Citation: WANG Ying, XUE Bing, LI Yi-Lin, LI Si-Nan, XU Chong-Fu. Extensive Hydrosilation of Acetyl Manganese Pentacarbonyl[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1393-1401. doi: 10.11862/CJIC.2015.194 shu

Extensive Hydrosilation of Acetyl Manganese Pentacarbonyl

WANG Ying ^1,2 ,
XUE Bing ¹ ,
LI Yi-Lin ¹ ,
LI Si-Nan ¹ ,
XU Chong-Fu ^1,2,,

1.
1 College of Petrochemical Engineering of Changzhou University, Changzhou, Jiangsu 213164, China;
2.
2 Jiangsu Province Key Laboratory of Green Catalytic Materials and Technologies Changzhou, Jiangsu 213164, China

Corresponding author: XU Chong-Fu,
Received Date: 23 March 2015
Available Online: 22 May 2015
Fund Project: 国家自然科学基金(No.21376032)资助项目。 (No.21376032)

(CO)₅MnCOCH₃ (1) was synthesized in two steps. A solution 1 with Me₂PhSiH in C₆D₆ was continuously monitored by ¹H NMR spectroscopy for 9 h and reaction profile was established using timely contents (mmol) obtained by directly integrating chemical labels of the reactants and derivatives against that of the internal standard C₆H₅(CH₂)₂C₆H₅. 9 intermediates and final products emerged in the extensive hydrosilation were prepared and the molecular structures of the derivations generated in the reaction process were positively confirmed by comparison of their NMR spectra with that of real substances. All besides the 6 species that were quantified by direct integration of their chemical labels the other 3 were indirectly quantified by combination of chemical stoichiometry and integration of their chemical labels. Attempt was made to make plausible explanations for the origins of these species. Finally, a mechanism with multiple step reactions process and double pathways was proposed. More than 90.7% of the total manganese source was accounted for at 9 h and meanwhile that of more than 91.4% of the total silicon source was accounted for.
- hydrosilation;integrating chemical labels;multiple step process;double pathways mechanism
1. [1]
  [1] Gregg B T, Hanna P K, Crawford E J, et al. J. Am. Chem. Soc., 1991, 113(47):384-385
2. [2]
  [2] Hanna P K, Gregg B T, CutlerA R. Organometallics, 1991, 10(1):31-33
3. [3]
  [3] Ziegler T, Verslius L, Tschinke V J. J. Am. Chem. Soc., 1986, 108(21):612-614
4. [4]
  [4] Axe F U, Marynick D S. Organometallics, 1987, 6(17):572-575
5. [5]
  [5] Wegman R W. Organometallics, 1986, 5(3):707-710
6. [6]
  [6] Kovacs I, Sisak A, Ungvary F, et al. Organometallics, 1988, 7 (10):1025-1029
7. [7]
  [7] Glaysz J A. Acc. Chem. Res., 1984, 17(57):326-330
8. [8]
  [8] Selover J C, Vaughn G D, Strouse C E, et al. J. Am. Chem. Soc., 1986, 108(11):1455-1457
9. [9]
  [9] Vaughn G D, Glaysz J A. J. Am. Chem. Soc., 1986, 108(35): 1473-1475
10. [10]
  [10] Gregg B T, Cutler A R. J. Am. Chem. Soc., 1996, 118, 42 (19):10069-10084
11. [11]
  [11] Krein K A, Gladysz J A. Organometallics, 1986, 5(15):936-940
12. [12]
  [12] Mars M, Brinkman K C, Lisensky C A, et al. J. Org. Chem., 1985, 50(24):3396-3398
13. [13]
  [13] XU Chong-Fu(徐崇福), FANG Jun-Zhuo(房俊卓), CHEN Miao(陈苗), et al. Acta Chim. Sin.(化学学报), 2008, 66(10): 1239-1244
14. [14]
  [14] Gregg B T, Cutler A R. Organometallics, 1994, 13(9):1039-1043
15. [15]
  [15] XU Chong-Fu(徐崇福), FANG Jun-Zhuo(房俊卓), XUE Bing (薛冰), et al. Acta Chim. Sin.(化学学报), 2011, 69(8):999-1006
16. [16]
  [16] Gladysz J A, Williams G M, Tam W, et al. Inorg. Chem., 1979, 18(3):553-558
17. [17]
  [17] Warner K E, Norton J R. Organometallics, 1985, 4(16):2150-2154
18. [18]
  [18] Tan K Y D, Teng G F, Fan W Y. Organometallics, 2011, 30 (15):4136-4143
19. [19]
  [19] Anderson G K. Acc. Chem. Res., 1984, 17(21):67-74
20. [20]
  [20] Gregg B T, Cutler A R. Organometallics, 1998, 17(32):4169-4175
21. [21]
  [21] Gray L M, Donald A T. Inorganic Chemistry. New Jersey: Prentice Hall, 1999:297
22. [22]
  [22] Gregg B T, Cutler A R. J. Am. Chem. Soc., 1995, 117(10): 10139-10140
23. [23]
  [23] Mao Z, Gregg B T, Cutler A R. Organometallics, 1998, 17(10): 1993-2002
24. [24]
  [24] Green M L H, Nagy P L I. J. Organomet. Chem., 1963, 1(27): 58-60
25. [25]
  [25] Xu C F, Anderson G K A. Organometallics, 1996, 15(7):1760-1764
26. [26]
  [26] XU Chong-Fu(徐崇福), FANG Jun-Zhuo(房俊卓), XUE Bing (薛冰), et al. Acta Chim. Sin.(化学学报), 2009, 67(20):2355-2362
27. [27]
  [27] LI Rong (厉荣), CHEN Peng-Gang(陈鹏刚). Chinese J. Inorg. Chem.(无机化学学报), 2008, 24(20):657-660
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