Citation: YE Hong-De, XU Bao-Hua, HU Jiu-Rong, YAN Hong. Cobalt(Ⅲ)-Mediated Intramolecular Coupling of B(3)/B(6) in CpCoS₂C₂B₁₀H₁₀ with Cp Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1447-1452. doi: 10.11862/CJIC.2015.200 shu

Cobalt(Ⅲ)-Mediated Intramolecular Coupling of B(3)/B(6) in CpCoS₂C₂B₁₀H₁₀ with Cp Ligand

YE Hong-De ^1,2,, ,
XU Bao-Hua ¹ ,
HU Jiu-Rong ² ,
YAN Hong ^1,,

1.
1 State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China;
2.
2 School of Chemistry and Chemical Engineering, Shangrao Normal University, Shangrao, Jiangxi 334001, China

Corresponding author: YE Hong-De, YAN Hong,
Received Date: 29 March 2015
Available Online: 8 May 2015
Fund Project: 国家自然科学基金(No.21361022, 21261020) (No.21361022, 21261020)第54批中国博士后科学基金面上基金(No.2013M541640) (No.2013M541640)

Half-sandwich 16e complex CpCoS₂C₂B₁₀H₁₀ (Cp: cyclopentadienyl) (1) reacted with HC≡CCO₂Me in the presence of 2-methylpropanedithioic acid to generate compounds {(C₅H₄CoS₂C₂B₉H₉)(CH=CHCO₂Me)(Me₂C=CS₂H)} (2) and (Me₂C=CS₂H)₃Co (3). In 2, one S-Co bond of 1 was broken, and the S atom linked with the terminal acetylenyl carbon atom of the HC≡CCO₂Me. Meanwhile, the Co atom in 1 linked to the S atom in 2-methylpropanedithioic acid with covalent bond while linked to the SH unit with coordinative bond. One carbon atom of Cp ring linked to the B(3)/B(6) cite of the carborane cage. The H atom of the B(3)/B(6) cite migrated to the internal acetylenyl carbon atom to form a trans-ethylenic bond. The Co atom of 1 linked to three S atoms of three 2-methylpropanedithioic acid molecules with covalent bond, while linked to the other three SH units with coordinative bond. As a result, product 3 formed. Complexes 2 and 3 have been characterized by IR, NMR, elemental analysis, mass spectrum and single-crystal X-ray diffraction analysis.
- cobalt;carborane;ligand;couple
1. [1]
  [1] Herberhold M, Jin G X, Yan H, et al. Eur. J. Inorg. Chem., 1999, 5:873-875
2. [2]
  [2] Herberhold M, Jin G X, Yan H, et al. J. Organomet. Chem., 1999, 587:252-257
3. [3]
  [3] Bae J Y, Park Y L, Ko J, et al. Inorg. Chim. Acta, 1999, 289: 141-148
4. [4]
  [4] Liu S, Han Y F, Jin G X. Chem. Soc. Rev., 2007, 36:1543-1560
5. [5]
  [5] Herberhold M, Yan H, Milius W, et al. Organometallics, 2000, 19:4289-4294
6. [6]
  [6] Xu B H, Wu D H, Li Y Z, et al. Organometallics, 2007, 26: 4344-4349
7. [7]
  [7] Xu B H, Tao J C, Li Y Z, et al. Organometallics, 2008, 27: 334-340
8. [8]
  [8] Herberhold M, Yan H, Milius W, et al. Chem. Eur. J., 2000, 6:3026-3032
9. [9]
  [9] Herberhold M, Yan H, Milius W, et al. J. Chem. Soc., Dalton Trans., 2001:1782-1789
10. [10]
  [10] Herberhold M, Yan H, Milius W, et al. Angew. Chem. Int. Ed., 1999, 38:3689-3691
11. [11]
  [11] Herberhold M, Yan H, Milius W, et al. Z. Anorg. Allg. Chem., 2000, 626:1627-1633
12. [12]
  [12] Kim D H, Ko J, Park K, et al. Organometallics, 1999, 18: 2738-2740
13. [13]
  [13] Won J H, Kim D H, Kim B Y, et al. Organometallics, 2002, 21:1443-1453
14. [14]
  [14] Zhang R, Zhu L, Liu G F, et al. J. Am. Chem. Soc., 2012, 134:10341-10344
15. [15]
  [15] Frith S A, Spencer J L. Inorg. Synth., 1990, 28:273-280
16. [16]
  [16] Hou X F, Wang X, Wang J Q, et al. J. Organomet. Chem., 2004, 689:2228-2235
17. [17]
  [17] Sheldrick G M. SADABS, An Empirical Absorption Correction Program, Bruker Analytical X-ray Systems, Madison, WI, 1996.
18. [18]
  [18] Sheldrick G M. SHELXS-97, Program for Crystal Structure Solution, University of Göttingen, Göttingen, Germany, 1997.
19. [19]
  [19] Sheldrick G M. SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Göttingen, Germany, 1997.
20. [20]
  [20] Boese R, Blaser D, Niederprum N, et al. Angew. Chem. Int. Ed., 1992, 31:314-316
21. [21]
  [21] Yao H J, Grimes R N. Organometallics, 2003, 22:4539-4546
22. [22]
  [22] Russell J M, Sabat H, Grimes R N. Organometallics, 2002, 21:5613-5621
23. [23]
  [23] Yan H, Beatty A M, Fehlner T P. Angew. Chem. Int. Ed., 2001, 40:4498-4501
24. [24]
  [24] Yan H, Beatty A M, Fehlner T P. Angew. Chem. Int. Ed., 2002, 41:2578-2581
25. [25]
  [25] Yan H, Beatty A M, Fehlner T P. J. Am. Chem. Soc., 2002, 124:10280-10281
26. [26]
  [26] Zhang R, Zhu L, Lu Z Z, et al. Dalton Trans., 2012, 41: 12054-12063
1. [1]
  Shengwen XU , Longlong YANG , Houji CAO , Deshuang TU , Xing WEI , Changsheng LU , Hong YAN . Research progress on light-induced functionalization of polyhedral carborane clusters. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2187-2200. doi: 10.11862/CJIC.20250192
2. [2]
  Wenjing ZHANG , Xiaoqing WANG , Zhipeng LIU . Recent developments of inorganic metal complex-based photothermal materials and their applications in photothermal therapy. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2356-2372. doi: 10.11862/CJIC.20240254
3. [3]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
4. [4]
  Wuxin Bai , Qianqian Zhou , Zhenjie Lu , Ye Song , Yongsheng Fu . Co-Ni Bimetallic Zeolitic Imidazolate Frameworks Supported on Carbon Cloth as Free-Standing Electrode for Highly Efficient Oxygen Evolution. Acta Physico-Chimica Sinica, 2024, 40(3): 2305041-0. doi: 10.3866/PKU.WHXB202305041
5. [5]
  Chenyang WANG , Yiyan BAI , Wei ZHANG , Zhaorong LIU , Yuchun WANG . Performance of photo-assisted copper oxide catalyzed hydrolysis of ammonia borane to produce hydrogen. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 97-110. doi: 10.11862/CJIC.20250116
6. [6]
  Xiaofei Zhang , Shanhao Xu , Zhiyuan Wang , Long He , Tiangcheng Huang , Yongming Xu , Yucui Bian , Yike Li , Haijun Chen , Zhongjun Li . Surface doping of graphene into BiOCl for efficient photocatalytic amine coupling under visible light. Acta Physico-Chimica Sinica, 2026, 42(5): 100202-0. doi: 10.1016/j.actphy.2025.100202
7. [7]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
8. [8]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
9. [9]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Corrosion inhibition of nickel-cobalt-phosphide in water by coating TiO₂ layer. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 365-384. doi: 10.11862/CJIC.20240063
10. [10]
  Xue-Peng Zhang , Yuchi Long , Yushu Pan , Jiding Wang , Baoyu Bai , Rui Ding . 定量构效关系方法学习探索：以钴卟啉活化氧气为例. University Chemistry, 2025, 40(8): 345-359. doi: 10.12461/PKU.DXHX202410107
11. [11]
  Lili Jiang , Shaoyu Zheng , Xuejiao Liu , Xiaomin Xie . Copper-Catalyzed Oxidative Coupling Reactions for the Synthesis of Aryl Sulfones: A Fundamental and Exploratory Experiment for Undergraduate Teaching. University Chemistry, 2025, 40(7): 267-276. doi: 10.12461/PKU.DXHX202408004
12. [12]
  Jichao XU , Ming HU , Xichang CHEN , Chunhui WANG , Leichen WANG , Lingyi ZHOU , Xing HE , Xiamin CHENG , Su JING . Construction and hydrogen peroxide-activated chemodynamic activity of ferrocene?benzoselenadiazole conjugate. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1495-1504. doi: 10.11862/CJIC.20250144
13. [13]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
14. [14]
  Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304
15. [15]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
16. [16]
  Zijuan LI , Xuan LÜ , Jiaojiao CHEN , Haiyang ZHAO , Shuo SUN , Zhiwu ZHANG , Jianlong ZHANG , Yanling MA , Jie LI , Zixian FENG , Jiahui LIU . Synthesis of visual fluorescence emission CdSe nanocrystals based on ligand regulation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 308-320. doi: 10.11862/CJIC.20240138
17. [17]
  Guilan He , Yaofeng Yuan . 手性二茂铁双膦配体Xyliphos的合成及应用. University Chemistry, 2025, 40(8): 130-137. doi: 10.12461/PKU.DXHX202409122
18. [18]
  Haotong Ma , Mingyu Heng , Yang Xu , Wei Bi , Yingchun Miao , Shuning Xiao . Synergistic carbon doping and Cu loading on boron nitride via microwave synthesis for enhanced atmospheric CO₂ photoreduction. Acta Physico-Chimica Sinica, 2025, 41(11): 100132-0. doi: 10.1016/j.actphy.2025.100132
19. [19]
  Xinhao Yan , Guoliang Hu , Ruixi Chen , Hongyu Liu , Qizhi Yao , Jiao Li , Lingling Li . Polyethylene Glycol-Ammonium Sulfate-Nitroso R Salt System for the Separation of Cobalt (II). University Chemistry, 2024, 39(6): 287-294. doi: 10.3866/PKU.DXHX202310073
20. [20]
  Jiahe LIU , Gan TANG , Kai CHEN , Mingda ZHANG . Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 719-728. doi: 10.11862/CJIC.20250023

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(834)
HTML views(101)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Cobalt(Ⅲ)-Mediated Intramolecular Coupling of B(3)/B(6) in CpCoS2C2B10H10 with Cp Ligand

Metrics

通讯作者: 陈斌, bchen63@163.com

Cobalt(Ⅲ)-Mediated Intramolecular Coupling of B(3)/B(6) in CpCoS₂C₂B₁₀H₁₀ with Cp Ligand