Citation: LI Zhong-Feng, ZHANG Yan-Ru, CUI Yang-Zhe, GENG Wen-Xiao, LIU Min, JIN Qiong-Hua. Syntheses, Crystal Structures and Spectroscopic Properties of Two Benzothiazoline-2-thione-Based Complexes for Silver(Ⅰ)[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1637-1643. doi: 10.11862/CJIC.2015.195 shu

Syntheses, Crystal Structures and Spectroscopic Properties of Two Benzothiazoline-2-thione-Based Complexes for Silver(Ⅰ)

1.
1. Department of Chemistry, Capital Normal University, Beijing 100048, China;
2.
2. The College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China

Corresponding author: JIN Qiong-Hua,
Received Date: 21 April 2015
Available Online: 13 May 2015
Fund Project: 国家自然科学基金(No.21171119) (No.21171119)863国家高技术研究发展计划(No.2012AA063201) (No.2012AA063201)北京教育委员会基金(No.KM201210028020) (No.KM201210028020)北京市优秀人才项目(No.2010D005016000002) (No.2010D005016000002)北京市自然科学基金(No.7122015)资助项目。 (No.7122015)

Two silver(Ⅰ) complexes with heterocyclic thione, [AgCl(PPh₃)₂(BTZT)]₂ (1) and [Ag(PPh₃)₂(BTZT)₂](NO₃)·CH₃OH (2) (PPh₃=triphenylphosphine; BTZT=benzothiazoline-2-thione) have been synthesized and characterized by IR, single-crystal X-ray diffraction, fluorescence spectrum and ¹H NMR spectroscopy. Heterocyclic thiones possess chemically active groups -N(H)-C(=S)- in equilibrium with its thiol form. 1 and 2 are obtained by the reactions of AgCl or AgNO₃ with PPh₃ in the presence of 2-mercaptobenzothiazole (MBT) in mixed solvent (CH₃OH/CH₂Cl₂). The complex 1 contains two same structures in each asymmetric unit, but there are different bond lengths and bond angles. Complex 2 is a simple mono-nuclear heteroleptic complex whose main structure links free CH₃OH and NO₃^- anion by hydrogen bonding interactions. The red-shift of emission peak of 1~2 is derived from ligand-centered π-π^* transition. CCDC: 1059719, 1; 1059720, 2.
- silver;triphenylphosphine;2-mercaptobenzothiazole;benzothiazoline-2-thione
1. [1]
  [1] Katagiri K, Sakai T, Hishikawa M, et al. Cryst. Growth Des., 2014,14:199-206
2. [2]
  [2] Kim E, Lee H, Noh T H, et al. Cryst. Growth Des., 2014,14:1888-1894
3. [3]
  [3] Nitsch J, Kleeberg C, Frhlichc R, et al. Dalton Trans., 2015, 44:6944-6960
4. [4]
  [4] Rajput G, Yadav M K, Drew M G B, et al. Inorg. Chem., 2015,54:2572-2579
5. [5]
  [5] Pallavicini P, Dacarroa G, Diaz-Fernandezb Y A, et al. Coord. Chem. Rev., 2014,275:37-53
6. [6]
  [6] Saira N, Stefano A S, Anita T, et al. Inorg. Chem., 2014,53:2404-2416
7. [7]
  [7] Qin L, Xiao S L, Ma P J, et al. Transition Met. Chem., 2013, 38:627-633
8. [8]
  [8] Karagiannidis P, Aslanidis P. Inorg. Chim. Acta, 1990,172:241-251
9. [9]
  [9] Lobana T S, Sultana R, Butcher R J, et al. Z. Anorg. Allg. Chem., 2014,640:1688-1695
10. [10]
  [10] Chen S C, Yu R M, Zhao Z G, et al. Cryst. Growth Des., 2010,10:1155-1160
11. [11]
  [11] Yue C Y, Yan C F, Feng R, et al. Inorg. Chem., 2009,48:2873-2879
12. [12]
  [12] Jin Q H, Zhou L L, Xu L J, et al. J. Chem. Crystallogr., 2010,40:432-436
13. [13]
  [13] Kyros L, Banti C N, Kourkoumelis N, et al. J. Biol. Inorg. Chem., 2014,19:449-464
14. [14]
  [14] McFarlane W, Akrivos P D, Aslanidis P, et al. Inorg. Chim. Acta, 1998,281:121-125
15. [15]
  [15] SMART and SAINT, Siemens Analytical X-ray Instrument Inc., Madison:WI, 1996.
16. [16]
  [16] Sheldrick G M. SHELXS-97 and SHELXL-97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany, 1997.
17. [17]
  [17] Lobana T S, Kumari P, Kaur I, et al. J. Coord. Chem., 2012, 65:1750-1764
18. [18]
  [18] Lobana T S, Sultana R, Butcher R J, et al. J. Organomet. Chem., 2013,745-746:460-469
19. [19]
  [19] Zhang Y Y, Wang Y, Tao X, et al. Polyhedron, 2008,27:2501-2505
20. [20]
  [20] Isab A A, Nawaz S, Saleem M, et al. Polyhedron, 2010,29:1251-1256
21. [21]
  [21] Christofidis G, Cox P J, Aslanidis P. Polyhedron, 2012,31:502-505
22. [22]
  [22] Huang X, Li Z F, Qiu Q M. et al. Polyhedron, 2013,65:129-135
1. [1]
  Laiying Zhang , Yaxian Zhu . Exploring the Silver Family. University Chemistry, 2024, 39(9): 1-4. doi: 10.12461/PKU.DXHX202409015
2. [2]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
3. [3]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
4. [4]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
5. [5]
  Anqiu LIU , Long LIN , Dezhi ZHANG , Junyu LEI , Kefeng WANG , Wei ZHANG , Junpeng ZHUANG , Haijun HAO . Synthesis, structures, and catalytic activity of aluminum and zinc complexes chelated by 2-((2,6-dimethylphenyl)amino)ethanolate. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 791-798. doi: 10.11862/CJIC.20230424
6. [6]
  Kangmin Wang , Liqiu Wan , Jingyu Wang , Chunlin Zhou , Ke Yang , Liang Zhou , Bijin Li . Multifunctional 2-(2′-hydroxyphenyl)benzoxazoles: Ready synthesis, mechanochromism, fluorescence imaging, and OLEDs. Chinese Chemical Letters, 2024, 35(10): 109554-. doi: 10.1016/j.cclet.2024.109554
7. [7]
  Aidang Lu , Yunting Liu , Yanjun Jiang . Comprehensive Organic Chemistry Experiment: Synthesis and Characterization of Triazolopyrimidine Compounds. University Chemistry, 2024, 39(8): 241-246. doi: 10.3866/PKU.DXHX202401029
8. [8]
  Wanmin Cheng , Juan Du , Peiwen Liu , Yiyun Jiang , Hong Jiang . Photoinitiated Grignard Reagent Synthesis and Experimental Improvement in Triphenylmethanol Preparation. University Chemistry, 2024, 39(5): 238-242. doi: 10.3866/PKU.DXHX202311066
9. [9]
  Yihao Zhao , Jitian Rao , Jie Han . Synthesis and Photochromic Properties of 3,3-Diphenyl-3H-Naphthopyran: Design and Teaching Practice of a Comprehensive Organic Experiment. University Chemistry, 2024, 39(10): 149-155. doi: 10.3866/PKU.DXHX202402050
10. [10]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
11. [11]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
12. [12]
  Yue Li , Minghao Fan , Conghui Wang , Yanxun Li , Xiang Yu , Jun Ding , Lei Yan , Lele Qiu , Yongcai Zhang , Longlu Wang . 3D layer-by-layer amorphous MoS_x assembled from [Mo₃S₁₃]^2- clusters for efficient removal of tetracycline: Synergy of adsorption and photo-assisted PMS activation. Chinese Chemical Letters, 2024, 35(9): 109764-. doi: 10.1016/j.cclet.2024.109764
13. [13]
  Jian Jin , Jing Cheng , Xueping Yang . Integration Practice of Organic Chemistry Experiment and Safety Education: Taking the Synthesis of Triphenylmethanol as an Example. University Chemistry, 2024, 39(3): 345-350. doi: 10.3866/PKU.DXHX202309010
14. [14]
  Qijin Mo , Meifang Zhuo , Zhiyi Zhong , Chunfang Gan , Lixia Zhang . Research-Oriented Experimental Teaching in Chemistry Education at Normal University: Taking the Project of Recovering Silver Nitrate from Silver-Containing Waste as an Example. University Chemistry, 2024, 39(6): 201-206. doi: 10.3866/PKU.DXHX202310099
15. [15]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
16. [16]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
17. [17]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
18. [18]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
19. [19]
  Yuanyi Lu , Jun Zhao , Hongshuang Li . Silver-Catalyzed Ring-Opening Minisci Reaction: Developing a Teaching Experiment Suitable for Undergraduates. University Chemistry, 2024, 39(11): 225-231. doi: 10.3866/PKU.DXHX202401088
20. [20]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(175)
HTML views(13)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142