Citation: HU Jia-Hua, DENG Wei, JIANG Xuan-Feng, YU Shu-Yan. Tuning Supramolecular Chiral Architecture of Molecular Corners from Achiral Dipalladium(Ⅱ) and Diplatinum(Ⅱ) Complexes with Achiral Anthracyl Pyrazole Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1278-1286. doi: 10.11862/CJIC.2015.185 shu

Tuning Supramolecular Chiral Architecture of Molecular Corners from Achiral Dipalladium(Ⅱ) and Diplatinum(Ⅱ) Complexes with Achiral Anthracyl Pyrazole Ligand

1.
1 Laboratory for Self-Assembly Chemistry, Department of Chemistry, Renmin University of China, Beijing 100872;
2.
2 Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Chemical Industry, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124

Corresponding author: YU Shu-Yan,
Received Date: 31 March 2015
Available Online: 31 May 2015
Fund Project: 国家自然科学基金(No.91127039, 21471011)资助项目。 (No.91127039, 21471011)

A novel kind of coordination molecular corners [M₂L₂] ([1=(bpy)Pd]₂L₂, 2=[(dmbpy)Pd]₂L₂, 3=[(phen)Pd]₂L₂, 4=[(ppy)Pt]₂L₂, where bpy=2,2'-bipyridine, dmbpy=4,4'-dimethyl-2,2'-bipyridine, phen=1,10-phenanthroline, ppy=2-phenylpyridine) was synthesized through synergistic metal-metal bonding interaction and spontaneous deprotonation from the pyrazole linkers 4-(4-(anthracen-9-yl)phenyl)-3,5-dimethyl-1H-pyrazole (L). Three complexes 1~3 were characterized by single crystal X-ray diffraction, ¹H and ¹³C NMR, ESI-MS and fluorescence spectroscopy. The neutral organometallic corner [(ppy)Pt]₂L₂ 4 was also determined by ¹H and ¹³C NMR, MALDI-TOF-MS and fluorescence spectroscopy. These achiral molecular corners assemble from different achiral dimetallic centers with the achiral ligand HL in quite different crystal structures, in particular, 3 with a [(phen)Pd]₂ assembling center crystallizes into a supramolecular chiral architecture.
- molecular corners;palladium (Ⅱ);platinum(Ⅱ);supramolecular chirality;metal-metal bonding interaction
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