Citation: QI Dan-Dan, ZHANG Fang, JIANG Da-Guang, QIN De-Cai, ZHANG Xiao-Gang. Fe2O3 Nanoparticles Prepared by Solid-State Thermolysis of Fe-Based Coordination Polymer and Their Enhanced Lithium Storage Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1171-1176. doi: 10.11862/CJIC.2015.159
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α-Fe2O3 nanoparticles with uniform size were synthesized via a complex-precursor strategy. First, iron ion-based coordination polymer was synthesized via a solvothermal method by using p-benzene-dicarboxylic acid (p-H2bdc) as ligand. Second, α-Fe2O3 nanoparticles with uniform size were prepared via a solid state pyrolysis procedure. The synthesized coordination polymer and Fe2O3 product were characterized by XRD, FT-IR, SEM and TEM respectively. When used as anode material for lithium-ion batteries, the Fe2O3 electrode can deliever a stable reversible capacity of 530 mAh·g-1 after 50 charge-discharge cycles at a current density of 0.1 A·g-1, which showed a higher specific capacity and superior cycle stability.
-
-
[1]
[1] GUO Wei(郭巍), WU Hang(吴行), ZHENG Zhen-Zhong(郑 振忠), et al. Electronic Components and Materials(电子元 件与材料), 2010,12:31-33
-
[2]
[2] Xu J S, Zhu Y J, Chen F. J. Solid State Chem., 2013,199:204-211
-
[3]
[3] Lai L, Huang G, Wang X, et al. Carbon, 2011,49:1581-1587
-
[4]
[4] Zeng Y, Yao J, Li D, et al. ACS Appl. Mater. Interfaces, 2011,3(1):35-42
-
[5]
[5] Poizot P, Laruelle S, Grugeon S. Nature, 2000,407:496-499
-
[6]
[6] Deng H, Long D, Liu X, et al. J. Power Sources, 2011,196 (5):3887-3893
-
[7]
[7] GU Bao-Xia(顾晓霞), DIAO Xun-Gang(刁训刚), HAO Lei (郝雷). Aerospace Materials and Technology(宇航材料工艺), 2008,3:58-62
-
[8]
[8] WANG Zhong-Chun(王忠春), LIU Er-Sheng(刘尔生), CHEN Nai-Sheng(陈耐生), et al. Chinese J. Struc. Chem.(结构化 学), 1996,15(6):450-453
-
[9]
[9] Niu M T, Huang F, Cui L F, et al. ACS Nano, 2010,4(2): 681-688
-
[10]
[10] ZHANG Ying(张颖), GAO Xue-Ping(高学平), HU Heng(胡 恒), et al. Chinese J. Inorg. Chem.(无机化学学报), 2004,20 (9):1013-1017
-
[11]
[11] Chen J, Xu L, Yu T, et al. Adv. Mater., 2005,17:582-587
-
[12]
[12] Zhu X J, Zhu Y W, Murali S, et al. ACS Nano, 2011,5(4): 3333-3338
-
[13]
[13] Okada J, Yamaki I. J. Ind. Eng. Chem., 2004,10:1104-1113
-
[14]
[14] ZHAO Tie-Peng(赵铁鹏), GAO De-Shu(高德淑), LEI Gang-Tie(雷钢铁), et al. Acta Chim. Sinica(化学学报), 2009,67 (17):1957-1961
-
[15]
[15] Xu X, Cao R, Chao J, et al. Nano Lett., 2012,12:4988-4991
-
[16]
[16] Zhang L, Wu H B, Lou X W. CrystEngComm, 2013,15:9332 -9335
-
[17]
[17] Wang B, Chen J S, Lou X W. J. Mater. Chem., 2012,22: 9466-9468
-
[18]
[18] Jia X, Chen J J, Xu J H, et al. Chem. Commun., 2012,48: 7410-7412
-
[19]
[19] Wang Z, Luan D, Madhavi S, et al. Chem. Commun., 2011, 47:8061-8063
-
[20]
[20] Kang N, Park J H, Choi J, et al. Angew. Chem. Int. Ed., 2012,51:6626-6632
-
[21]
[21] Zhu T, Yang X H, Yang H G, et al. J. Am. Chem. Soc., 2010,132:13162-13168
-
[22]
[22] Li C C, Chen L B, Wang T H, et al. Chem. Eur. J., 2010,16: 5215-5221
-
[23]
[23] Jiang H L, Xu Q. Chem. Commun., 2011,47(12):3351-3370
-
[24]
[24] Morsali A, Masoomi M Y. Coord. Chem. Rev., 2012,256: 2921-2943
-
[25]
[25] Abhik B, Upendra S, Madhavi S, et al. Nano Energy, 2013, 2(6):1158-1163
-
[26]
[26] Xu X D, Cao R G, Cho J, et al. Nano Lett., 2012,12:4988-4991
-
[27]
[27] ZHANG Fang(张防), HAO Liang(郝亮), ZHANG Xiao-Gang (张校刚), et al. Chinese J. Inorg. Chem.(无机化学学报), 2010,26(5):827-831
-
[28]
[28] Zhang F, Hao L, Zhang X G. Mater. Chem. Phys., 2011,126: 853-858
-
[29]
[29] Arenas J F, Marcos J I. Spectrochim. Acta, Part A, 1980,36 (12):1075-1081
-
[30]
[30] Baca S G, Gherco O A, Gdaniec M, et al. Inorg. Chim. Acta, 2004,357(12):3419-3429
-
[31]
[31] Nakamoto K, Translated by HUANG De-Ru(黄德如), WANG Ren-Qing(汪仁庆). Infrared and Raman Spectra of Inorganic and Coordination Compounds. 3rd Ed.(无机和配位化合物 的红外和拉曼光谱.3版). Beijing: Chemical Industry Press, 1986.
-
[32]
[32] Banerjee A, Bhatnagar S, Ogale S, et al. Nano Energy, 2013, 2(5):890-896
-
[33]
[33] Aravindan V, Gnanaraj J, Liu H K, et al. Chem. Eur. J., 2011,17:14326-14346
-
[34]
[34] Park C M, Kim J H, Sohn H J, et al. Chem. Soc. Rev., 2010,39:3115-3141
-
[35]
[35] Geissler W, Schmidt M, Aurbach D, et al. Electrochem. Commun., 2003,5:946-951
-
[36]
[36] Wang Z, Luan D, Hu Y, et al. Energy Environ. Sci., 2012,5: 5252-5258
-
[37]
[37] Reddy M V, Yu T, Shen Z X, et al. Adv. Funct. Mater., 2007,17:2792-2796
-
[38]
[38] Wu X L, Guo Y G, Wan L J, et al. J. Phys. Chem. C, 2008, 112:16824-16829
-
[39]
[39] Wang B, Chen J S, Wu H B, et al. J. Chem. Soc., 2011,133: 17146-17148
-
[40]
[40] Chen J S, Zhu T, Yang X H, et al. J. Chem. Soc., 2010,132: 13162-13167
-
[41]
[41] Kim H S, Piao Y, Kang S H, et al. Electrochem. Commun., 2010,12:382-386
-
[42]
[42] Zaghib K, Goodenough J B, Mauger A, et al. J. Power Sources, 2009,194:1021-1023
-
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