Citation: LIU Feng-Xian, SHAO Meng-Meng, XIA Sheng-Jie, NI Zhe-Ming. Adsorption to Acid Red 14 in Wastewater by ZnCr Bimetal Layered Materials[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1342-1350. doi: 10.11862/CJIC.2015.187 shu

Adsorption to Acid Red 14 in Wastewater by ZnCr Bimetal Layered Materials

1.
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China

Corresponding author: NI Zhe-Ming,
Received Date: 1 February 2015
Available Online: 13 May 2015
Fund Project: 浙江省自然科学基金(No.LQ15B030002)资助项目。 (No.LQ15B030002)

Zinc chrome bimetal layered materials (Zn_xCr-LDHs, x=2, 3, 4) were successfully synthesized by the coprecipitation method and different factors on the adsorption of AR14 were also investigated. The characterization of XRD, ICP, FTIR and BET revealed that the crystal structures of Zn_xCr-LDHs (x=2, 3, 4) were very good and stable, it had the mesoporous structure. Experimental results indicated that the optimum sorbent was Zn₃Cr-LDHs with a specific surface area of 101 m²·g^-1, the maximum adsorption capacity for AR14 was 484.63 mg·g^-1. Moreover, lower pH value and higher temperature were favorable to the removal of AR14. Adsorption isotherms and kinetics showed that the adsorption process could be well fitted with the pseudo-second-order kinetic and Freundlich equation. Based on the analysis of Materials Studio 5.5 simulation, the adsorption menchanism was that AR14 were adsorbed on the surface of Zn₃Cr-LDHs, the -SO₃^- group was the reaction point.
- ZnCr layered double hydroxides;adsorption;acid red 14
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沈阳化工大学材料科学与工程学院沈阳 110142