Citation: YE Hong-De, XU Bao-Hua, HU Jiu-Rong, YAN Hong. Cobalt(Ⅲ)-Mediated Intramolecular Coupling of B(3)/B(6) in CpCoS₂C₂B₁₀H₁₀ with Cp Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1447-1452. doi: 10.11862/CJIC.2015.200 shu

Cobalt(Ⅲ)-Mediated Intramolecular Coupling of B(3)/B(6) in CpCoS₂C₂B₁₀H₁₀ with Cp Ligand

YE Hong-De ^1,2,, ,
XU Bao-Hua ¹ ,
HU Jiu-Rong ² ,
YAN Hong ^1,,

1.
1 State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China;
2.
2 School of Chemistry and Chemical Engineering, Shangrao Normal University, Shangrao, Jiangxi 334001, China

Corresponding author: YE Hong-De, YAN Hong,
Received Date: 29 March 2015
Available Online: 8 May 2015
Fund Project: 国家自然科学基金(No.21361022, 21261020) (No.21361022, 21261020)第54批中国博士后科学基金面上基金(No.2013M541640) (No.2013M541640)

Half-sandwich 16e complex CpCoS₂C₂B₁₀H₁₀ (Cp: cyclopentadienyl) (1) reacted with HC≡CCO₂Me in the presence of 2-methylpropanedithioic acid to generate compounds {(C₅H₄CoS₂C₂B₉H₉)(CH=CHCO₂Me)(Me₂C=CS₂H)} (2) and (Me₂C=CS₂H)₃Co (3). In 2, one S-Co bond of 1 was broken, and the S atom linked with the terminal acetylenyl carbon atom of the HC≡CCO₂Me. Meanwhile, the Co atom in 1 linked to the S atom in 2-methylpropanedithioic acid with covalent bond while linked to the SH unit with coordinative bond. One carbon atom of Cp ring linked to the B(3)/B(6) cite of the carborane cage. The H atom of the B(3)/B(6) cite migrated to the internal acetylenyl carbon atom to form a trans-ethylenic bond. The Co atom of 1 linked to three S atoms of three 2-methylpropanedithioic acid molecules with covalent bond, while linked to the other three SH units with coordinative bond. As a result, product 3 formed. Complexes 2 and 3 have been characterized by IR, NMR, elemental analysis, mass spectrum and single-crystal X-ray diffraction analysis.
- cobalt;carborane;ligand;couple
1. [1]
  [1] Herberhold M, Jin G X, Yan H, et al. Eur. J. Inorg. Chem., 1999, 5:873-875
2. [2]
  [2] Herberhold M, Jin G X, Yan H, et al. J. Organomet. Chem., 1999, 587:252-257
3. [3]
  [3] Bae J Y, Park Y L, Ko J, et al. Inorg. Chim. Acta, 1999, 289: 141-148
4. [4]
  [4] Liu S, Han Y F, Jin G X. Chem. Soc. Rev., 2007, 36:1543-1560
5. [5]
  [5] Herberhold M, Yan H, Milius W, et al. Organometallics, 2000, 19:4289-4294
6. [6]
  [6] Xu B H, Wu D H, Li Y Z, et al. Organometallics, 2007, 26: 4344-4349
7. [7]
  [7] Xu B H, Tao J C, Li Y Z, et al. Organometallics, 2008, 27: 334-340
8. [8]
  [8] Herberhold M, Yan H, Milius W, et al. Chem. Eur. J., 2000, 6:3026-3032
9. [9]
  [9] Herberhold M, Yan H, Milius W, et al. J. Chem. Soc., Dalton Trans., 2001:1782-1789
10. [10]
  [10] Herberhold M, Yan H, Milius W, et al. Angew. Chem. Int. Ed., 1999, 38:3689-3691
11. [11]
  [11] Herberhold M, Yan H, Milius W, et al. Z. Anorg. Allg. Chem., 2000, 626:1627-1633
12. [12]
  [12] Kim D H, Ko J, Park K, et al. Organometallics, 1999, 18: 2738-2740
13. [13]
  [13] Won J H, Kim D H, Kim B Y, et al. Organometallics, 2002, 21:1443-1453
14. [14]
  [14] Zhang R, Zhu L, Liu G F, et al. J. Am. Chem. Soc., 2012, 134:10341-10344
15. [15]
  [15] Frith S A, Spencer J L. Inorg. Synth., 1990, 28:273-280
16. [16]
  [16] Hou X F, Wang X, Wang J Q, et al. J. Organomet. Chem., 2004, 689:2228-2235
17. [17]
  [17] Sheldrick G M. SADABS, An Empirical Absorption Correction Program, Bruker Analytical X-ray Systems, Madison, WI, 1996.
18. [18]
  [18] Sheldrick G M. SHELXS-97, Program for Crystal Structure Solution, University of Göttingen, Göttingen, Germany, 1997.
19. [19]
  [19] Sheldrick G M. SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Göttingen, Germany, 1997.
20. [20]
  [20] Boese R, Blaser D, Niederprum N, et al. Angew. Chem. Int. Ed., 1992, 31:314-316
21. [21]
  [21] Yao H J, Grimes R N. Organometallics, 2003, 22:4539-4546
22. [22]
  [22] Russell J M, Sabat H, Grimes R N. Organometallics, 2002, 21:5613-5621
23. [23]
  [23] Yan H, Beatty A M, Fehlner T P. Angew. Chem. Int. Ed., 2001, 40:4498-4501
24. [24]
  [24] Yan H, Beatty A M, Fehlner T P. Angew. Chem. Int. Ed., 2002, 41:2578-2581
25. [25]
  [25] Yan H, Beatty A M, Fehlner T P. J. Am. Chem. Soc., 2002, 124:10280-10281
26. [26]
  [26] Zhang R, Zhu L, Lu Z Z, et al. Dalton Trans., 2012, 41: 12054-12063
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Cobalt(Ⅲ)-Mediated Intramolecular Coupling of B(3)/B(6) in CpCoS₂C₂B₁₀H₁₀ with Cp Ligand