Citation: YANG Yang, CONG Yan, XIAO Yu, FU Yue, XIA Sheng-Qiang, DONG Bin. Luminescent and Long-Lasting Properties of Cd₃Al₂Ge₃O₁₂:Mn²⁺ Phosphor[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1529-1533. doi: 10.11862/CJIC.2015.207 shu

Luminescent and Long-Lasting Properties of Cd₃Al₂Ge₃O₁₂:Mn²⁺ Phosphor

YANG Yang ¹ ,
CONG Yan ^1,2,, ,
XIAO Yu ¹ ,
FU Yue ¹ ,
XIA Sheng-Qiang ¹ ,
DONG Bin ^1,2,,

1.
1. School of Physics & Materials Engineering, Dalian Nationalities University, Dalian, Liaoning 11660, China;
2.
2. Liaoning Key Laboratory of Optoelectronic Films and Materials, Dalian, Liaoning 11660, China

Corresponding author: CONG Yan, DONG Bin,
Received Date: 24 January 2015
Available Online: 29 May 2015
Fund Project: 国家自然科学基金(No.61205178,11274057,11474046) (No.61205178,11274057,11474046)辽宁省博士启动基金(No.20121073) (No.20121073)大连市金州新区科技计划项目(No.2012-A1-051) (No.2012-A1-051)中央高校基本科研业务费专项资金(No.DC201502080302,DC201502080203) (No.DC201502080302,DC201502080203)大连民族学院大学生创新创业训练计划(No.X201413257)资助项目。 (No.X201413257)

Cd₃Al₂Ge₃O₁₂:Mn²⁺ afterglow phosphors were synthesized by the conventional solid-state reaction in this work, and the enhanced afterglow properties were observed with Zr⁴⁺ ions co-doping. The Cd₃Al₂Ge₃O₁₂:Mn²⁺, Zr⁴⁺ phosphors were characterized by using XRD, photoluminescence and thermoluminescence spectroscopy. The emission spectrum shows a broad emission band from 500 to 700 nm which is assigned to the ⁴T₁(⁴G)→⁶A₁(⁶S) transitions of Mn²⁺ ion. An energy transfer from the Cd₃Al₂Ge₃O₁₂ host to Mn²⁺ ions was observed. The center and the profile of the emission remain unchanged when co-doped with Zr⁴⁺ ions, but the introduction of Zr⁴⁺ ions improved the afterglow duration. Thermoluminescence spectra indicated that the introduction of Zr⁴⁺ into the host produces traps with suitable depth, resulting in the enhanced phosphorescence of Mn²⁺.
- long-lasting luminescence;Mn²⁺ ion;energy transfer
1. [1]
  [1] LIU Ying-Liang(刘应亮), LEI Bing-Fu(雷炳富), KUANG Jin-Yong(邝金勇), et al. Chinese J. Inorg. Chem.(无机化学学报), 2009,25(8):1323-1329
2. [2]
  [2] Lei B, Sha L, Zhang H, et al. Solid State Sci., 2010,12(12):2177-2181
3. [3]
  [3] Matsuzawa T, Aoki Y, Takeuchi N. J. Electrochem. Soc., 1996,143(8):2670-2673
4. [4]
  [4] LI Cheng-Yu(李成宇), SU Qiang(苏锵), QIU Jiang-Rong(邱建荣). Chinese J. Lumin.(发光学报), 2003,24:19-27
5. [5]
  [5] SHI Chao-Shu(施朝淑), QI Ze-Ming(戚泽明). Chinese J. Inorg. Chem.(无机化学学报), 2004,19:961-969
6. [6]
  [6] Pan Z, Lu Y, Liu F. Nat. Mater., 2012,11:58-63
7. [7]
  [7] Lei B, Liu Y, Zhang J, et al. J. Alloys Compd., 2010,459:247-253
8. [8]
  [8] Jha Pardeep K, Jha Priyanka A, Kumar P, et al. J. Mater. Sci.:Mater. Electron., 2014,25:664-672
9. [9]
  [9] Sun Y, Yu H, Liu H, et al. Adv. Mater. Res., 2012,415-417:495-498
10. [10]
  [10] HE Ming-Rui(贺明睿), XIAO Jiu-Lin(肖久林), TIAN Yan-Wen(田彦文), et al. Chinese Rare Earths(稀土), 2009,30(1):10-13
11. [11]
  [11] LIU Xing-Ren(刘行仁), TIAN Jun(田军), WANG Xiao-Jun (王晓君), et al. Chinese J. Lumin.(发光学报), 1994,15(2):83-88
12. [12]
  [12] LIU Zheng-Wei(刘正伟). Thesis for the Masterate of Jinan University(暨南大学硕士论文). 2005.
13. [13]
  [13] Nosenko A E, Abramov A P, Kostyk L V, et al. Opt. Spectrasc., 1986,61(5):648-653
14. [14]
  [14] Zhang T, Su Q. J. Soc. Inf. Disp., 2000,8(1):27-30
15. [15]
  [15] Ihara M, Igarashi T, Kusunoki I, et al. J. Electrochem. Soc., 2002,149(3):H72-H75
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Luminescent and Long-Lasting Properties of Cd₃Al₂Ge₃O₁₂:Mn²⁺ Phosphor