Citation: CHU Zhao-Hua, XIE Qing-Fan, LI Ying-Qian, CHEN Yan-Min. Syntheses, Crystal Structures and Properties of Copper(Ⅱ) and Nickel(Ⅱ) Complexes Based on Nicotinoyl Hydrazone Schiff Base[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1380-1386. doi: 10.11862/CJIC.2015.189 shu

Syntheses, Crystal Structures and Properties of Copper(Ⅱ) and Nickel(Ⅱ) Complexes Based on Nicotinoyl Hydrazone Schiff Base

1.
1 Department of Chemistry, HanShan Normal University, Chaozhou, Guangdong 521041, China;
2.
2 College of Chemistry & Life Science, Quanzhou Normal University, Quanzhou, Fujian 362000, China

Corresponding author: CHEN Yan-Min,
Received Date: 11 April 2015
Available Online: 27 May 2015
Fund Project: 福建省教育厅A类重点项目(No.JA14261) (No.JA14261) 2014年国家级大学生创新创业训练计划项目(No.201410399017)资助。 (No.201410399017)

The copper(Ⅱ) and nickel(Ⅱ) complexes of nicotinoyl hydrazone Schiff base, [Cu(Py)(HL¹)]₂ (1) and [Ni(L²)₂] (2), where H₃L¹ is pyridine-3-carboxylic acid (2,4-dihydroxy-benzylidene)hydrazide, HL² is pyridine-3-carboxylic acid (pyridine-2-yl ethylidyne)hydrazide, were respectively synthesized by slow evaporation methods in mixed-solvent, and characterized by elemental analysis, IR, UV-Vis, FL spectra, TGA and single crystal X-ray diffraction. The crystals of 1 and 2 belongs to the monoclinic system, space group P2₁/c with cell parameters (1) a=0.739 86(12) nm, b=1.903 7(3) nm, c=1.154 86(19) nm, β=105.090(3)°, V=1.570 5(4) nm³ and (2) a=2.034 0(5) nm, b=1.183 2(3) nm, c=1.020 7(3) nm, V=2.456 1(11) nm³. The complex 1 is a centrosymmetric binuclear complex with Cu(Ⅱ) ions in square pyramidal geometry. The structure units of 1 are linked by intermolecular π-π interactions and O-H…N hydrogen bonds, forming three-dimensional supermolecular network. In 2, the Ni(Ⅱ) ions act as distorted octahedral geometry, being surrounded by two imine nitrogen atoms, two deprotonated amide oxygen atoms and two pyridyl nitrogen atoms from two monovalence anions of HL₂ ligand. The tests showed the two complexes displayed good thermal stability below 315 ℃ (1)和358 ℃ (2), respectively.
- nicotinoyl hydrazone;complexes;crystal structure;thermal stability
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