30] Huddleston J G, Willauer H D. Chem. Commun., 1998,16:1765-1766
31. [31]
  [31] Brindaban C R, Subhash B. Org. Lett., 2005,7(14):3049-3052
32. [32]
  [32] Fernandes D M, Silva R, Hechenleitner A A, et al. Mater. Chem. Phys., 2009,115(1):110-115
33. [33]
  [33] Xing R M, Zhu J H, Liu Q W, et al. Chem. Res., 2012,23(5):57-60
34. [34]
  [34] JING Li-Qiang(井立强), YUAN Fu-Long(袁福龙), HOU Hai-Ou(侯海鸥), et al. Sci. China Ser. B:Chem.(中国科学B辑:化学), 2004,34(4):310-314
35. [35]
  [35] HOU Chun-Yan(侯春燕). Thesis for the Master of Dalian Maritime University(大连海事大学硕士论文). 2006.
1. [1]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
2. [2]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 2406012-0. doi: 10.3866/PKU.WHXB202406012
3. [3]
  Haoyu Sun , Dun Li , Yuanyuan Min , Yingying Wang , Yanyun Ma , Yiqun Zheng , Hongwen Huang . Hierarchical Palladium-Copper-Silver Porous Nanoflowers as Efficient Electrocatalysts for CO₂ Reduction to C₂₊ Products. Acta Physico-Chimica Sinica, 2024, 40(6): 2307007-0. doi: 10.3866/PKU.WHXB202307007
4. [4]
  Jiahui YU , Jixian DONG , Yutong ZHAO , Fuping ZHAO , Bo GE , Xipeng PU , Dafeng ZHANG . The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO₄:Yb³⁺,Er³⁺ photocatalyst. Journal of Fuel Chemistry and Technology, 2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1
5. [5]
  Linfeng Xiao , Wanlu Ren , Shishi Shen , Mengshan Chen , Runhua Liao , Yingtang Zhou , Xibao Li . Enhancing Photocatalytic Hydrogen Evolution through Electronic Structure and Wettability Adjustment of ZnIn₂S₄/Bi₂O₃ S-Scheme Heterojunction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308036-0. doi: 10.3866/PKU.WHXB202308036
6. [6]
  Hui Wang , Abdelkader Labidi , Menghan Ren , Feroz Shaik , Chuanyi Wang . Recent Progress of Microstructure-Regulated g-C₃N₄ in Photocatalytic NO Conversion: The Pivotal Roles of Adsorption/Activation Sites. Acta Physico-Chimica Sinica, 2025, 41(5): 100039-0. doi: 10.1016/j.actphy.2024.100039
7. [7]
  Jiatong Hu , Qiyi Wang , Ruiwen Tang , Jiajing Feng . Photocatalytic Journey of Perylene Diimides in a Competitive Arena. University Chemistry, 2025, 40(5): 328-333. doi: 10.12461/PKU.DXHX202407015
8. [8]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
9. [9]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
10. [10]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029
11. [11]
  Jingping Li , Suding Yan , Jiaxi Wu , Qiang Cheng , Kai Wang . Improving hydrogen peroxide photosynthesis over inorganic/organic S-scheme photocatalyst with LiFePO₄. Acta Physico-Chimica Sinica, 2025, 41(9): 100104-0. doi: 10.1016/j.actphy.2025.100104
12. [12]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-0. doi: 10.3866/PKU.WHXB202403009
13. [13]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-0. doi: 10.1016/j.actphy.2025.100067
14. [14]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
15. [15]
  Kexin Yan , Zhaoqi Ye , Lingtao Kong , He Li , Xue Yang , Yahong Zhang , Hongbin Zhang , Yi Tang . Seed-Induced Synthesis of Disc-Cluster Zeolite L Mesocrystals with Ultrashort c-Axis: Morphology Control, Decoupled Mechanism, and Enhanced Adsorption. Acta Physico-Chimica Sinica, 2024, 40(9): 2308019-0. doi: 10.3866/PKU.WHXB202308019
16. [16]
  Yuanqing Wang , Yusong Pan , Hongwu Zhu , Yanlei Xiang , Rong Han , Run Huang , Chao Du , Chengling Pan . Enhanced Catalytic Activity of Bi₂WO₆ for Organic Pollutants Degradation under the Synergism between Advanced Oxidative Processes and Visible Light Irradiation. Acta Physico-Chimica Sinica, 2024, 40(4): 2304050-0. doi: 10.3866/PKU.WHXB202304050
17. [17]
  Yanhui Guo , Li Wei , Zhonglin Wen , Chaorong Qi , Huanfeng Jiang . Recent Progress on Conversion of Carbon Dioxide into Carbamates. Acta Physico-Chimica Sinica, 2024, 40(4): 2307004-0. doi: 10.3866/PKU.WHXB202307004
18. [18]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d-Band Center Regulated O₂ Adsorption on Transition Metal Single Atoms Loaded COF: A DFT Study. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-0. doi: 10.3866/PKU.WHXB202407013
19. [19]
  Meihong Luo , Hongyu Wang . Teaching Reform of Benzoin Oxidation Experiment in the Context of Green Pharmaceutical Chemistry. University Chemistry, 2025, 40(5): 376-382. doi: 10.12461/PKU.DXHX202411055
20. [20]
  Xia ZHANG , Yushi BAI , Xi CHANG , Han ZHANG , Haoyu ZHANG , Liman PENG , Shushu HUANG . Preparation and photocatalytic degradation performance of rhodamine B of BiOCl/polyaniline. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 913-922. doi: 10.11862/CJIC.20240255

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(573)
HTML views(120)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142