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Citation: CHEN Ai-Min, WANG Jing, BO Ying-Ying, LIU Rui, GU Pei, PAN Zai-Fa, HU Jun. Synthesis, Characterization and Photoluminescence Properties of Hierarchical Mg3B2O6:Eu3+ Flower-Like Microspheres[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1548-1554. doi: 10.11862/CJIC.2015.208 shu

Synthesis, Characterization and Photoluminescence Properties of Hierarchical Mg3B2O6:Eu3+ Flower-Like Microspheres

  • 1.

    College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China

  • Corresponding author: CHEN Ai-Min,  HU Jun, 
  • Received Date: 11 March 2015
    Available Online: 3 June 2015

    Fund Project: 国家自然科学基金(No.10804099,51002137) (No.10804099,51002137)浙江省自然科学基金(No.Y4080382)资助项目。 (No.Y4080382)

  • Flower-like Mg3B2O6:Eu3+ hierarchical microspheres, with an average diameter of 2.0~2.5 μm, were successfully synthesized via a simple precipitation method using poly (vinyl pyrrolidone) as template and followed by a subsequent heat treatment. The structure, morphology, composition and photoluminescence (PL) properties of as-prepared and calcined samples were systematically characterized by XRD, SEM, TEM and PL spectra, respectively. The resultant products presented a strong characteristic of red emission at 612 nm corresponding to 5D0→7F2 of the Eu3+ transition under ultraviolet excitation at 393 nm, which may open a wide door for its applications especially in fluorescent lamps, display systems, and optoelectronic devices. Besides, we demonstrated the morphology, concentration of Eu3+ as well as calcination temperature had a great effect on the PL properties of the microspheres.
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