Citation: ZHAI Chang-Wei, CHENG Mei-Ling, HAN Wei, LIU Qi. Syntheses, Crystal Structures and Luminescent Properties of Manganese and Cadmium Complexes Based on 5-Methyl-1H-Pyrazole-3-Carboxylic Acid and Phenanthroline Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1409-1416. doi: 10.11862/CJIC.2015.193 shu

Syntheses, Crystal Structures and Luminescent Properties of Manganese and Cadmium Complexes Based on 5-Methyl-1H-Pyrazole-3-Carboxylic Acid and Phenanthroline Ligands

ZHAI Chang-Wei ¹ ,
CHENG Mei-Ling ¹ ,
HAN Wei ¹ ,
LIU Qi ^1,2,,

1.
1 School of Petrochemical Engineering and Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Changzhou University, Changzhou, Jiangsu 213164, China;
2.
2 State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China

Corresponding author: LIU Qi,
Received Date: 28 January 2015
Available Online: 13 May 2015
Fund Project: 国家自然科学基金(No.20971060, 21101018) (No.20971060, 21101018)

One monomeric complex [Mn(HMPCA)₂(phen)]·2H₂O (1) and one 1D coordination polymer [Cd₂(HMPCA)₂ (phen)₂(H₂O)₂]·2H₂O (2) with binuclear structural unit (H₂MPCa=5-methyl-1H-pyrazole-3-carboxylic acid, phen=phenanthroline) have been synthesized and characterized by elemental analysis, IR spectra, thermogravimetric analysis and single crystal X-ray diffraction. Complex 1 crystallizes in the triclinic system, space group P1, while 2 in the orthorhombic system, space group Pccn. In 1, Mn(Ⅱ) ion located in a distorted octahedral coordination geometry, discrete water molecules and mononucleate units are assembled into a 3D supramolecular network. In 2, each Cd(Ⅱ) ion located in a pentagonal bipyramid geometry. Each carboxyl group from HMPA- anion bridges two adjacent Cd(Ⅱ) ions, forming a 1D chain. These chains and water molecules are connected by hydrogen bonds, forming a 3D supramolecular framework. The thermal stability and luminescent properties of them are also investigated. CCDC: 1044243, 1; 1044244, 2.
- manganese(Ⅱ);cadmium(Ⅱ);5-methyl-1H-pyrazole-3-carboxylic acid;crystal structure;photoluminescence
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