Citation: LI Zhong-Feng, ZHANG Yan-Ru, CUI Yang-Zhe, GENG Wen-Xiao, LIU Min, JIN Qiong-Hua. Syntheses, Crystal Structures and Spectroscopic Properties of Two Benzothiazoline-2-thione-Based Complexes for Silver(Ⅰ)[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1637-1643. doi: 10.11862/CJIC.2015.195 shu

Syntheses, Crystal Structures and Spectroscopic Properties of Two Benzothiazoline-2-thione-Based Complexes for Silver(Ⅰ)

1.
1. Department of Chemistry, Capital Normal University, Beijing 100048, China;
2.
2. The College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China

Corresponding author: JIN Qiong-Hua,
Received Date: 21 April 2015
Available Online: 13 May 2015
Fund Project: 国家自然科学基金(No.21171119) (No.21171119)863国家高技术研究发展计划(No.2012AA063201) (No.2012AA063201)北京教育委员会基金(No.KM201210028020) (No.KM201210028020)北京市优秀人才项目(No.2010D005016000002) (No.2010D005016000002)北京市自然科学基金(No.7122015)资助项目。 (No.7122015)

Two silver(Ⅰ) complexes with heterocyclic thione, [AgCl(PPh₃)₂(BTZT)]₂ (1) and [Ag(PPh₃)₂(BTZT)₂](NO₃)·CH₃OH (2) (PPh₃=triphenylphosphine; BTZT=benzothiazoline-2-thione) have been synthesized and characterized by IR, single-crystal X-ray diffraction, fluorescence spectrum and ¹H NMR spectroscopy. Heterocyclic thiones possess chemically active groups -N(H)-C(=S)- in equilibrium with its thiol form. 1 and 2 are obtained by the reactions of AgCl or AgNO₃ with PPh₃ in the presence of 2-mercaptobenzothiazole (MBT) in mixed solvent (CH₃OH/CH₂Cl₂). The complex 1 contains two same structures in each asymmetric unit, but there are different bond lengths and bond angles. Complex 2 is a simple mono-nuclear heteroleptic complex whose main structure links free CH₃OH and NO₃^- anion by hydrogen bonding interactions. The red-shift of emission peak of 1~2 is derived from ligand-centered π-π^* transition. CCDC: 1059719, 1; 1059720, 2.
- silver;triphenylphosphine;2-mercaptobenzothiazole;benzothiazoline-2-thione
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