Citation: ZHENG Hui, XU Yang, DUAN Chun-Ying. Tuning Intrachain Magnetic Interactions of Cyanide-bridged Fe^ⅢMn^Ⅱ Chain[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1460-1466. doi: 10.11862/CJIC.2015.177 shu

Tuning Intrachain Magnetic Interactions of Cyanide-bridged Fe^ⅢMn^Ⅱ Chain

1.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, China

Corresponding author: DUAN Chun-Ying,
Received Date: 7 April 2015
Available Online: 8 May 2015
Fund Project: 国家自然科学基金(No.91122031)资助项目。 (No.91122031)

Two cyanide bridged Fe^ⅢMn^Ⅱ double zigzag chains {[Fe(Tp)(CN)₃]₂[Mn(bib)]}·CH₃OH·2H₂O (1) and {[Fe(pzTp)(CN)₃]₂[Mn(bib)]}·3H₂O (2) were synthesized utilizing tricyanometallate building blocks. The chains were further linked via long ditopic ligand to form two dimensional compounds. With the alignment of chains fixed by the rigid ditopic linker, the intrachain magnetic interactions between Fe^Ⅲ and Mn^Ⅱ could be further tuned via changing the capping ligand of Fe^Ⅲ ions.
- cyanide;zigzag chain;ditopic linker;magnetic interactions 0 Introduction
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Tuning Intrachain Magnetic Interactions of Cyanide-bridged FeⅢMnⅡ Chain

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通讯作者: 陈斌, bchen63@163.com

Tuning Intrachain Magnetic Interactions of Cyanide-bridged Fe^ⅢMn^Ⅱ Chain