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Citation: ZHANG Qiu-Lin, XU Li-Si, LIU Xin, NING Ping. Effect of P123 on Structure and CO Catalytic Oxidation Performance of CuO-CeO2 Catalysts[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1555-1562. doi: 10.11862/CJIC.2015.192 shu

Effect of P123 on Structure and CO Catalytic Oxidation Performance of CuO-CeO2 Catalysts

  • 1.

    Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China

  • Corresponding author: NING Ping, 
  • Received Date: 13 March 2015
    Available Online: 25 May 2015

    Fund Project: 国家自然科学基金(No.21307047、U1137603)资助项目。 (No.21307047、U1137603)

  • A series of CuO-CeO2 (nCu:nCe=1:9, 2:8, 3:7, 4:6, 5:5, 6:4, 7:3) catalysts with different Cu/Ce molar ratios (nCu:nCe) were prepared by soft template hydrothermal method. The effect of nCu:nCe and preparation methods (soft template hydrothermal method and co-precipitation without template method) on CO catalytic oxidation performance was investigated, and the structure, reduction features and surface chemical states of the CuO-CeO2 catalysts were characterized by XRD, TEM, low temperature adsorption-desorption, temperature programmed reduction (H2-TPR) and XPS. The results show that with the increase of nCu:nCe, the CO catalytic oxidation activities of CuO-CeO2 catalysts increase firstly and then decrease. When the nCu:nCe is 5:5, the CO catalytic oxidation activity of the catalyst is more than 90% at 100℃. The large specific surface area, narrow pore structure distribution, high dispersion of active CuO species and the strong interaction between CuO and CeO2 of CuO-CeO2 catalyst prepared by soft template hydrothermal method are the main factors for its excellent CO catalytic oxidation activity.
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