Citation: CHU Zhao-Hua, XIE Qing-Fan, LI Ying-Qian, CHEN Yan-Min. Syntheses, Crystal Structures and Properties of Copper(Ⅱ) and Nickel(Ⅱ) Complexes Based on Nicotinoyl Hydrazone Schiff Base[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1380-1386. doi: 10.11862/CJIC.2015.189 shu

Syntheses, Crystal Structures and Properties of Copper(Ⅱ) and Nickel(Ⅱ) Complexes Based on Nicotinoyl Hydrazone Schiff Base

1.
1 Department of Chemistry, HanShan Normal University, Chaozhou, Guangdong 521041, China;
2.
2 College of Chemistry & Life Science, Quanzhou Normal University, Quanzhou, Fujian 362000, China

Corresponding author: CHEN Yan-Min,
Received Date: 11 April 2015
Available Online: 27 May 2015
Fund Project: 福建省教育厅A类重点项目(No.JA14261) (No.JA14261) 2014年国家级大学生创新创业训练计划项目(No.201410399017)资助。 (No.201410399017)

The copper(Ⅱ) and nickel(Ⅱ) complexes of nicotinoyl hydrazone Schiff base, [Cu(Py)(HL¹)]₂ (1) and [Ni(L²)₂] (2), where H₃L¹ is pyridine-3-carboxylic acid (2,4-dihydroxy-benzylidene)hydrazide, HL² is pyridine-3-carboxylic acid (pyridine-2-yl ethylidyne)hydrazide, were respectively synthesized by slow evaporation methods in mixed-solvent, and characterized by elemental analysis, IR, UV-Vis, FL spectra, TGA and single crystal X-ray diffraction. The crystals of 1 and 2 belongs to the monoclinic system, space group P2₁/c with cell parameters (1) a=0.739 86(12) nm, b=1.903 7(3) nm, c=1.154 86(19) nm, β=105.090(3)°, V=1.570 5(4) nm³ and (2) a=2.034 0(5) nm, b=1.183 2(3) nm, c=1.020 7(3) nm, V=2.456 1(11) nm³. The complex 1 is a centrosymmetric binuclear complex with Cu(Ⅱ) ions in square pyramidal geometry. The structure units of 1 are linked by intermolecular π-π interactions and O-H…N hydrogen bonds, forming three-dimensional supermolecular network. In 2, the Ni(Ⅱ) ions act as distorted octahedral geometry, being surrounded by two imine nitrogen atoms, two deprotonated amide oxygen atoms and two pyridyl nitrogen atoms from two monovalence anions of HL₂ ligand. The tests showed the two complexes displayed good thermal stability below 315 ℃ (1)和358 ℃ (2), respectively.
- nicotinoyl hydrazone;complexes;crystal structure;thermal stability
1. [1]
  [1] Bazzicalupi C, Bencini A, Bianchi A, et al. Coord. Chem. Rev., 2008, 252:1052-1068
2. [2]
  [2] Saadeh H A, Shaireh E A A, Mosleh I M, et al. Med. Chem. Res., 2012, 21:2969-2974
3. [3]
  [3] Grivani G, Ghavami A, Kueráková M, et al. J Mol. Struct., 2014, 1076(5):326-332
4. [4]
  [4] Ray S, Konar S, Jana A, et al. J. Mol. Struct., 2014, 1058 (24):213-220
5. [5]
  [5] WANG Yan(王彦), LIU Guang-Xiang(刘光祥). Chinese J. Inorg. Chem.(无机化学学报), 2009, 25(4):713-719
6. [6]
  [6] HUO Yong-Qian(霍涌前), WANG Sheng-Wen(王升文), CUI Hua-Li(崔华莉), et al. Chinese J. Inorg. Chem.(无机化学学报), 2010, 26(7):1274-1278
7. [7]
  [7] Qin X T, Ding S, Xu X B, et al. Polyhedron, 2014, 83(24): 36-43
8. [8]
  [8] Ainscough E W, Brodie A M, Dobbs A J, et al. Inorg. Chim. Acta, 1998, 267:27-38
9. [9]
  [9] Richardson D R, Becker E, Bernhardt P V. Acta Cryst., 1999, C55:2102-2105
10. [10]
  [10] XIE Qing-Fan(解庆范), GAO Ping-Zhang(高平章), CHEN Yan-Min(陈延民). Chinese J. Inorg. Chem.(无机化学学报), 2014, 30(10):2382-2388
11. [11]
  [11] CHEN Yan-Min(陈延民), XIE Qing-Fan(解庆范), WEI Zan-Bin(魏赞斌), et al. Chinese J. Inorg. Chem.(无机化学学报), 2014, 30(6):1243-1249
12. [12]
  [12] Ebrahimipour S Y, Khabazadeh H, Castro J, et al. Inorg. Chim. Acta, 2015, 427:52-61
13. [13]
  [13] You Z L, Shi D H, Zhang J C, et al. Inorg. Chim. Acta, 2012, 384:54-61
14. [14]
  [14] Mondal S, Naskar S, Dey A K, et al. Inorg. Chim. Acta, 2013, 398:98-105
15. [15]
  [15] Khandar A A, Afkhami F A, Hosseini-Yazdi S A, et al. Inorg. Chim. Acta, 2015, 427:87-96
16. [16]
  [16] Yi L J, Xu G C, Zhang L, et al. Inorg. Chem. Commun., 2014, 45:6-39
17. [17]
  [17] CHEN Yan-Min(陈延民), XIE Qing-Fan(解庆范), LIU Jin-Hua(刘金花), et al. Chinese J. Inorg. Chem.(无机化学学报), 2015, 31(1):74-80
18. [18]
  [18] Sheldrick G M. SHELX-97, Program for X-ray Crystal Structure Solution and Refinement, University of Göttingen, Germany, 1997.
19. [19]
  [19] Sheldrick G M. SHELXTL, Program for X-ray Crystal Structure Solution and Refinement, University of Göttingen, Germany, 1997.
20. [20]
  [20] WANG Hui(王慧), GAN Guo-Qing(甘国庆), QU Yang(瞿阳), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012, 28 (6):1217-1221
21. [21]
  [21] WU Qiong-Jie(吴琼洁), CHEN Xiao-Hua(陈小华), CAI Bi-Qiong(蔡碧琼), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012, 28(1):201-206
22. [22]
  [22] ZHENG Chang-Zheng(郑长征), WANG Yan-Yan(王燕燕), WANG Liang(王亮). Chinese J. Inorg. Chem.(无机化学学报), 2014, 30(7):1474-1480
23. [23]
  [23] QIU Xiao-Yang(仇晓阳). Chinese J. Inorg. Chem.(无机化学学报), 2014, 30(7):1667-1672
1. [1]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
2. [2]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
3. [3]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
4. [4]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
5. [5]
  Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr_1-xZrSi₂O₇∶xDy³⁺ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096
6. [6]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
7. [7]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
8. [8]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
9. [9]
  Zuozhong Liang , Lingling Wei , Yiwen Cao , Yunhan Wei , Haimei Shi , Haoquan Zheng , Shengli Gao . Exploring the Development of Undergraduate Scientific Research Ability in Basic Course Instruction: A Case Study of Alkali and Alkaline Earth Metal Complexes in Inorganic Chemistry. University Chemistry, 2024, 39(7): 247-263. doi: 10.3866/PKU.DXHX202310103
10. [10]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
11. [11]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
12. [12]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
13. [13]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
14. [14]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
15. [15]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
16. [16]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
17. [17]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
18. [18]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
19. [19]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
20. [20]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(279)
HTML views(18)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142