Citation: YIN Wei-Dong, LI Gui-Lian, LIU Guang-Zhen, XIN Ling-Yun, LI Xiao-Ling, MA Lu-Fang. Syntheses, Structures and Properties of Two Coordination Polymers Constructed by 3-Nitrobenzene-1,2-dicarboxylate Acid and Zn/Co[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1439-1446. doi: 10.11862/CJIC.2015.202 shu

Syntheses, Structures and Properties of Two Coordination Polymers Constructed by 3-Nitrobenzene-1,2-dicarboxylate Acid and Zn/Co

1.
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, Henan 471022, China

Corresponding author: LIU Guang-Zhen,
Received Date: 29 March 2015
Available Online: 8 June 2015
Fund Project: 国家自然科学基金(No.20971064, 21271098) (No.20971064, 21271098) 河南省大学科技创新人才(No.14HASTIT017) (No.14HASTIT017) 河南省大学科技创新团队(No.14IRTSTHN008) 资助项目。 (No.14IRTSTHN008)

Two coordination polymers {[Zn(3-Nbdc)(bpmp)]·H₂O}_n (1) and {[Co(3-Nbdc)(bpmp)(H₂O)]·H₂O}_n (2) (3-Nbdc^2-=3-nitrobenzene-1,2-dicarboxylate, bpmp=1,4-bis(4-pyridylmethyl)piperazine) were synthesized hydrother-mally and characterized structurally by single-crystal X-ray diffractions, elemental analysis and infrared spectros-copy (IR). Both complexes 1 and 2 display (4,4) grid layers containing the dinuclear units in 1 and helix metal-carboxylate chains in 2. Thermogravimetric Analyses (TGA), powder X-ray diffractions (PXRD), fluorescence property and magnetic property for compounds 1 and 2 are also investigated. The solid state fluorescence indicates that the complex 1 shows similar emission spectra to the free 3-NbdcH₂ ligand due to little contribution from the Zn-O inorganic motifs to the emission and very little degree change of interligand coupling upon metal coordination. The complex 2 exhibits a ferromagnetic coupling between the metal centers in the low-temperature region, and the decrease of χ_MT value in the high-temperature region may be attributed to the strong spin-orbit coupling through the ⁴T_1g state of the octahedral Co²⁺ centers.
- hydrothermal synthesis;cobalt;photoluminescence;magnetic property;coordination polymer
1. [1]
  [1] O'Keeffe M. Chem. Soc. Rev., 2009, 38:1215-1217
2. [2]
  [2] Xuan W M, Zhu C F, Liu Y, et al. Chem. Soc. Rev., 2012, 41:1677-1695
3. [3]
  [3] Férey G. Chem. Soc. Rev., 2008, 37:191-214
4. [4]
  [4] Guo H, Zhu G, Hewitt I J, et al. J. Am. Chem. Soc., 2009, 131:1646-1647
5. [5]
  [5] Huang A, Bux H, Steinbach F, et al. Angew. Chem. Int. Ed., 2010, 49:4958-4961
6. [6]
  [6] Du M, Li C P, Chen M, et al. J. Am. Chem. Soc., 2014, 136: 10906-10909
7. [7]
  [7] Zhao Y, Deng D S, Ma L F, et al. Chem. Commun., 2013, 49: 10299-10301
8. [8]
  [8] Li L C, Matsuda R, Tanaka I, et al. J. Am. Chem. Soc., 2014, 136:7543-7546
9. [9]
  [9] Bauer C A, Timofeeva T V, Setterstten T B, et al. J. Am. Chem. Soc., 2007, 129:7136-7144
10. [10]
  [10] Bourne S A, Lu J, Mondal A, et al. Angew. Chem. Int. Ed., 2001, 40:2111-2113
11. [11]
  [11] Zou R Q, Bu X H, Zhang R H. Inorg. Chem., 2004, 43:5382-5386
12. [12]
  [12] Ye B H, Ding B B, Weng Y Q, et al. Cryst. Growth Des., 2005, 5:801-806
13. [13]
  [13] GONG Teng-Fei(龚腾飞), ZHU Cheng-Feng(朱成峰), YE Cheng-Cheng(叶诚诚), et al. Chinese J. Struct. Chem.(结构化学), 2013, 8:1222-1228
14. [14]
  [14] Li W, Barton P T, Burwooda R P, et al. Dalton Trans., 2011, 40:7147-7152
15. [15]
  [15] Li G L, Liu G Z, Ma L F, et al. Chem. Commun., 2014, 50: 2615-2617
16. [16]
  [16] Li G L, Yin W D, Liu G Z, et al. J. Solid State Chem., 2014, 220:1-8
17. [17]
  [17] Li G L, Yin W D, Liu G Z, et al. Inorg. Chem. Commun., 2014, 43:165-168
18. [18]
  [18] Li G L, Liu G Z, Huang L L, et al. J. Inorg. Organomet. Polym., 2014, 24:617-623
19. [19]
  [19] Zhang J, Zhu L G. CrystEngComm, 2011, 13:553-560
20. [20]
  [20] Wang X L, Mu B, Lin H Y, et al. CrystEngComm, 2012, 14: 1001-1009
21. [21]
  [21] Qu H, Qiu L, Leng X K, et al. Inorg. Chem. Commun., 2011, 14:1347-1352
22. [22]
  [22] Liu G Z, Li S H, Li X L, et al. CrystEngComm, 2013, 15: 4571-4580
23. [23]
  [23] Xin L Y, Liu G Z, Li X L, et al. Cryst. Growth Des., 2012, 12:147-157
24. [24]
  [24] Li X L, Liu G Z, Xin L Y, et al. CrystEngComm, 2012, 14: 5757-5760
25. [25]
  [25] Banisafar A, Martin D P, Lucas J S, et al. Cryst. Growth Des., 2011, 11:1651-1661
26. [26]
  [26] Xu B, Lü J, Cao R. Cryst. Growth Des., 2009, 9:3003-3005
27. [27]
  [27] Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structure, University of Göttingen, Germany, 1997.
28. [28]
  [28] Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany, 1997.
29. [29]
  [29] LIU Xiu-Xiu(刘秀秀), CHENG Mei-Ling(程美令), REN Yan-Qiu(任艳秋), et al. Chinese J. Inorg. Chem.(无机化学学报), 2015, 31:611-618
30. [30]
  [30] Bordiga S, Lamberti C, Ricchiardi G, et al. Chem. Commun., 2004, 20:2300-2301
31. [31]
  [31] Zeng M H, Zhang W X, Sun X Z, et al. Angew. Chem. Int. Ed., 2005, 44:3079-3082
32. [32]
  [32] Zhang X M, Hao Z M, Zhang W X, et al. Angew. Chem. Int. Ed., 2007, 46:3456-3459
33. [33]
  [33] Fang Z L, Yu R M, He J G, et al. Inorg. Chem., 2009, 48: 7691-7697
34. [34]
  [34] Su Z, Fan J, Chen M, et al. Cryst. Growth Des., 2011, 11: 1159-1169
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