Citation: ZHENG Hui, XU Yang, DUAN Chun-Ying. Tuning Intrachain Magnetic Interactions of Cyanide-bridged Fe^ⅢMn^Ⅱ Chain[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1460-1466. doi: 10.11862/CJIC.2015.177 shu

Tuning Intrachain Magnetic Interactions of Cyanide-bridged Fe^ⅢMn^Ⅱ Chain

1.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, China

Corresponding author: DUAN Chun-Ying,
Received Date: 7 April 2015
Available Online: 8 May 2015
Fund Project: 国家自然科学基金(No.91122031)资助项目。 (No.91122031)

Two cyanide bridged Fe^ⅢMn^Ⅱ double zigzag chains {[Fe(Tp)(CN)₃]₂[Mn(bib)]}·CH₃OH·2H₂O (1) and {[Fe(pzTp)(CN)₃]₂[Mn(bib)]}·3H₂O (2) were synthesized utilizing tricyanometallate building blocks. The chains were further linked via long ditopic ligand to form two dimensional compounds. With the alignment of chains fixed by the rigid ditopic linker, the intrachain magnetic interactions between Fe^Ⅲ and Mn^Ⅱ could be further tuned via changing the capping ligand of Fe^Ⅲ ions.
- cyanide;zigzag chain;ditopic linker;magnetic interactions 0 Introduction
1. [1]
  [1] (a)Caneschi A, Gatteschi D, Lalioti N, et al. Angew. Chem. Int. Ed., 2001, 40:1760-1763
2. [2]
  (b)Miyasaka H, Julve M, Yamashita M, et al. Inorg. Chem., 2009, 48:3420-3437
3. [3]
  [2] (a)Zhang X M, Wang Y Q, Wang K, et al. Chem. Commun., 2011, 47:1815-1817
4. [4]
  (b)Miyasaka H, Madanbashi T, Sugimoto K, et al. Chem. Eur. J., 2006, 12:7028
5. [5]
  (c)Bai Y L, Tao J, Wernsdorfer W, et al. J. Am. Chem. Soc., 2006, 128:16428-16429
6. [6]
  [3] (a)Coronado E, Mascarós J R G and Gastaldo C M. J. Am. Chem. Soc., 2008, 130:14987-14989
7. [7]
  (b)Zhang Y Z, Tong M L, Chen X M, et al. Angew. Chem. Int. Ed., 2006, 45:6310-6314
8. [8]
  (c)Venkatakrishnan T S, Sahoo S, Bréfuel N, et al. J. Am. Chem. Soc., 2010, 132:6047-6057
9. [9]
  (d)Coulon C, Clérac R, Wernsdorfer W, et al. Phys. Rev. Lett., 2009, 102:167204-167207
10. [10]
  [4] (a)Lescouzec R, Vaissermann J, Ruiz-Prez C, et al. Angew. Chem., 2003, 115:1521-1524; Angew. Chem. Int. Ed., 2003, 42:1483-1486
11. [11]
  (b)Toma L M, Lescouzec R, Lloret F, et al. Chem. Commun., 2003, 24:1850-1851
12. [12]
  (c)Wang S, Zuo J L, Gao S, et al. J. Am. Chem. Soc., 2004, 126:8900-8901
13. [13]
  (d)Toma L M, Lescouzec R, Lloret F, et al. J. Am. Chem. Soc., 2006, 128:4842-4853
14. [14]
  [5] (a)Ferbinteanu M, Miyasaka H, Wernsdorfer W, et al. J. Am. Chem. Soc., 2005, 127:3090-3099
15. [15]
  (b)Lescouzec R, Toma M L, Vaissermann J, et al. Coord. Chem. Rev., 2005, 249:269-27291
16. [16]
  (c)Kou H Z, Ni Z H, Liu C M, et al. New J. Chem., 2009, 33: 2296-2299
17. [17]
  [6] (a)Rinehart J D, Long J R. Chem. Sci., 2011, 2:2078-2085
18. [18]
  (b)Sun H L, Wang Z M, Gao S. Coord. Chem. Rev., 2010, 254:1081-1101
19. [19]
  (c)Aubin S M J, Sun Z, Pardi L, et al. Inorg. Chem., 1999, 38:5329-5340
20. [20]
  [7] (a)Cucinotta G, Perfetti M, Luzon J, et al. Angew. Chem. Int. Ed., 2012, 51:1606-1610
21. [21]
  (b)Zuo J L, Bartlett B M, You X Z, et al. J. Am. Chem. Soc., 2006, 128:7162-7163
22. [22]
  (c)Kostakisa G E, Perlepesb S P, Blatovc V A, et al. Acc. Chem. Res., 2005, 38:325-334
23. [23]
  (d)Berseth P A, Sokol J J, Shores M P, et al. J. Am. Chem. Soc., 2000, 122:9655-9662
24. [24]
  [8] Kostakisa G E, Perlepesb S P, Blatovc V A, et al. Acc. Chem. Res., 2005, 38:325-334
25. [25]
  [9] Berseth P A, Sokol J J, Shores M P, et al. J. Am. Chem. Soc., 2000, 122:9655-9622
26. [26]
  [10] Wen H R, Zuo J L, et al. Inorg. Chem., 2006, 45:582-590
27. [27]
  [11] (a)Liu T, Dong D P, Kanegawa S, et al. Angew. Chem. Int. Ed., 2012, 51:4367-4370
28. [28]
  (b)Wang S, Zuo J L, Zhou H C, et al. Angew. Chem. Int. Ed., 2004, 43:594-597
29. [29]
  (c)Dong D P, Liu T, Zheng H, et al. Inorg. Chem. Comm., 2012, 24:153-156
30. [30]
  [12] Zhang Y Z, Wang B W, Sato O, et al. Chem. Commun., 2010, 46:6959-6961
31. [31]
  [13] Song X J, Muddassir M, Chen Y, et al. Dalton Trans., 2013, 42:1116-1121
32. [32]
  [14] Bogani L, Vindigni A, Sessoli R, et al. J. Mater. Chem., 2008, 18:4750-4758
33. [33]
  [15] (a)Harris T D, Bennett M V, Clérac R, et al. J. Am. Chem. Soc., 2010, 132:3980-3988
34. [34]
  (b)Bernot K, Bogani L, Caneschi A, et al. J. Am. Chem. Soc., 2006, 128:7947-7956
35. [35]
  (c)Clérac R, Miyasaka H, Yamashita M, et al. J. Am. Chem. Soc., 2002, 124:12837-12844
36. [36]
  [16] (a)Liu T, Zheng H, Kang S, et al. Nat. Commun., 2013, 4: 2826-2833
37. [37]
  (b)Liu T, Zhang Y J, Kanegawa S, et al. Angew. Chem. Int. Ed., 2010, 49:8645-8648
38. [38]
  (c)Liu T, Zhang Y J, Kanegawa S, et al. J. Am. Chem. Soc., 2010, 132:8250-8251
39. [39]
  [17] Ohkoshi S, Tokoro H, Utsunomiya M, et al. J. Phys. Chem. B, 2002, 106:2423-2425
40. [40]
  [18] Lescouëzec R, Vaissermann J, Lloret F, et al. Inorg. Chem., 2002, 41:5943-5945
41. [41]
  [19] LI Dong-Feng(李东峰), Clérac R, Parkin S, et al. Inorg. Chem., 2006, 45:5251-5253
42. [42]
  [20] Vlahakis J Z, Mitu S, Roman G, et al. Bioorganic & Medicinal Chemistry, 2011, 19:6525-6545
43. [43]
  [21] DONG Da-Peng(董大鹏), LIU Tao(刘涛), ZHENG Hui(郑慧), et al. Scince China B: Chem.(中国科学:化学), 2012, 55 (6):1018-1021
44. [44]
  [22] CHEN Man-Sheng (陈满生), LUO Li(罗莉), SUN Wei-Yin (孙为银), et al. Chinese J. Inorg. Chem.(无机化学学报), 2010, 16(12):2227-2232
1. [1]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
2. [2]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
3. [3]
  Jiaxun Wu , Mingde Li , Li Dang . The R eaction of Metal Selenium Complexes with Olefins as a Tutorial Case Study for Analyzing Molecular Orbital Interaction Modes. University Chemistry, 2025, 40(3): 108-115. doi: 10.12461/PKU.DXHX202405098
4. [4]
  Huiying Xu , Minghui Liang , Zhi Zhou , Hui Gao , Wei Yi . Application of Quantum Chemistry Computation and Visual Analysis in Teaching of Weak Interactions. University Chemistry, 2025, 40(3): 199-205. doi: 10.12461/PKU.DXHX202407011
5. [5]
  Jinyao Du , Xingchao Zang , Ningning Xu , Yongjun Liu , Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039
6. [6]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
7. [7]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
8. [8]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
9. [9]
  Linhan Tian , Changsheng Lu . Discussion on Sextuple Bonding in Diatomic Motifs of Chromium Family Elements. University Chemistry, 2024, 39(8): 395-402. doi: 10.3866/PKU.DXHX202401056
10. [10]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
11. [11]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
12. [12]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
13. [13]
  Danqing Wu , Jiajun Liu , Tianyu Li , Dazhen Xu , Zhiwei Miao . Research Progress on the Simultaneous Construction of C—O and C—X Bonds via 1,2-Difunctionalization of Olefins through Radical Pathways. University Chemistry, 2024, 39(11): 146-157. doi: 10.12461/PKU.DXHX202403087
14. [14]
  Di Yang , Jiayi Wei , Hong Zhai , Xin Wang , Taiming Sun , Haole Song , Haiyan Wang . Rapid Detection of SARS-CoV-2 Using an Innovative “Magic Strip”. University Chemistry, 2024, 39(4): 373-381. doi: 10.3866/PKU.DXHX202312023
15. [15]
  Runze Xu , Rui Liu . U-Pb Dating in the Age of Dinosaurs. University Chemistry, 2024, 39(9): 243-247. doi: 10.12461/PKU.DXHX202404083
16. [16]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
17. [17]
  Ming Li , Zhaoyin Li , Mengzhu Liu , Shaoxiang Luo . Unveiling the Artistry of Mordant Dyeing: The Coordination Chemistry Beneath. University Chemistry, 2024, 39(5): 258-265. doi: 10.3866/PKU.DXHX202311085
18. [18]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
19. [19]
  Lei Shi . Nucleophilicity and Electrophilicity of Radicals. University Chemistry, 2024, 39(11): 131-135. doi: 10.3866/PKU.DXHX202402018
20. [20]
  Min LIU , Huapeng RUAN , Zhongtao FENG , Xue DONG , Haiyan CUI , Xinping WANG . Neutral boron-containing radical dimers. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 123-130. doi: 10.11862/CJIC.20240362

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(463)
HTML views(78)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Tuning Intrachain Magnetic Interactions of Cyanide-bridged FeⅢMnⅡ Chain

Metrics

通讯作者: 陈斌, bchen63@163.com

Tuning Intrachain Magnetic Interactions of Cyanide-bridged Fe^ⅢMn^Ⅱ Chain