Citation: ZHENG An-Hua, YANG Xue-Lin, XIA Dong-Dong, WU Xuan, WEN Zhao-Yin. Effect of Heat Treatment Temperature on Electrochemical Performance of Graphite Composite Anode for Lithium Ion Battery[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1159-1164. doi: 10.11862/CJIC.2015.158 shu

Effect of Heat Treatment Temperature on Electrochemical Performance of Graphite Composite Anode for Lithium Ion Battery

1.
1 College of Mechanical and Power Engineering, Three Gorges University, Yichang, Hubei 443002, China;
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2 College of Materials and Chemical Engineering, Three Gorges University, Collaborative Innovation Center for Microgrid of New Energy, Hubei Province, Yichang, Hubei 443002, China;
3.
3 Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

Corresponding author: YANG Xue-Lin,
Received Date: 10 March 2015
Available Online: 15 April 2015
Fund Project: 国家自然科学基金(No.51272128) (No.51272128)湖北省自然科学基金(No.2014CFB667)资助项目。 (No.2014CFB667)

The graphite composite (G/C) anode was prepared by spray drying and high temperature sintering using natural spherical graphite as raw material and citric acid as carbon source. X-ray diffraction (XRD), scanning electron microscope (SEM) and high-resolution transmission electron microscope (HRTEM) were used to characterize crystal structure and morphology of samples. Galvanostatic charge-discharge tests and cyclic voltammentry (CV) were utilized to study the effect of heat treatment temperature on electrochemical performance of G/C anode. With typical voltage feature of graphite anode, G/C-2900 sample shows higher capacity than commercial graphite anode. The charge capacity of the G/C-2900 after the first activation is 423 mAh·g^-1, and the 100th charge capacity is 416 mAh·g^-1 with capacity retention rate of 98%.
- citric acid;G/C;lithium-ion battery;anode materials
1. [1]
  [1] Rüdorff W, Hofmann U. Zeitschrift Für Anorganische und Allgemeine Chemie, 1938,238(1):1-50
2. [2]
  [2] van Schalkwijk W A, Scrosati B. Advances in Lithium-Ion Batteries. New York: Kluwer Academic/Plenum Publishers, 2002:85-103
3. [3]
  [3] Fujimoto H. J. Power Sources, 2010,195:5019-5024
4. [4]
  [4] Kida Y, Yanagida K, Funahashi A, et al. J. Power Sources, 2001,94(1):74-77
5. [5]
  [5] Wang H, Abe T, Maruyama S, et al. Adv. Mater., 2005,17: 2857-2860
6. [6]
  [6] Peled E, Menachem C, Bar-Tow D, et al. J. Electrochem. Soc., 1996,143(1):L4-L7
7. [7]
  [7] Wu Y P, Jiang C, Wan C, et al. J. Power Sources, 2002,111 (2):329-334
8. [8]
  [8] Wu Y P, Jiang C, Wan C, et al. Electrochem. Commun., 2000,2(4):272-275
9. [9]
  [9] Wu Y P, Holze R. J. Solid State Electrochem., 2003,8(1):73-78
10. [10]
  [10] Shim J, Striebel K A. J. Power Sources, 2007,164(2):862-867
11. [11]
  [11] Bhattacharya A, Hazra A, Chatterjee S, et al. J. Power Sources, 2004,136(2):208-210
12. [12]
  [12] Yang S, Song H, Chen X. Electrochem. Commun., 2006,8 (1):137-142
13. [13]
  [13] Zou L, Kang F, Zheng Y P, et al. Electrochim. Acta, 2009, 54(15):3930-3934
14. [14]
  [14] Lin Y, Huang Z H, Yu X, et al. Electrochim. Acta, 2014, 116:170-174
15. [15]
  [15] Yoshio M, Wang H, Fukuda K, et al. J. Electrochem. Soc., 2000,147(4):1245-1250
16. [16]
  [16] Wang H, Yoshio M. J. Power Sources, 2001,93(1):123-129
17. [17]
  [17] Wang H, Yoshio M, Abe T, et al. J. Electrochem. Soc., 2002,149(4):A499-A503
18. [18]
  [18] Ohzawa Y, Yamanaka Y, Naga K, et al. J. Power Sources, 2005,146(1):125-128
19. [19]
  [19] Zhang H L, Liu S H, Li F, et al. Carbon, 2006,44(11):2212 -2218
20. [20]
  [20] Natarajan C, Fujimoto H, Tokumitsu K, et al. Carbon, 2001,39(9):1409-1413
21. [21]
  [21] Lee H Y, Baek J K, Jang S W, et al. J. Power Sources, 2001,101(2):206-212
22. [22]
  [22] Tsumura T, Katanosaka A, Souma I, et al. Solid State Ionics, 2000,135(1):209-212
23. [23]
  [23] Nozaki H, Nagaoka K, Hoshi K, et al. J. Power Sources, 2009,194(1):486-493
24. [24]
  [24] Yoon S, Kim H, Oh S M. J. Power Sources, 2001,94(1):68-73
25. [25]
  [25] Lee J, Park M S, Park Y S, et al. ChemElectroChem, 2014,1 (10):1672-1678
26. [26]
  [26] Lian P, Zhu X, Liang S, et al. Electrochim. Acta, 2010,55 (12):3909-3914
27. [27]
  [27] Kudin K N, Ozbas B, Schniepp H C. et al. Nano Lett., 2008,8(1):36-41
28. [28]
  [28] Ferrari A C, Robertson J. Phys. Rev. B, 2000,61(20):14095 -14107
29. [29]
  [29] Pimenta M A, Dresselhaus G, Dresselhaus M S, et al. Phys. Chem. Chem. Phys., 2007,9(11):1276-1290
30. [30]
  [30] Zou L, Kang F Y, Li X L, et al. J. Phys. Chem. Solids, 2008,69(5):1265-1271
31. [31]
  [31] Yao J, Wang G X, Ahn J, et al. J. Power Sources, 2003,114 (2):292-297
32. [32]
  [32] Mabuchi A, Fujimoto H, Tokumitsu K, et al. J. Electrochem. Soc., 1995,142(9):3049-3051
33. [33]
  [33] Zhou H, Zhu S, Hibino M, et al. Adv. Mater., 2003,15(24): 2107-2111
34. [34]
  [34] Dahn J R. Phys. Rev. B, 1991,44(17):9170
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