Citation: YANG Yang, CONG Yan, XIAO Yu, FU Yue, XIA Sheng-Qiang, DONG Bin. Luminescent and Long-Lasting Properties of Cd₃Al₂Ge₃O₁₂:Mn²⁺ Phosphor[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1529-1533. doi: 10.11862/CJIC.2015.207 shu

Luminescent and Long-Lasting Properties of Cd₃Al₂Ge₃O₁₂:Mn²⁺ Phosphor

YANG Yang ¹ ,
CONG Yan ^1,2,, ,
XIAO Yu ¹ ,
FU Yue ¹ ,
XIA Sheng-Qiang ¹ ,
DONG Bin ^1,2,,

1.
1. School of Physics & Materials Engineering, Dalian Nationalities University, Dalian, Liaoning 11660, China;
2.
2. Liaoning Key Laboratory of Optoelectronic Films and Materials, Dalian, Liaoning 11660, China

Corresponding author: CONG Yan, DONG Bin,
Received Date: 24 January 2015
Available Online: 29 May 2015
Fund Project: 国家自然科学基金(No.61205178,11274057,11474046) (No.61205178,11274057,11474046)辽宁省博士启动基金(No.20121073) (No.20121073)大连市金州新区科技计划项目(No.2012-A1-051) (No.2012-A1-051)中央高校基本科研业务费专项资金(No.DC201502080302,DC201502080203) (No.DC201502080302,DC201502080203)大连民族学院大学生创新创业训练计划(No.X201413257)资助项目。 (No.X201413257)

Cd₃Al₂Ge₃O₁₂:Mn²⁺ afterglow phosphors were synthesized by the conventional solid-state reaction in this work, and the enhanced afterglow properties were observed with Zr⁴⁺ ions co-doping. The Cd₃Al₂Ge₃O₁₂:Mn²⁺, Zr⁴⁺ phosphors were characterized by using XRD, photoluminescence and thermoluminescence spectroscopy. The emission spectrum shows a broad emission band from 500 to 700 nm which is assigned to the ⁴T₁(⁴G)→⁶A₁(⁶S) transitions of Mn²⁺ ion. An energy transfer from the Cd₃Al₂Ge₃O₁₂ host to Mn²⁺ ions was observed. The center and the profile of the emission remain unchanged when co-doped with Zr⁴⁺ ions, but the introduction of Zr⁴⁺ ions improved the afterglow duration. Thermoluminescence spectra indicated that the introduction of Zr⁴⁺ into the host produces traps with suitable depth, resulting in the enhanced phosphorescence of Mn²⁺.
- long-lasting luminescence;Mn²⁺ ion;energy transfer
1. [1]
  [1] LIU Ying-Liang(刘应亮), LEI Bing-Fu(雷炳富), KUANG Jin-Yong(邝金勇), et al. Chinese J. Inorg. Chem.(无机化学学报), 2009,25(8):1323-1329
2. [2]
  [2] Lei B, Sha L, Zhang H, et al. Solid State Sci., 2010,12(12):2177-2181
3. [3]
  [3] Matsuzawa T, Aoki Y, Takeuchi N. J. Electrochem. Soc., 1996,143(8):2670-2673
4. [4]
  [4] LI Cheng-Yu(李成宇), SU Qiang(苏锵), QIU Jiang-Rong(邱建荣). Chinese J. Lumin.(发光学报), 2003,24:19-27
5. [5]
  [5] SHI Chao-Shu(施朝淑), QI Ze-Ming(戚泽明). Chinese J. Inorg. Chem.(无机化学学报), 2004,19:961-969
6. [6]
  [6] Pan Z, Lu Y, Liu F. Nat. Mater., 2012,11:58-63
7. [7]
  [7] Lei B, Liu Y, Zhang J, et al. J. Alloys Compd., 2010,459:247-253
8. [8]
  [8] Jha Pardeep K, Jha Priyanka A, Kumar P, et al. J. Mater. Sci.:Mater. Electron., 2014,25:664-672
9. [9]
  [9] Sun Y, Yu H, Liu H, et al. Adv. Mater. Res., 2012,415-417:495-498
10. [10]
  [10] HE Ming-Rui(贺明睿), XIAO Jiu-Lin(肖久林), TIAN Yan-Wen(田彦文), et al. Chinese Rare Earths(稀土), 2009,30(1):10-13
11. [11]
  [11] LIU Xing-Ren(刘行仁), TIAN Jun(田军), WANG Xiao-Jun (王晓君), et al. Chinese J. Lumin.(发光学报), 1994,15(2):83-88
12. [12]
  [12] LIU Zheng-Wei(刘正伟). Thesis for the Masterate of Jinan University(暨南大学硕士论文). 2005.
13. [13]
  [13] Nosenko A E, Abramov A P, Kostyk L V, et al. Opt. Spectrasc., 1986,61(5):648-653
14. [14]
  [14] Zhang T, Su Q. J. Soc. Inf. Disp., 2000,8(1):27-30
15. [15]
  [15] Ihara M, Igarashi T, Kusunoki I, et al. J. Electrochem. Soc., 2002,149(3):H72-H75
1. [1]
  Ruoxi Sun , Yiqian Xu , Shaoru Rong , Chunmiao Han , Hui Xu . The Enchanting Collision of Light and Time Magic: Exploring the Footprints of Long Afterglow Lifetime. University Chemistry, 2024, 39(5): 90-97. doi: 10.3866/PKU.DXHX202310001
2. [2]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
3. [3]
  Xingyuan Lu , Yutao Yao , Junjing Gu , Peifeng Su . Energy Decomposition Analysis and Its Application in the Many-Body Effect of Water Clusters. University Chemistry, 2025, 40(3): 100-107. doi: 10.12461/PKU.DXHX202405074
4. [4]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
5. [5]
  Shipeng WANG , Shangyu XIE , Luxian LIANG , Xuehong WANG , Jie WEI , Deqiang WANG . Piezoelectric effect of Mn, Bi co-doped sodium niobate for promoting cell proliferation and bacteriostasis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1919-1931. doi: 10.11862/CJIC.20240094
6. [6]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
7. [7]
  Changyan Sun , Hualei Zhou , Bin Dong . Application of “PBL” Teaching Mode in Inorganic Chemistry Experimental Education in the Perspective of Course Ideology and Politics: Taking Preparation of Manganese Carbonate as an Example. University Chemistry, 2024, 39(11): 378-383. doi: 10.12461/PKU.DXHX202402016
8. [8]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
9. [9]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
10. [10]
  Guoze Yan , Bin Zuo , Shaoqing Liu , Tao Wang , Ruoyu Wang , Jinyang Bao , Zhongzhou Zhao , Feifei Chu , Zhengtong Li , Yusuke Yamauchi , Saad Melhi , Xingtao Xu . Opportunities and Challenges of Capacitive Deionization for Uranium Extraction from Seawater. Acta Physico-Chimica Sinica, 2025, 41(4): 100032-. doi: 10.3866/PKU.WHXB202404006
11. [11]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
12. [12]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
13. [13]
  Qin Li , Kexin Yang , Qinglin Yang , Xiangjin Zhu , Xiaole Han , Tao Huang . Illuminating Chlorophyll: Innovative Chemistry Popularization Experiment. University Chemistry, 2024, 39(9): 359-368. doi: 10.3866/PKU.DXHX202309059
14. [14]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
15. [15]
  Xiaochen Zhang , Fei Yu , Jie Ma . 多角度数理模拟在电容去离子中的前沿应用. Acta Physico-Chimica Sinica, 2024, 40(11): 2311026-. doi: 10.3866/PKU.WHXB202311026
16. [16]
  Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . 卤化物钙钛矿的单双向离子迁移. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-. doi: 10.3866/PKU.WHXB202311011
17. [17]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
18. [18]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
19. [19]
  Dongqi Cai , Fuping Tian , Zerui Zhao , Yanjuan Zhang , Yue Dai , Feifei Huang , Yu Wang . Exploration of Factors Influencing the Determination of Ion Migration Number by Hittorf Method. University Chemistry, 2024, 39(4): 94-99. doi: 10.3866/PKU.DXHX202310031
20. [20]
  Jiayu Tang , Jichuan Pang , Shaohua Xiao , Xinhua Xu , Meifen Wu . Improvement for Measuring Transference Numbers of Ions by Moving-Boundary Method. University Chemistry, 2024, 39(5): 193-200. doi: 10.3866/PKU.DXHX202311021

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(282)
HTML views(30)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Luminescent and Long-Lasting Properties of Cd3Al2Ge3O12:Mn2+ Phosphor

Metrics

通讯作者: 陈斌, bchen63@163.com

Luminescent and Long-Lasting Properties of Cd₃Al₂Ge₃O₁₂:Mn²⁺ Phosphor