Advanced Search

Citation: CHEN Ai-Min, WANG Jing, BO Ying-Ying, LIU Rui, GU Pei, PAN Zai-Fa, HU Jun. Synthesis, Characterization and Photoluminescence Properties of Hierarchical Mg3B2O6:Eu3+ Flower-Like Microspheres[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1548-1554. doi: 10.11862/CJIC.2015.208 shu

Synthesis, Characterization and Photoluminescence Properties of Hierarchical Mg3B2O6:Eu3+ Flower-Like Microspheres

  • 1.

    College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China

  • Corresponding author: CHEN Ai-Min,  HU Jun, 
  • Received Date: 11 March 2015
    Available Online: 3 June 2015

    Fund Project: 国家自然科学基金(No.10804099,51002137) (No.10804099,51002137)浙江省自然科学基金(No.Y4080382)资助项目。 (No.Y4080382)

  • Flower-like Mg3B2O6:Eu3+ hierarchical microspheres, with an average diameter of 2.0~2.5 μm, were successfully synthesized via a simple precipitation method using poly (vinyl pyrrolidone) as template and followed by a subsequent heat treatment. The structure, morphology, composition and photoluminescence (PL) properties of as-prepared and calcined samples were systematically characterized by XRD, SEM, TEM and PL spectra, respectively. The resultant products presented a strong characteristic of red emission at 612 nm corresponding to 5D0→7F2 of the Eu3+ transition under ultraviolet excitation at 393 nm, which may open a wide door for its applications especially in fluorescent lamps, display systems, and optoelectronic devices. Besides, we demonstrated the morphology, concentration of Eu3+ as well as calcination temperature had a great effect on the PL properties of the microspheres.
  • 加载中
    1. [1]

      [1] Mu J S, Zhang L, Zhao M, et al. ACS Appl. Mater. Interfaces, 2014,6:7090-7098

    2. [2]

      [2] Hu J S, Zhong L S, Song W G, et al. J. Adv. Mater., 2008, 20:2977-2982

    3. [3]

      [3] Li C C, Yin X M, Wang T H, et al. Chem. Mater., 2009,21:4984-4992

    4. [4]

      [4] Chen A M, Li J, Gu P, et al. Powder Technol., 2014,267:54-60

    5. [5]

      [5] Yin S Y, Zhang Y Y, Kong J H. ACS Nano, 2011,5:3831-3838

    6. [6]

      [6] Kim P, Kreder M J, Alvarenga J, et al. Nano Lett., 2013,13:1793-1799

    7. [7]

      [7] Wei X W, Zhou X M, Wu K L, et al. CrystEngComm, 2011, 13:1328-1332

    8. [8]

      [8] Sarkar S, Pradhan M, Sinha A K, et al. Inorg. Chem., 2010, 49(19):8813-8827

    9. [9]

      [9] Singh B P, Parchur A K, Ningthoujam R S, et al. Dalton Trans., 2014,43:4779-4789

    10. [10]

      [10] Zeuner M, Hintze F, Schnick W. Chem. Mater., 2009,21:336-342

    11. [11]

      [11] Qin X P, Zhou G H, Yang H, et al. J. Alloys Compd., 2010, 493:672-677

    12. [12]

      [12] Di W H, Wang X J, Chen B J. Opt. Mater., 2005,27:1386-1390

    13. [13]

      [13] Yang J, Quan Z W, Kong D Y, et al. Cryst. Growth Des., 2007,7:730-735

    14. [14]

      [14] Pao R P. J. Electrochem. Soc., 1996,143(1):189-197

    15. [15]

      [15] Szczeszak A, Kubasiewicz K, Lis S. Opt. Mater., 2013,35:1297-1303

    16. [16]

      [16] Szczeszak A, Grzyb T, Barszcz B, et al. Inorg. Chem., 2013, 52:4934-4940

    17. [17]

      [17] Cai G M, Zheng F, Yi D Q, et al. J. Lumin., 2010,130:910-916

    18. [18]

      [18] Yang J, Li C X, Zhang X M, et al. Chem. Eur. J., 2008,14:4336-4345

    19. [19]

      [19] Jiang X C, Sun L D, Feng W, et al. Cryst. Growth Des., 2004,4(3):517-520

    20. [20]

      [20] Jia G, Zhang C M, Wang C Z, et al. CrystEngComm, 2012, 14:579-584

    21. [21]

      [21] Dwivedi Y, Rai D K, Rai S B. Opt. Mater., 2010,32:913-919

    22. [22]

      [22] WU Yan-Li(吴燕利), XU Xian-Zhu(徐贤柱), WEN Jia(文佳), et al. Chinese J. Inorg. Chem.(无机化学学报), 2015, 31:1-6

    23. [23]

      [23] Jiang X C, Yan C H, Sun L D, et al. J. Solid State Chem., 2003,175:245-251

    24. [24]

      [24] Jiang X C, Sun L D, Yan C H. J. Phys. Chem. B, 2004,108:3387-3390

    25. [25]

      [25] Diaz A, Keszler D A. Chem. Mater., 1997,9:2071-2077

    26. [26]

      [26] Furetta C, Kitis G, Weng P S, et al. Nucl. Instrum. Methods Phys. Res. Sect. A, 1999,420:441-445

    27. [27]

      [27] Liu J P, Li Y, Huang X T, et al. Chem. Mater., 2008,20:250-257

    28. [28]

      [28] Zhang J, Li Z Q, Zhang B. Mater. Chem. Phys., 2006,98:195-197

    29. [29]

      [29] Tao X Y, Li X D. Nano Lett., 2008,8(2):505-510

    30. [30]

      [30] Xu B S, Li T B, Zhang Y, et al. Cryst. Growth Des., 2008,8(4):1218-1222

    31. [31]

      [31] Zhu W C, Zhang Q, Xiang L, et al. Cryst. Growth Des., 2008,8(8):2938-2944

    32. [32]

      [32] Nuansing W, Ninmuang S, Jarernboon W, et al. Mater. Sci. Eng. B, 2006,131:147-155

    33. [33]

      [33] Zhang Z Y, Li X H, Wang C H, et al. J. Phys. Chem. C, 2009,113:19397-19403

    34. [34]

      [34] Maensiri S, Sangmanee M, Wiengmoon A. Nanoscale Res. Lett., 2009,4:221-228

    35. [35]

      [35] Li C R, Cui M Y, Sun Q T, et al. J. Alloys Compd., 2010, 504:498-502

    36. [36]

      [36] LI Shan-Shan(李珊珊), XIA Hai-Ping(夏海平), FU Li(符立), et al. Acta Phys.-Chim. Sin.(物理化学学报), 2014,30(9):1752-1757

    37. [37]

      [37] Bao S P, Chen X Y, Li Z, et al. CrystEngComm, 2011,13:2511-2520

    38. [38]

      [38] Levin E M, Roth R S, Martin J B. Am. Mineral., 1961,46:1030-1053

    39. [39]

      [39] Zhang L H, Jia G, You H P, et al. J. Inorg. Chem., 2010,49:3305-3309

    40. [40]

      [40] Pang H C, Ning G L, Gong W T, et al. New J. Chem., 2011, 35:1449-1452

    41. [41]

      [41] Judd B R. Phys. Rev., 1962,127:750-761

  • 加载中
    1. [1]

      Ruixin XU , Hongtuo LI , Chen SHI , Yanhong YAN . Factors influencing the spectral properties of composite luminescent materials SrTiO3: Eu3+/SrAl2O4: Eu2+, Dy3+. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2307-2316. doi: 10.11862/CJIC.20250055

    2. [2]

      Cheng Zheng ,  Shiying Zheng ,  Yanping Zhang ,  Shoutian Zheng ,  Qiaohua Wei . Synthesis, Copper Content Analysis, and Luminescent Performance Study of Binuclear Copper (I) Complexes with Isomeric Luminescence Shift: A Comprehensive Chemical Experiment Recommendation. University Chemistry, 2024, 39(7): 322-329. doi: 10.3866/PKU.DXHX202310131

    3. [3]

      Song ZHOU , Hongrui LI , Zekang YAN , Zhijun WANG , Panlai LI . Preparation and luminescence properties of color-tunable CaScBO4∶Bi3+, Eu3+ phosphors. Chinese Journal of Inorganic Chemistry, 2026, 42(6): 1261-1275. doi: 10.11862/CJIC.20250329

    4. [4]

      Yuheng Zhou . 大学课堂的色彩——探索过渡元素的美. University Chemistry, 2025, 40(6): 303-309. doi: 10.12461/PKU.DXHX202407110

    5. [5]

      Ben Yang ,  Shukun Shen ,  Pujun Jin ,  Yujia Luo ,  Jianyong Hu . Covalent organic frameworks: emerging organic porous materials. University Chemistry, 2026, 41(4): 264-274. doi: 10.12461/PKU.DXHX202502128

    6. [6]

      Yan ZHAO , Jiaxu WANG , Zhonghu LI , Changli LIU , Xingsheng ZHAO , Hengwei ZHOU , Xiaokang JIANG . Gd3+-doped Sc2W3O12: Eu3+ red phosphor: Preparation and luminescence performance. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 461-468. doi: 10.11862/CJIC.20240316

    7. [7]

      Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na3CrF6 phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098

    8. [8]

      Weihao LI , Fangzhou JIA , Ying SONG , Yunsong XU , Guifeng LU , Xinzhi WANG , Zhongping YAO . Micro/nano hierarchical MoS2/Ni3S2@nickel foam porous composite photothermal material: Preparation and interfacial evaporation performance. Chinese Journal of Inorganic Chemistry, 2026, 42(6): 1190-1202. doi: 10.11862/CJIC.20250365

    9. [9]

      Mengyun Wu ,  Yuxin Deng ,  Wenhui Wang ,  Dongdong Xu ,  Langui Xie ,  Peipei Sun . 电化学合成4-氯-2-三异丙基硅基喹啉. University Chemistry, 2026, 41(5): 222-229. doi: 10.12461/PKU.DXHX202511044

    10. [10]

      Chang LIU , Cuiping HE , Jie LIU , Shicheng XU , Zhanchao WU . Effects of Gd3+/Y3+ doping on crystal phase transition and luminescent properties of Ba3P4O13: Eu2+ phosphors. Chinese Journal of Inorganic Chemistry, 2026, 42(7): 1420-1428. doi: 10.11862/CJIC.20260101

    11. [11]

      Nian LIU , Biao ZHENG , Kun WANG , Chunbao ZHENG , Qingyan HAN , Enjie HE , Saidong XUE . Synthesis and spectroscopic performance of double perovskite Li0.5La0.5MgSrWO6∶Mn4+ phosphors for plant growth lighting. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 129-140. doi: 10.11862/CJIC.20250069

    12. [12]

      Yan ZHAO , Xiaokang JIANG , Zhonghui LI , Jiaxu WANG , Hengwei ZHOU , Hai GUO . Preparation and fluorescence properties of Eu3+-doped CaLaGaO4 red-emitting phosphors. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1861-1868. doi: 10.11862/CJIC.20240242

    13. [13]

      Tong WANG , Xuefang ZHU , Qi GAO , Hongbo ZHANG , Chao REN , Lixia GE . Luminescence and thermal stability of Tb3+-Eu3+ doped glass-ceramics containing Na8.12Y1.293Si6O18 crystal phase. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2237-2250. doi: 10.11862/CJIC.20250137

    14. [14]

      Shuhao FENG , Feibing XIONG , Yaqing LIN , Han SU , Xu HAN . Preparation and luminescent properties of alkaline metal doped Cd3Al2Ge3O12: Pr3+ orange phosphors. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 284-296. doi: 10.11862/CJIC.20250171

    15. [15]

      Yueyue DU , Yuwei ZHENG , Xuanhe WEI , Yifan LU , Yingchao HAN . Sodium alginate/nano lanthanum hydroxide composite microspheres: Electrospraying preparation and phosphorus adsorption performance. Chinese Journal of Inorganic Chemistry, 2026, 42(8): 1669-1684. doi: 10.11862/CJIC.20260002

    16. [16]

      Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr1-xZrSi2O7∶xDy3+ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096

    17. [17]

      Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO2/Bi2MoO6 Microsphere Heterojunction for Efficient Photocatalytic CO2 Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-0. doi: 10.3866/PKU.WHXB202309031

    18. [18]

      Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363

    19. [19]

      Tong WANG , Qinyue ZHONG , Qiong HUANG , Weimin GUO , Xinmei LIU . Mn-doped carbon quantum dots/Fe-doped ZnO flower-like microspheres heterojunction: Construction and photocatalytic performance. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1589-1600. doi: 10.11862/CJIC.20250011

    20. [20]

      Zhao Feifan ,  Xu Feiyan ,  Yu Jiaguo . Interfacial stabilization of alkali metal oxides on carbon spheres for high-performance CO2 chemisorption. Acta Physico-Chimica Sinica, 2026, 42(5): 100234-. doi: 10.1016/j.actphy.2025.100234

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(1049)
  • HTML views(115)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return