Citation: YUAN Su-Jun, ZHANG Qing-Hong, LEI Fang, XIE Jian-Jun, SHI Ying. Self Assembly TiO₂ Films on the Flexible Transparent Conductive Oxide Substrates: Preparation and Photoelectrochemical Activity[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1099-1104. doi: 10.11862/CJIC.2015.165 shu

Self Assembly TiO₂ Films on the Flexible Transparent Conductive Oxide Substrates: Preparation and Photoelectrochemical Activity

1.
1 School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China;
2.
2 College of Materials Science and Engineering, Donghua University, Shanghai 201620, China

Corresponding author: YUAN Su-Jun,
Received Date: 14 November 2014
Available Online: 5 May 2015
Fund Project: 中国博士后科学基金(No.2013M540353)资助项目。 (No.2013M540353)

The all-nanoparticle TiO₂ films were directly prepared on the flexible transparent conductive oxide substrates by the layer-by-layer (LBL) self assembly method through the crystallized TiO_2. During the preparation, the polyelectrolytes were replaced and the calcination is avoided. The TiO₂ used in the self assembling process included an anatase TiO₂ sol and the Degussa P_25. The microstructure of the self assembly films was controlled through the ultrafine TiO₂ crystallites of the sol, which could improve the uniformity and density of the films. The TiO₂ film was introduced to be the working electrode in a three-electrode photoelectrochemical bulk cell, and the one with the high uniformity and density showed a good photoelectrochemical property. The photocurrent responses obtained from the TiO₂ electrodes prepared with the TiO₂ sol were about 25% higher than that of the one prepared without the sol.
- titania;layer-by-layer;self assembly;all-nanoparticle;photoelecrochemical activity
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Self Assembly TiO2 Films on the Flexible Transparent Conductive Oxide Substrates: Preparation and Photoelectrochemical Activity

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通讯作者: 陈斌, bchen63@163.com

Self Assembly TiO₂ Films on the Flexible Transparent Conductive Oxide Substrates: Preparation and Photoelectrochemical Activity