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Citation: ZHANG Ruo-Ran, WU Xiao-Mei, ZENG Xiao-Qin, ZOU Jian-Xin, DING Wen-Jiang. Electrochemical Properties of Nanostructured Greigite (Fe3S4) as a Cathode Material in Rechargeable Magnesium Battery[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1351-1356. doi: 10.11862/CJIC.2015.182 shu

Electrochemical Properties of Nanostructured Greigite (Fe3S4) as a Cathode Material in Rechargeable Magnesium Battery

  • 1.

    State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

  • Corresponding author: WU Xiao-Mei, 
  • Received Date: 6 February 2015
    Available Online: 28 April 2015

    Fund Project: 国家自然科学基金(No.51274140)资助项目。 (No.51274140)

  • Nanostructured greigite (Fe3S4) prepared by hydrothermal method was firstly used as a cathode material for rechargeable magnesium battery. The as-synthesized samples were characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM). Cyclic voltammetry and galvanostatic charge-discharge cycling tests showed that the obtained Fe3S4 could be reversibly cycled in rechargeable magnesium battery. The discharge voltage plateau located at 0.9 V. The nanostructured Fe3S4 electrode exhibited a high capacity of 267 mAh·g-1 during the first discharge process, then the capacity gradually dropped to 110 mAh·g-1 after 50 cycles. Electrochemical impedance spectroscopy tests showed that Mg2+ can diffuse in the lattice of Fe3S4.
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    1. [1]

      [1] Aurbach D, Lu Z, Schechter A, et al. Nature, 2000, 407:724-727

    2. [2]

      [2] Saha P, Datta M K, Velikokhatnyi O I, et al. Prog. Mater. Sci., 2014, 66:1-86

    3. [3]

      [3] Muldoon J, Bucur C B, Oliver AG, et al. Energy Environ. Sci., 2012, 5:5941-5950

    4. [4]

      [4] SHEN Jian(沈健), PEN Bo(彭博), TAO Zhan-Liang(陶占良), et al. Prog. Chem.(化学进展), 2010, 22(2/3):515-521

    5. [5]

      [5] Yoo H D, Shterenberg I, Gofer Y, et al. Energ. Environ. Sci., 2013, 6:2265-2279

    6. [6]

      [6] Levi E, Levi M D, Chasid O, et al. J. Electroceram., 2009, 22:13-19

    7. [7]

      [7] Levi E, Gofer Y, Aurbach D. Chem. Mater., 2010, 22:860-868

    8. [8]

      [8] Levi E, Mitelman A, Aurbach D, et al. Chem. Mater., 2007, 19:5131-5142

    9. [9]

      [9] Levi E, Mitelman A, Aurbach D, et al. Inorg. Chem., 2007, 46:7528-7535

    10. [10]

      [10] Levi E, Gershinsky G, Aurbach D, et al. Chem. Mater., 2009, 21:1390-1399

    11. [11]

      [11] Imamura D, Miyayama M. Solid State Ionics, 2003, 161:173-180

    12. [12]

      [12] Gershinsky G, Yoo H D, Gofer Y, et al. Langmuir, 2013, 29: 10964-10972

    13. [13]

      [13] JIAO Li-Fang(焦丽芳). Thesis for the Doctorate of Nankai University(南开大学博士论文). 2005.

    14. [14]

      [14] Arthur T S, Zhang R, Ling C, et al. Acs. Appl. Mater. Inter., 2014, 6:7004-7008

    15. [15]

      [15] Tao Z L, Xu L N, Gou X L, et al. Chem. Commun., 2004, 18:2080-2081

    16. [16]

      [16] Liang Y, Feng R, Yang S, et al. Adv. Mater., 2011, 23:640-643

    17. [17]

      [17] Liu Y, Jiao L, Wu Q, et al. Nanoscale, 2013, 5:9562-9567

    18. [18]

      [18] Liu Y, Jiao L, Wu Q, et al. J. Mater. Chem. A, 2013, 1:5822-5826

    19. [19]

      [19] Huang Z D, Masese T, Orikasa Y, et al. RSC Adv., 2015, 5: 8598-8603

    20. [20]

      [20] Nuli Y N, Yang J, Wang J L, et al. J. Phys. Chem. C, 2009, 113:12594-12597

    21. [21]

      [21] NuLi Y N, Zheng Y, Wang F, et al. Electrochem. Commun., 2011, 13:1143-1146

    22. [22]

      [22] Sun J Z. Asian J. Chem., 2012, 24(5):1909-1911

    23. [23]

      [23] Sun J Z. Monatsh. Chem., 2014, 145:103-106

    24. [24]

      [24] Spender M R, Coey J M D, Morrish A H. Can. J. Phys., 1972, 50:2313-2326

    25. [25]

      [25] Cao F, Hu W, Zhou L, et al. Dalton Trans., 2009, 42:9246-9252

    26. [26]

      [26] Chang L, Rainford B D, Stewart J R, et al. J. Geophys. Res., 2009, 114:B07101

    27. [27]

      [27] Coey J, Spender M, Morrish A. Solid State Commun., 1970, 8:1605-1608

    28. [28]

      [28] Haider S, Grau-Crespo R, Devey A J, et al. Geochim. Cosmochim. Acta, 2012, 88:275-282

    29. [29]

      [29] Martic M, Jakab-Simon I N, Haahr L T, et al. J. Biol. Inorg. Chem., 2013, 18:261-276

    30. [30]

      [30] Roberts A P, Chang L, Rowan C J, et al. Rev. Geophys., 2011, 49:RG1002

    31. [31]

      [31] Dekkers M J, Passier H F, Schoonen M A. Geophys. J. Int., 2000, 141:809-819

    32. [32]

      [32] Paolella A, George C, Povia M, et al. Chem. Mater., 2011, 23: 3762-3768

    33. [33]

      [33] Guo Y G, Hu J S, Wan L J. Adv. Mater., 2008, 20:2878-2887

    34. [34]

      [34] Devan R S, Patil R A, Lin J H, et al. Adv. Funct. Mater., 2012, 22:3326-3370

    35. [35]

      [35] Tarascon J M. J. Electrochem. Soc., 1987, 134(6):1345-1351

    36. [36]

      [36] Reddy M V, Yu T, Sow C H, et al. Adv. Funct. Mater., 2007, 17(15):2792-2799

    37. [37]

      [37] Mizuno Y, Okubo M, Hosono E, et al. J. Mater. Chem. A, 2013, 1:13055-13059

    38. [38]

      [38] Zhang R, Yu X, Nam K W, et al. Electrochem. Commun., 2012, 23:110-113

    39. [39]

      [39] Yu L, Zhang X. J. Colloid Interface Sci., 2004, 278:160-165

    40. [40]

      [40] TANG Zhi-Yuan(唐致远), RUAN Yan-Li(阮艳莉). Prog. Chem.(化学进展), 2005, 17(1):1-7

    41. [41]

      [41] MA Ling(马苓), DU Guang-Yuan(杜光远), XU Qiang(徐强), et al. Chinese J. Power Sources(电源技术), 2014, 38(3):553-556

    42. [42]

      [42] ZHUANG Quan-Chao(庄全超). Thesis for the Doctorate of Xiamen University(厦门大学博士论文). 2007.

    43. [43]

      [43] WANG Lian-Liang(王连亮), SUN Zhi-Zhong(孙志中), YI Wen-Tao(伊文涛), et al. J. Salt Lake Res.(盐湖研究), 2008, 16(4):21-26

    44. [44]

      [44] ZHUANG Quan-Chao(庄全超), XU Shou-Dong(徐守冬), QIU Xiang-Yun(邱祥云), et al. Prog. Chem.(化学进展), 2010, 22:1044-1057

    45. [45]

      [45] QIU Xiang-Yun (邱祥云). Thesis for the Doctorate of China University of Mining(中国矿业大学博士论文). 2013.

    46. [46]

      [46] Aurbach D, Levi M D, Levi E. Solid State Ionics, 2008, 179: 742-751

    47. [47]

      [47] Aurbach D, Gofer Y, Schechter A, et al. J. Power Sources, 2001, 97:269-273

    48. [48]

      [48] Levi M D, Gizbar H, Lancry E, et al. J. Electroanal. Chem., 2004, 569:211-223

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