Citation: CUI Yang-Zhe, GENG Wen-Xiao, QIU Qi-Ming, GAO Sen, LIU Min, LI Zhong-Feng, JIN Qiong-Hua. Syntheses, Crystal Structures and Spectroscopic Properties of Two Silver(Ⅰ) Complexes with Heterocyclic Thione[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1224-1230. doi: 10.11862/CJIC.2015.156 shu

Syntheses, Crystal Structures and Spectroscopic Properties of Two Silver(Ⅰ) Complexes with Heterocyclic Thione

1.
1 Department of Chemistry, Capital Normal University, Beijing 100048, China;
2.
2 College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China

Corresponding author: JIN Qiong-Hua,
Received Date: 16 January 2015
Available Online: 27 March 2015
Fund Project: 国家自然科学基金(No.21171119) (No.21171119)863国家高技术研究发展计划(No.2012AA063201) (No.2012AA063201)北京教育委员会基金(No.KM201210028020) (No.KM201210028020)北京市优秀人才项目(No.2010D005016000002) (No.2010D005016000002)北京市自然科学基金(No.7122015)资助。 (No.7122015)

Two silver(Ⅰ) complexes with heterocyclic thione, [AgBr(PPh₃)₂(BTZT)]₂ (1) and [Ag₂Cl₂(PPh₃)₂(BTZT)₂]·CH₃OH (2) (PPh₃=triphenylphosphine; BTZT=benzothiazoline-2-thione) have been synthesized and characterized by IR, single-crystal X-ray diffraction, fluorescence spectrum and ¹H NMR spectroscopy. 1 and 2 are obtained by the reactions of AgX (X=Cl, Br) with PPh₃ in the presence of 2-mercaptobenzothiazole (MBT) in mixed solvent (CH₃OH/CH₂Cl₂). The MBTligand possesses chemically active groups (-N=C(-SH)), so MBTligand can transform into BTZTligand. Structure analysis shows that there exist two same molecular structures in complex 1, but they have different bond lengths and bond angles. Complex 2 consists of inversion symmetric dimers with a diamond-shaped Ag₂Cl₂ group at the center, and two adjacent [AgCl(PPh₃)(BTZT)] units are bridged by two Cl atoms.
- fluorescence;silver;triphenylphosphine;2-mercaptobenzothiazole;benzothiazoline-2-thione
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