Citation: CHU Zhao-Hua, XIE Qing-Fan, LI Ying-Qian, CHEN Yan-Min. Syntheses, Crystal Structures and Properties of Copper(Ⅱ) and Nickel(Ⅱ) Complexes Based on Nicotinoyl Hydrazone Schiff Base[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1380-1386. doi: 10.11862/CJIC.2015.189
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The copper(Ⅱ) and nickel(Ⅱ) complexes of nicotinoyl hydrazone Schiff base, [Cu(Py)(HL1)]2 (1) and [Ni(L2)2] (2), where H3L1 is pyridine-3-carboxylic acid (2,4-dihydroxy-benzylidene)hydrazide, HL2 is pyridine-3-carboxylic acid (pyridine-2-yl ethylidyne)hydrazide, were respectively synthesized by slow evaporation methods in mixed-solvent, and characterized by elemental analysis, IR, UV-Vis, FL spectra, TGA and single crystal X-ray diffraction. The crystals of 1 and 2 belongs to the monoclinic system, space group P21/c with cell parameters (1) a=0.739 86(12) nm, b=1.903 7(3) nm, c=1.154 86(19) nm, β=105.090(3)°, V=1.570 5(4) nm3 and (2) a=2.034 0(5) nm, b=1.183 2(3) nm, c=1.020 7(3) nm, V=2.456 1(11) nm3. The complex 1 is a centrosymmetric binuclear complex with Cu(Ⅱ) ions in square pyramidal geometry. The structure units of 1 are linked by intermolecular π-π interactions and O-H…N hydrogen bonds, forming three-dimensional supermolecular network. In 2, the Ni(Ⅱ) ions act as distorted octahedral geometry, being surrounded by two imine nitrogen atoms, two deprotonated amide oxygen atoms and two pyridyl nitrogen atoms from two monovalence anions of HL2 ligand. The tests showed the two complexes displayed good thermal stability below 315 ℃ (1)和358 ℃ (2), respectively.
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