Citation: ZHENG An-Hua, YANG Xue-Lin, XIA Dong-Dong, WU Xuan, WEN Zhao-Yin. Effect of Heat Treatment Temperature on Electrochemical Performance of Graphite Composite Anode for Lithium Ion Battery[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1159-1164. doi: 10.11862/CJIC.2015.158 shu

Effect of Heat Treatment Temperature on Electrochemical Performance of Graphite Composite Anode for Lithium Ion Battery

1.
1 College of Mechanical and Power Engineering, Three Gorges University, Yichang, Hubei 443002, China;
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2 College of Materials and Chemical Engineering, Three Gorges University, Collaborative Innovation Center for Microgrid of New Energy, Hubei Province, Yichang, Hubei 443002, China;
3.
3 Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

Corresponding author: YANG Xue-Lin,
Received Date: 10 March 2015
Available Online: 15 April 2015
Fund Project: 国家自然科学基金(No.51272128) (No.51272128)湖北省自然科学基金(No.2014CFB667)资助项目。 (No.2014CFB667)

The graphite composite (G/C) anode was prepared by spray drying and high temperature sintering using natural spherical graphite as raw material and citric acid as carbon source. X-ray diffraction (XRD), scanning electron microscope (SEM) and high-resolution transmission electron microscope (HRTEM) were used to characterize crystal structure and morphology of samples. Galvanostatic charge-discharge tests and cyclic voltammentry (CV) were utilized to study the effect of heat treatment temperature on electrochemical performance of G/C anode. With typical voltage feature of graphite anode, G/C-2900 sample shows higher capacity than commercial graphite anode. The charge capacity of the G/C-2900 after the first activation is 423 mAh·g^-1, and the 100th charge capacity is 416 mAh·g^-1 with capacity retention rate of 98%.
- citric acid;G/C;lithium-ion battery;anode materials
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