Citation: LIU Feng-Xian, SHAO Meng-Meng, XIA Sheng-Jie, NI Zhe-Ming. Adsorption to Acid Red 14 in Wastewater by ZnCr Bimetal Layered Materials[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1342-1350. doi: 10.11862/CJIC.2015.187 shu

Adsorption to Acid Red 14 in Wastewater by ZnCr Bimetal Layered Materials

1.
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China

Corresponding author: NI Zhe-Ming,
Received Date: 1 February 2015
Available Online: 13 May 2015
Fund Project: 浙江省自然科学基金(No.LQ15B030002)资助项目。 (No.LQ15B030002)

Zinc chrome bimetal layered materials (Zn_xCr-LDHs, x=2, 3, 4) were successfully synthesized by the coprecipitation method and different factors on the adsorption of AR14 were also investigated. The characterization of XRD, ICP, FTIR and BET revealed that the crystal structures of Zn_xCr-LDHs (x=2, 3, 4) were very good and stable, it had the mesoporous structure. Experimental results indicated that the optimum sorbent was Zn₃Cr-LDHs with a specific surface area of 101 m²·g^-1, the maximum adsorption capacity for AR14 was 484.63 mg·g^-1. Moreover, lower pH value and higher temperature were favorable to the removal of AR14. Adsorption isotherms and kinetics showed that the adsorption process could be well fitted with the pseudo-second-order kinetic and Freundlich equation. Based on the analysis of Materials Studio 5.5 simulation, the adsorption menchanism was that AR14 were adsorbed on the surface of Zn₃Cr-LDHs, the -SO₃^- group was the reaction point.
- ZnCr layered double hydroxides;adsorption;acid red 14
1. [1]
  [1] Gao J F, Wang J H, Yang C, et al. Chem. Eng. J., 2011, 171 (3):967-975
2. [2]
  [2] Wang S, Choon W N, Wang W, et al. Chem. Eng. J., 2012, 197:34-40
3. [3]
  [3] Arami M, Limaee N Y, Mahmoodi N M, et al. J. Hazard. Mater., 2006, 135(1/2/3):171-179
4. [4]
  [4] Arami M, Limaee N Y, Mahmoodi N M. Chem. Eng. J., 2008, 139(1):2-10
5. [5]
  [5] Valderrama C, Cortina J L, Farran A, et al. React. Funct. Polym., 2008, 68(3):679-691
6. [6]
  [6] CHEN Shu-Wei(陈树薇), SHI Wen-Jian(施文健), SONG Wei(宋伟), et al. J. Funct. Mater.(功能材料), 2009, 40(4): 656-659
7. [7]
  [7] Mahmoodi N M, Khorramfar S, Najafi F. Desalination, 2011, 279(1/2/3):61-68
8. [8]
  [8] Mahmoodi N M, Najafi F. Microporous Mesoporous Mater., 2012, 156:153-160
9. [9]
  [9] Mahmoodi N M, Masrouri O, Arabi A M. J. Alloys Compd., 2014, 602:210-220
10. [10]
  [10] Gennequin C, Barakat T, Tidahy H L, et al. Catal. Today, 2010, 157(1/2/3/4):191-197
11. [11]
  [11] Zhang C, Yang S G, Chen H Z, et al. Appl. Surf. Sci., 2014, 301:329-337
12. [12]
  [12] Jimenez-Nunez M L, Solache-Rios M, Chavez-Garduno J, et al. Chem. Eng. J., 2012, 181:371-375
13. [13]
  [13] Zhou J B, Cheng Y, Yu J G, et al. J. Mater. Chem., 2011, 21 (48):19353-19361
14. [14]
  [14] Yang K, Yan L G, Yang Y M, et al. Sep. Purif. Technol., 2014, 124:36-42
15. [15]
  [15] Ni Z M, Xia S J, Wang L G, et al. J. Colloid Interface Sci., 2007, 316(2):284-291
16. [16]
  [16] XUE Ji-Long(薛继龙), CAO Gen-Ting(曹根庭), NI Zhe-Ming(倪哲明). Chinese J. Inorg. Chem.(无机化学学报), 2012, 28(6):1117-1124
17. [17]
  [17] WANG Qiao-Qiao(王巧巧), NI Zhe-Ming(倪哲明), ZHANG Feng(张峰), et al. Chinese J. Inorg. Chem.(无机化学学报), 2009, 25(12):2156-2162
18. [18]
  [18] XUE Ji-Long(薛继龙), QIAN Ping-Ping(钱萍萍), NI Zhe-Ming(倪哲明). Chinese J. Inorg. Chem.(无机化学学报), 2014, 30(5):1009-1016
19. [19]
  [19] Gasser M S, Aly H F. Colloid Surf. A-Physicochem. Eng. Asp., 2009, 336(1/2/3):167-173
20. [20]
  [20] Zhou Z J, Wu Y Y, Liu C, et al. Environ. Sci. Technol., 2010, 44(23):8884-8890
21. [21]
  [21] Parida K, Mohapatra L. Dalton Trans., 2012, 41:1173-1178
22. [22]
  [22] Gunjakar J L, Kim T W, Kim H N, et al. J. Am. Chem. Soc., 2011, 133(38):14998-15007
23. [23]
  [23] Chen D, Li Y, Zhang J, et al. Chem. Eng. J., 2012, 185:120-126
24. [24]
  [24] Lan M, Fan G L, Yang L, et al. Ind. Eng. Chem. Res., 2014, 53:12943-12952
25. [25]
  [25] WANG Xiao-Rong(王小蓉), WU Ping-Xiao(吴平霄). Environ. Sci.(环境科学), 2012, 33(7):2432-2437
26. [26]
  [26] GU Jian-Jie(顾剑杰), WANG Yan-Feng(王炎锋), JIANG Ru (蒋茹), et al. Ind. Water & Wastewater(工业用水与废水), 2014, 45(2):9-13
27. [27]
  [27] Xia S J, Liu F X, Ni Z M, et al. J. Colloid Interface Sci., 2013, 405:195-200
28. [28]
  [28] Jiao F P, Chen X Q, Liu L, et al. J. Mol. Struct., 2010, 964 (1/2/3):152-157
29. [29]
  [29] Ai L H, Zhang C Y, Meng L Y. J. Chem. Eng. Data, 2011, 56(11):4217-4225
1. [1]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
2. [2]
  Hui Wang , Abdelkader Labidi , Menghan Ren , Feroz Shaik , Chuanyi Wang . 微观结构调控的g-C₃N₄在光催化NO转化中的最新进展：吸附/活化位点的关键作用. Acta Physico-Chimica Sinica, 2025, 41(5): 100039-. doi: 10.1016/j.actphy.2024.100039
3. [3]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
4. [4]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
5. [5]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097
6. [6]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
7. [7]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
8. [8]
  Wei Li , Jinfan Xu , Yongjun Zhang , Ying Guan . 共价有机框架整体材料的制备及食品安全非靶向筛查应用——推荐一个仪器分析综合化学实验. University Chemistry, 2025, 40(6): 276-285. doi: 10.12461/PKU.DXHX202406013
9. [9]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
10. [10]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
11. [11]
  Shuhong Xiang , Lv Yang , Yingsheng Xu , Guoxin Cao , Hongjian Zhou . Selective electrosorption of Cs(Ⅰ) from high-salinity radioactive wastewater using CNT-interspersed potassium zinc ferrocyanide electrodes. Acta Physico-Chimica Sinica, 2025, 41(9): 100097-0. doi: 10.1016/j.actphy.2025.100097
12. [12]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
13. [13]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
14. [14]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
15. [15]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
16. [16]
  Yaping Li , Sai An , Aiqing Cao , Shilong Li , Ming Lei . The Application of Molecular Simulation Software in Structural Chemistry Education: First-Principles Calculation of NiFe Layered Double Hydroxide. University Chemistry, 2025, 40(3): 160-170. doi: 10.12461/PKU.DXHX202405185
17. [17]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
18. [18]
  Jianan Zhang , Mengzhen Xu , Jiamin Liu , Yufei He . 面向“双碳”目标的脱氯吸附剂开发研究型综合实验设计. University Chemistry, 2025, 40(6): 248-255. doi: 10.12461/PKU.DXHX202408068
19. [19]
  Xueqi Yang , Juntao Zhao , Jiawei Ye , Desen Zhou , Tingmin Di , Jun Zhang . Modulating the d-band center of NNU-55(Fe) for enhanced CO₂ adsorption and photocatalytic activity. Acta Physico-Chimica Sinica, 2025, 41(7): 100074-0. doi: 10.1016/j.actphy.2025.100074
20. [20]
  Zhaoxuan ZHU , Lixin WANG , Xiaoning TANG , Long LI , Yan SHI , Jiaojing SHAO . Application of poly(vinyl alcohol) conductive hydrogel electrolytes in zinc ion batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 893-902. doi: 10.11862/CJIC.20240368

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(362)
HTML views(39)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142