Citation:
ZHU Xiao-Ming, KUANG Dai-Zhi, FENG Yong-Lan, ZHANG Fu-Xing, YU Jiang-Xi, JIANG Wu-Jiu, ZHANG Zhi-Jian. Syntheses, Crystal Structures, Thermal Stability and Biological Activities of Two Bis[tri(2-methyl-2-phenyl)propyltin]dicarboxylates (CH2)n[CO2Sn(CH2CMe2Ph)3]2 (n=5,6)[J]. Chinese Journal of Inorganic Chemistry,
;2015, 31(7): 1373-1379.
doi:
10.11862/CJIC.2015.181
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The two bis[tri(2-methyl-2-phenyl)propyltin]dicarboxylates (CH2)n[CO2Sn(CH2CMe2Ph)3]2 (n=5 (1), 6 (2)) have been synthesized by the reaction of pimelic acid and suberic acid with bis[tri(2-methyl-2-phenyl)propyltin]oxide, respectively. IR, 1H and 13C NMR, elemental analysis and X-ray diffraction for the title complexes were presented. The two complexes belong to monoclinic, space group P21/c. The tin atoms have a distorted tetrahedral geometry. A 1D chain structure of complex 1 is generated by intermolecular hydrogen bonds and a 2D network structure of complex 2 is formed by C-H…O and C-H…π interactions. The thermal gravimetric analysis has showed that the complexes 1 and 2 are stable below 340 ℃. The two complexes showed strong in vitro anti-tumor activity against five human tumor cell lines, Colo205, HepG2, MCF-7, Hela and NCI-H460, and have antibacterial activity.
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[2]
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[3]
[3] ZHANG Shu-Kui(张树奎), CHEN Xue-Ren(陈学仁), LI Zhi-Chun(李之春), et al. Chem. J. Chinese Universities(高等学校化学学报), 1999, 20(11):1743-1745
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[4]
[4] YU Jiang-Xi(庾江喜), FENG Yong-Lan(冯泳兰), JIANG Wu-Jiu(蒋伍玖), et al. Chinese J. Inorg. Chem.(无机化学学报), 2014, 30(9):2025-2031
-
[5]
[5] ZHU Xiao-Ming(朱小明), FENG Yong-Lan(冯泳兰), KUANG Dai-Zhi(邝代治), et al. Chinese J. Struct. Chem.(结构化学), 2012, 31(9):1241-1246
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[6]
[6] YU Jiang-Xi(庾江喜), FENG Yong-Lan(冯泳兰), KUANG Dai-Zhi(邝代治), et al. Chinese J. Inorg. Chem.(无机化学学报), 2014, 30(10):2353-2359
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[7]
[7] ZHANG Zhi-Jian(张志坚), KUANG Dai-Zhi(邝代治), ZHANG Fu-Xing(张复兴), et al. Chinese J. Appl. Chem.(应用化学), 2014, 31(9):1058-1062
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[8] FENG Yong-Lan(冯泳兰), YU Jiang-Xi(庾江喜), KUANG Dai-Zhi(邝代治), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012, 28(8):1629-1634
-
[9]
[9] TAN Yu-Xing(谭宇星), FENG Yong-Lan(冯泳兰), YIN Du-Lin(尹笃林), et al. Chinese J. Inorg. Chem.(无机化学学报), 2014, 30(12):2781-2788
-
[10]
[10] YAN Wen-Hua(闫文华), KANG Wan-Li(康万利), LI Jin-Huan(李金环). Chemistry(化学通报), 2007(4):313-316
-
[11]
[11] Sheldrick G M. SHELXTL-97, Program for Crystal Structure Analysis, University of Göttingen, Germany, 1997.
-
[12]
[12] WENG Shi-Fu(翁诗甫). Fourier Translation Infrared Spec-troscopy Analysis. 2nd Ed.(傅里叶变换红外光谱分析. 2版). Beijing: Chemical Industry Press, 2005:309-327
-
[13]
[13] YIN Han-Dong(尹汉东), CUI Ji-Chun(崔继春), LI Jing(李静). J. Liaocheng University(聊城大学学报), 2009, 22(3):66-68
-
[14]
[14] LIU Chun-Ling(刘春玲), XU Da(徐达), Wen Qiao(温俏), et al. Chemistry(化学通报), 2014, 77(8):819-322
-
[15]
[15] KE Yi-Kan(柯以侃), DONG Hui-Ru(董慧茹). Analysis Chemistry Handbook: Vol.3(分析化学手册:第三分册). Beijing: Chemical Industry Press, 1998:932-935
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