Citation: YANG Yang, CONG Yan, XIAO Yu, FU Yue, XIA Sheng-Qiang, DONG Bin. Luminescent and Long-Lasting Properties of Cd₃Al₂Ge₃O₁₂:Mn²⁺ Phosphor[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1529-1533. doi: 10.11862/CJIC.2015.207 shu

Luminescent and Long-Lasting Properties of Cd₃Al₂Ge₃O₁₂:Mn²⁺ Phosphor

YANG Yang ¹ ,
CONG Yan ^1,2,, ,
XIAO Yu ¹ ,
FU Yue ¹ ,
XIA Sheng-Qiang ¹ ,
DONG Bin ^1,2,,

1.
1. School of Physics & Materials Engineering, Dalian Nationalities University, Dalian, Liaoning 11660, China;
2.
2. Liaoning Key Laboratory of Optoelectronic Films and Materials, Dalian, Liaoning 11660, China

Corresponding author: CONG Yan, DONG Bin,
Received Date: 24 January 2015
Available Online: 29 May 2015
Fund Project: 国家自然科学基金(No.61205178,11274057,11474046) (No.61205178,11274057,11474046)辽宁省博士启动基金(No.20121073) (No.20121073)大连市金州新区科技计划项目(No.2012-A1-051) (No.2012-A1-051)中央高校基本科研业务费专项资金(No.DC201502080302,DC201502080203) (No.DC201502080302,DC201502080203)大连民族学院大学生创新创业训练计划(No.X201413257)资助项目。 (No.X201413257)

Cd₃Al₂Ge₃O₁₂:Mn²⁺ afterglow phosphors were synthesized by the conventional solid-state reaction in this work, and the enhanced afterglow properties were observed with Zr⁴⁺ ions co-doping. The Cd₃Al₂Ge₃O₁₂:Mn²⁺, Zr⁴⁺ phosphors were characterized by using XRD, photoluminescence and thermoluminescence spectroscopy. The emission spectrum shows a broad emission band from 500 to 700 nm which is assigned to the ⁴T₁(⁴G)→⁶A₁(⁶S) transitions of Mn²⁺ ion. An energy transfer from the Cd₃Al₂Ge₃O₁₂ host to Mn²⁺ ions was observed. The center and the profile of the emission remain unchanged when co-doped with Zr⁴⁺ ions, but the introduction of Zr⁴⁺ ions improved the afterglow duration. Thermoluminescence spectra indicated that the introduction of Zr⁴⁺ into the host produces traps with suitable depth, resulting in the enhanced phosphorescence of Mn²⁺.
- long-lasting luminescence;Mn²⁺ ion;energy transfer
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Luminescent and Long-Lasting Properties of Cd₃Al₂Ge₃O₁₂:Mn²⁺ Phosphor