Citation: QUAN Wei-Lei, ZHANG Jin-Min, SHEN Jun-Hai, LI Liang-Chao, LI Jia-Jia. Hierarchical ZnO: Architecture, Morphological Control and Photocatalytic Activity[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1626-1636. doi: 10.11862/CJIC.2015.212 shu

Hierarchical ZnO: Architecture, Morphological Control and Photocatalytic Activity

1.
College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

Corresponding author: LI Liang-Chao,
Received Date: 21 April 2015
Available Online: 29 June 2015
Fund Project: 国家自然科学基金(No.21071125) (No.21071125)浙江省大学生科技创新计划(No.2014R404056)资助项目。 (No.2014R404056)

Under the green and mild conditions, the hierarchical ZnO was fabricated by the secondary deposition with mixed two zinc salts (zinc source), ionic liquid (surfactant). The composition, structure, morphology, photoluminescence properties and photocatalytic activity of samples were characterized by XRD, IR, SEM, UV-Vis and PL, respectively. The influential factors on sample morphology, such as surfactant, the kind of anion and temperature, were discussed. The results indicate that surfactant has a significant regulation on the morphologies of as-prepared ZnO samples. Furthermore, the anion and temperature also play a critical role in the crystal structure and morphology of ZnO. In addition, all of as-prepared hierarchical ZnO show an excellent photocatalytic activity on methyl orange under UV lamp, where the sample-1 is slightly better than others.
- ZnO;hierarchical structure;morphological control;photocatalysis
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