Advanced Search

Citation: ZHANG Ruo-Ran, WU Xiao-Mei, ZENG Xiao-Qin, ZOU Jian-Xin, DING Wen-Jiang. Electrochemical Properties of Nanostructured Greigite (Fe3S4) as a Cathode Material in Rechargeable Magnesium Battery[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1351-1356. doi: 10.11862/CJIC.2015.182 shu

Electrochemical Properties of Nanostructured Greigite (Fe3S4) as a Cathode Material in Rechargeable Magnesium Battery

  • 1.

    State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

  • Corresponding author: WU Xiao-Mei, 
  • Received Date: 6 February 2015
    Available Online: 28 April 2015

    Fund Project: 国家自然科学基金(No.51274140)资助项目。 (No.51274140)

  • Nanostructured greigite (Fe3S4) prepared by hydrothermal method was firstly used as a cathode material for rechargeable magnesium battery. The as-synthesized samples were characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM). Cyclic voltammetry and galvanostatic charge-discharge cycling tests showed that the obtained Fe3S4 could be reversibly cycled in rechargeable magnesium battery. The discharge voltage plateau located at 0.9 V. The nanostructured Fe3S4 electrode exhibited a high capacity of 267 mAh·g-1 during the first discharge process, then the capacity gradually dropped to 110 mAh·g-1 after 50 cycles. Electrochemical impedance spectroscopy tests showed that Mg2+ can diffuse in the lattice of Fe3S4.
  • 加载中
    1. [1]

      [1] Aurbach D, Lu Z, Schechter A, et al. Nature, 2000, 407:724-727

    2. [2]

      [2] Saha P, Datta M K, Velikokhatnyi O I, et al. Prog. Mater. Sci., 2014, 66:1-86

    3. [3]

      [3] Muldoon J, Bucur C B, Oliver AG, et al. Energy Environ. Sci., 2012, 5:5941-5950

    4. [4]

      [4] SHEN Jian(沈健), PEN Bo(彭博), TAO Zhan-Liang(陶占良), et al. Prog. Chem.(化学进展), 2010, 22(2/3):515-521

    5. [5]

      [5] Yoo H D, Shterenberg I, Gofer Y, et al. Energ. Environ. Sci., 2013, 6:2265-2279

    6. [6]

      [6] Levi E, Levi M D, Chasid O, et al. J. Electroceram., 2009, 22:13-19

    7. [7]

      [7] Levi E, Gofer Y, Aurbach D. Chem. Mater., 2010, 22:860-868

    8. [8]

      [8] Levi E, Mitelman A, Aurbach D, et al. Chem. Mater., 2007, 19:5131-5142

    9. [9]

      [9] Levi E, Mitelman A, Aurbach D, et al. Inorg. Chem., 2007, 46:7528-7535

    10. [10]

      [10] Levi E, Gershinsky G, Aurbach D, et al. Chem. Mater., 2009, 21:1390-1399

    11. [11]

      [11] Imamura D, Miyayama M. Solid State Ionics, 2003, 161:173-180

    12. [12]

      [12] Gershinsky G, Yoo H D, Gofer Y, et al. Langmuir, 2013, 29: 10964-10972

    13. [13]

      [13] JIAO Li-Fang(焦丽芳). Thesis for the Doctorate of Nankai University(南开大学博士论文). 2005.

    14. [14]

      [14] Arthur T S, Zhang R, Ling C, et al. Acs. Appl. Mater. Inter., 2014, 6:7004-7008

    15. [15]

      [15] Tao Z L, Xu L N, Gou X L, et al. Chem. Commun., 2004, 18:2080-2081

    16. [16]

      [16] Liang Y, Feng R, Yang S, et al. Adv. Mater., 2011, 23:640-643

    17. [17]

      [17] Liu Y, Jiao L, Wu Q, et al. Nanoscale, 2013, 5:9562-9567

    18. [18]

      [18] Liu Y, Jiao L, Wu Q, et al. J. Mater. Chem. A, 2013, 1:5822-5826

    19. [19]

      [19] Huang Z D, Masese T, Orikasa Y, et al. RSC Adv., 2015, 5: 8598-8603

    20. [20]

      [20] Nuli Y N, Yang J, Wang J L, et al. J. Phys. Chem. C, 2009, 113:12594-12597

    21. [21]

      [21] NuLi Y N, Zheng Y, Wang F, et al. Electrochem. Commun., 2011, 13:1143-1146

    22. [22]

      [22] Sun J Z. Asian J. Chem., 2012, 24(5):1909-1911

    23. [23]

      [23] Sun J Z. Monatsh. Chem., 2014, 145:103-106

    24. [24]

      [24] Spender M R, Coey J M D, Morrish A H. Can. J. Phys., 1972, 50:2313-2326

    25. [25]

      [25] Cao F, Hu W, Zhou L, et al. Dalton Trans., 2009, 42:9246-9252

    26. [26]

      [26] Chang L, Rainford B D, Stewart J R, et al. J. Geophys. Res., 2009, 114:B07101

    27. [27]

      [27] Coey J, Spender M, Morrish A. Solid State Commun., 1970, 8:1605-1608

    28. [28]

      [28] Haider S, Grau-Crespo R, Devey A J, et al. Geochim. Cosmochim. Acta, 2012, 88:275-282

    29. [29]

      [29] Martic M, Jakab-Simon I N, Haahr L T, et al. J. Biol. Inorg. Chem., 2013, 18:261-276

    30. [30]

      [30] Roberts A P, Chang L, Rowan C J, et al. Rev. Geophys., 2011, 49:RG1002

    31. [31]

      [31] Dekkers M J, Passier H F, Schoonen M A. Geophys. J. Int., 2000, 141:809-819

    32. [32]

      [32] Paolella A, George C, Povia M, et al. Chem. Mater., 2011, 23: 3762-3768

    33. [33]

      [33] Guo Y G, Hu J S, Wan L J. Adv. Mater., 2008, 20:2878-2887

    34. [34]

      [34] Devan R S, Patil R A, Lin J H, et al. Adv. Funct. Mater., 2012, 22:3326-3370

    35. [35]

      [35] Tarascon J M. J. Electrochem. Soc., 1987, 134(6):1345-1351

    36. [36]

      [36] Reddy M V, Yu T, Sow C H, et al. Adv. Funct. Mater., 2007, 17(15):2792-2799

    37. [37]

      [37] Mizuno Y, Okubo M, Hosono E, et al. J. Mater. Chem. A, 2013, 1:13055-13059

    38. [38]

      [38] Zhang R, Yu X, Nam K W, et al. Electrochem. Commun., 2012, 23:110-113

    39. [39]

      [39] Yu L, Zhang X. J. Colloid Interface Sci., 2004, 278:160-165

    40. [40]

      [40] TANG Zhi-Yuan(唐致远), RUAN Yan-Li(阮艳莉). Prog. Chem.(化学进展), 2005, 17(1):1-7

    41. [41]

      [41] MA Ling(马苓), DU Guang-Yuan(杜光远), XU Qiang(徐强), et al. Chinese J. Power Sources(电源技术), 2014, 38(3):553-556

    42. [42]

      [42] ZHUANG Quan-Chao(庄全超). Thesis for the Doctorate of Xiamen University(厦门大学博士论文). 2007.

    43. [43]

      [43] WANG Lian-Liang(王连亮), SUN Zhi-Zhong(孙志中), YI Wen-Tao(伊文涛), et al. J. Salt Lake Res.(盐湖研究), 2008, 16(4):21-26

    44. [44]

      [44] ZHUANG Quan-Chao(庄全超), XU Shou-Dong(徐守冬), QIU Xiang-Yun(邱祥云), et al. Prog. Chem.(化学进展), 2010, 22:1044-1057

    45. [45]

      [45] QIU Xiang-Yun (邱祥云). Thesis for the Doctorate of China University of Mining(中国矿业大学博士论文). 2013.

    46. [46]

      [46] Aurbach D, Levi M D, Levi E. Solid State Ionics, 2008, 179: 742-751

    47. [47]

      [47] Aurbach D, Gofer Y, Schechter A, et al. J. Power Sources, 2001, 97:269-273

    48. [48]

      [48] Levi M D, Gizbar H, Lancry E, et al. J. Electroanal. Chem., 2004, 569:211-223

  • 加载中
    1. [1]

      Jianbao Mei ,  Bei Li ,  Shu Zhang ,  Dongdong Xiao ,  Pu Hu ,  Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na3.5-xMn0.5V1.5-xZrx(PO4)3/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023

    2. [2]

      Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li2FeSiO4/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115

    3. [3]

      Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn0.8Fe0.2PO4/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252

    4. [4]

      Feiya Cao ,  Qixin Wang ,  Pu Li ,  Zhirong Xing ,  Ziyu Song ,  Heng Zhang ,  Zhibin Zhou ,  Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094

    5. [5]

      Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO2 with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149

    6. [6]

      Zunyuan Xie ,  Lijin Yang ,  Zixiao Wan ,  Xiaoyu Liu ,  Yushan He . Exploration of the Preparation and Characterization of Nano Barium Titanate and Its Application in Inorganic Chemistry Laboratory Teaching. University Chemistry, 2024, 39(4): 62-69. doi: 10.3866/PKU.DXHX202310137

    7. [7]

      Juan Yuan ,  Bin Zhang ,  Jinping Wu ,  Mengfan Wang . Design of a Comprehensive Experiment on Preparation and Characterization of Cu2(Salen)2 Nanomaterials with Two Distinct Morphologies. University Chemistry, 2024, 39(10): 420-425. doi: 10.3866/PKU.DXHX202402014

    8. [8]

      Simin Fang ,  Wei Huang ,  Guanghua Yu ,  Cong Wei ,  Mingli Gao ,  Guangshui Li ,  Hongjun Tian ,  Wan Li . Integrating Science and Education in a Comprehensive Chemistry Design Experiment: The Preparation of Copper(I) Oxide Nanoparticles and Its Application in Dye Water Remediation. University Chemistry, 2024, 39(8): 282-289. doi: 10.3866/PKU.DXHX202401023

    9. [9]

      Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020

    10. [10]

      Zhenming Xu ,  Mingbo Zheng ,  Zhenhui Liu ,  Duo Chen ,  Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO4 Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022

    11. [11]

      Doudou Qin ,  Junyang Ding ,  Chu Liang ,  Qian Liu ,  Ligang Feng ,  Yang Luo ,  Guangzhi Hu ,  Jun Luo ,  Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034

    12. [12]

      Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl0.08Mn1.92O4 single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022

    13. [13]

      Qi Li ,  Pingan Li ,  Zetong Liu ,  Jiahui Zhang ,  Hao Zhang ,  Weilai Yu ,  Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030

    14. [14]

      Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C3N4 nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086

    15. [15]

      Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga2O3 coated modification and electrochemical performance of Li1.2Mn0.54Ni0.13Co0.13O2 cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488

    16. [16]

      Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023

    17. [17]

      Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe3O4@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239

    18. [18]

      Kexin Dong ,  Chuqi Shen ,  Ruyu Yan ,  Yanping Liu ,  Chunqiang Zhuang ,  Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag3PO4/C3N5 Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013

    19. [19]

      Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO2/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189

    20. [20]

      Haihua Yang ,  Minjie Zhou ,  Binhong He ,  Wenyuan Xu ,  Bing Chen ,  Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(235)
  • HTML views(22)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return