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Citation: QI Dan-Dan, ZHANG Fang, JIANG Da-Guang, QIN De-Cai, ZHANG Xiao-Gang. Fe2O3 Nanoparticles Prepared by Solid-State Thermolysis of Fe-Based Coordination Polymer and Their Enhanced Lithium Storage Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1171-1176. doi: 10.11862/CJIC.2015.159 shu

Fe2O3 Nanoparticles Prepared by Solid-State Thermolysis of Fe-Based Coordination Polymer and Their Enhanced Lithium Storage Properties

  • 1.

    College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Jiangsu Key Laboratory of Materials and Technology for Energy Conversion, Nanjing 210016, China

  • Received Date: 20 January 2015
    Available Online: 7 March 2015

    Fund Project: 江苏省自然科学基金(No.BK2011740) (No.BK2011740)

  • α-Fe2O3 nanoparticles with uniform size were synthesized via a complex-precursor strategy. First, iron ion-based coordination polymer was synthesized via a solvothermal method by using p-benzene-dicarboxylic acid (p-H2bdc) as ligand. Second, α-Fe2O3 nanoparticles with uniform size were prepared via a solid state pyrolysis procedure. The synthesized coordination polymer and Fe2O3 product were characterized by XRD, FT-IR, SEM and TEM respectively. When used as anode material for lithium-ion batteries, the Fe2O3 electrode can deliever a stable reversible capacity of 530 mAh·g-1 after 50 charge-discharge cycles at a current density of 0.1 A·g-1, which showed a higher specific capacity and superior cycle stability.
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