Citation: LIU Fa-Qian, ZHAO Jie, ZHANG Dong, DUAN Xiao-Quan, WANG Lei, DENG Yue-Yi, LI Wei-Hua. Binuclear Cobalt(Ⅱ) Complex and Cobalt(Ⅱ) Coordination Polymer of Bidentate Ligand 1,3-Bis(2-benzimidazolyl)benzene: Crystal Structures and Magnetic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1402-1408. doi: 10.11862/CJIC.2015.166 shu

Binuclear Cobalt(Ⅱ) Complex and Cobalt(Ⅱ) Coordination Polymer of Bidentate Ligand 1,3-Bis(2-benzimidazolyl)benzene: Crystal Structures and Magnetic Properties

LIU Fa-Qian ^1,, ,
ZHAO Jie ² ,
ZHANG Dong ³ ,
DUAN Xiao-Quan ³ ,
WANG Lei ¹ ,
DENG Yue-Yi ^3,, ,
LI Wei-Hua ^2,,

1.
1 Engineering Research Center of High Performance Polymer and Molding Technology, Ministry of Education, Qingdao University of Science and Technology, Qingdao, Shandong 266042, China;
2.
2 Institute of Oceanology, Chinese Academy of Sciences, Qingdao, Shandong 266071, China;
3.
3 College of Pharmacy, Guilin Medical University, Guilin, Guangxi 541004, China

Corresponding author: LIU Fa-Qian, DENG Yue-Yi, LI Wei-Hua,
Received Date: 28 February 2015
Available Online: 2 April 2015
Fund Project: 国家自然科学基金(No.21371105, 51372125, 51179182) (No.21371105, 51372125, 51179182) 青岛市科技发展计划(No.14-2-4-41-jch, 13-1-4-209-jch)资助项目。 (No.14-2-4-41-jch, 13-1-4-209-jch)

Two cobalt(Ⅱ) complexes, Co₂(MBimB)₂Cl₄·2H₂O·EDA (1) (MBimb=1,3-bis(2-benzimidazolyl)benzene, EDa=ethylenediamine) and [Co(MBimB)Cl₂]_n (2), have been synthesized based on the rigid ligand MBimB and characterized by single crystal X-ray diffraction. In complex 1, two MBimB molecules adopt "cis" conformation and bridge two cobalt(Ⅱ) ions to form a binuclear metallaycyclic framework. In complex 2, MBimB ligand adopts "trans" conformation and bridges two adjacent cobalt(Ⅱ) ions into 1D zigzag chain. Magnetic susceptibility of 1 and 2 showed ferromagnetic coupling firstly and then antiferromagnetic coupling as the temperature decreases. Compared to complex 2, stronger ferromagnetic interaction and/or spin-orbital coupling between the cobalt(Ⅱ) ions in 1 can be ascribed to the shorter distance of Co…Co and enhanced intervening aromatic π-system between the metal centers.
- 1, 3-bis(2-benzimidazolyl)benzene;coordination polymer;binuclear cobalt(Ⅱ) complex;magnetic properties
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