Citation: XIAO Hui, SUN Li-Ping, ZHAO Hui, HUO Li-Hua, Jean-Marc Bassat, Aline Rougier, Sébastien Fourcade, Jean-Claude Grenier. Preparation and Electrochemical Properties of LaBiMn₂O₆ Cathode for IT-SOFCs[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1139-1144. doi: 10.11862/CJIC.2015.153 shu

Preparation and Electrochemical Properties of LaBiMn₂O₆ Cathode for IT-SOFCs

1.
1 Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China;
2.
2 CNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr. A. Schweitzer, F-33608 Pessac-Cedex, France

Received Date: 13 December 2014
Available Online: 23 March 2015
Fund Project: 国家自然科学基金(No.51302069,51372073) (No.51302069,51372073)高等学校博士学科点专项科研基金(No.20132301110002) (No.20132301110002)

LaBiMn₂O₆(LBM) cathode for IT-SOFCs (intermediate temperature solid oxide fuel cells) has been prepared by solid state reaction and studied by XRDand EISspectrum,respectively. The results show that LBM has no reaction with Ce_0.7Bi_0.3O_1.85(CBO) electrolyte at 1000 ℃ for 12 h. AC impedance spectroscopy and DC polarization measurements are used to study the electrode performances. The polarization resistance decreases with temperature and reaches 0.71 Ω·cm² at 700 ℃ in air. Oxygen partial pressure study indicated that charge transfer process is the major rate limiting step for LaBiMn₂O₆ cathode from 600 to 700 ℃. The LaBiMn₂O₆ cathode exhibits the lowest overpotential of 85 mVunder current density of 216 mA·cm^-2 at 700 ℃ in air. This preliminary work showes that LaBiMn₂O₆ material may be potential cathodes for IT-SOFCs.
- intermediate temperature solid oxide fuel cells (IT-SOFCs);cathode material;LaBiMn₂O₆;electrode reaction
1. [1]
  [1] Adler S B. Chem. Rev., 2004,104:4791-4843
2. [2]
  [2] Kim G, Wang S, Jacobson A J, et al. J. Mater. Chem., 2007, 17:2500-2505
3. [3]
  [3] Tarancón A, Skinner S J, Chater R J, et al. J. Mater. Chem., 2007,17:3175-3181
4. [4]
  [4] Yoo S, Shin J Y, Kim G. J. Mater. Chem., 2011,21:439-443
5. [5]
  [5] Burriel M, Peña-Martínez J, Chater R J, et al. J. Mater. Chem., 2012,24:613-621
6. [6]
  [6] Zhang K, Ge L, Ran R, et al. Acta Mater., 2008,56:4876 -4889
7. [7]
  [7] Jin M F, Zhang X L, Qiu Y E, et al. J. Alloys Compd., 2010,494:359-361
8. [8]
  [8] Kim J H, Manthiram A. J. Electrochem. Soc., 2008,155:385 -390
9. [9]
  [9] Zhou Q J, Wang F, Shen Y, et al. J. Power Sources, 2010, 195:2174-2181
10. [10]
  [10] Chen D J, Ran R, Zhang K, et al. J. Power Sources, 2009, 188:96-105
11. [11]
  [11] Albert Tarancón, Mónica Burriel, José Santiso, et al. J. Mater. Chem., 2010,20:3799-3813
12. [12]
  [12] Taskin A A, Lavrov A N, Yoichi Ando. Appl. Phys. Lett., 2005,86(9):091910-3
13. [13]
  [13] Liu Y. J. Alloys Compd., 2009,477:860-862
14. [14]
  [14] Zhang X T, Hao H S, He Q L. Physica B, 2007,394:118 -121
15. [15]
  [15] Xue J F, Shen Y, He T M. J. Power Sources, 2011,196: 3729-3735
16. [16]
  [16] Martin C, Maignan A, Pelloquin D. Appl. Phys. Lett., 1997, 71:1421-1423
17. [17]
  [17] Maignan A, Martin C, Pelloquin D, et al. J. Solid State Chem.,1999,142(2):247-260
18. [18]
  [18] Chen D, Wang F C, Shi H G. Electrochim. Acta, 2012,78: 466-474
19. [19]
  [19] Lu K, Shen F Y, Rose Roberts, et al. J. Power Sources, 2014,268:379-387
20. [20]
  [20] Sun L P, Huo L H, Zhao H. J. Power Sources, 2008,179:96 -100
21. [21]
  [21] Li Q, Sun L P, Zeng X. J. Power Sources, 2013,238:11-16
22. [22]
  [22] Wang Y X, Zhao X Y, Lü S Q. Ceram. Int., 2014,40:11343 -11350
23. [23]
  [23] Zhao H, Feng S H, Xu W. Mater. Res. Bull., 2000,35(15): 2379-2386
24. [24]
  [24] Asish K K, Pralong V, Caignaert V, et al. J. Mater. Chem., 2007,17:3347-3353
25. [25]
  [25] Daroukha M A, Vashooka V V, Ullmanna H, et al. Solid State Ionics, 2003,158:141-150
26. [26]
  [26] Nagde K R, Bhoga S S. Ionics, 2009,15:571-578
27. [27]
  [27] Jiang S P. J. Power Sources, 2003,124:390-402
28. [28]
  [28] Gao Z, Liu X M, Bergman B, et al. J. Power Sources, 2011,196:9195-9203
29. [29]
  [29] Kim J D, Kim G D, Moon J W, et al. Solid State Ionics, 2001,143:379-389
1. [1]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
2. [2]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . 氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化. Acta Physico-Chimica Sinica, 2025, 41(1): 2309037-. doi: 10.3866/PKU.WHXB202309037
3. [3]
  Ji-Quan Liu , Huilin Guo , Ying Yang , Xiaohui Guo . Calculation and Discussion of Electrode Potentials in Redox Reactions of Water. University Chemistry, 2024, 39(8): 351-358. doi: 10.3866/PKU.DXHX202401031
4. [4]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
5. [5]
  Tong Zhou , Jun Li , Zitian Wen , Yitian Chen , Hailing Li , Zhonghong Gao , Wenyun Wang , Fang Liu , Qing Feng , Zhen Li , Jinyi Yang , Min Liu , Wei Qi . Experiment Improvement of “Redox Reaction and Electrode Potential” Based on the New Medical Concept. University Chemistry, 2024, 39(8): 276-281. doi: 10.3866/PKU.DXHX202401005
6. [6]
  Ru SONG , Biao WANG , Chunling LU , Bingbing NIU , Dongchao QIU . Electrochemical properties of stable and highly active PrBa_0.5Sr_0.5Fe_1.6Ni_0.4O_5+δ cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 639-649. doi: 10.11862/CJIC.20240397
7. [7]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
8. [8]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
9. [9]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
10. [10]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
11. [11]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
12. [12]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
13. [13]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
14. [14]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
15. [15]
  Shiyi WANG , Chaolong CHEN , Xiangjian KONG , Lansun ZHENG , Lasheng LONG . Polynuclear lanthanide compound [Ce₄^ⅢCe₆^Ⅳ(μ₃-O)₄(μ₄-O)₄(acac)₁₄(CH₃O)₆]·2CH₃OH for the hydroboration of amides to amine. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 88-96. doi: 10.11862/CJIC.20240342
16. [16]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
17. [17]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
18. [18]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 100038-. doi: 10.3866/PKU.WHXB202408015
19. [19]
  Heng Zhang . Determination of All Rate Constants in the Enzyme Catalyzed Reactions Based on Michaelis-Menten Mechanism. University Chemistry, 2024, 39(4): 395-400. doi: 10.3866/PKU.DXHX202310047
20. [20]
  Bowen Yang , Rui Wang , Benjian Xin , Lili Liu , Zhiqiang Niu . C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100015-. doi: 10.3866/PKU.WHXB202310024

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(413)
HTML views(22)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Electrochemical Properties of LaBiMn2O6 Cathode for IT-SOFCs

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Electrochemical Properties of LaBiMn₂O₆ Cathode for IT-SOFCs