Citation: XIAO Hui, SUN Li-Ping, ZHAO Hui, HUO Li-Hua, Jean-Marc Bassat, Aline Rougier, Sébastien Fourcade, Jean-Claude Grenier. Preparation and Electrochemical Properties of LaBiMn₂O₆ Cathode for IT-SOFCs[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1139-1144. doi: 10.11862/CJIC.2015.153 shu

Preparation and Electrochemical Properties of LaBiMn₂O₆ Cathode for IT-SOFCs

1.
1 Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China;
2.
2 CNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr. A. Schweitzer, F-33608 Pessac-Cedex, France

Received Date: 13 December 2014
Available Online: 23 March 2015
Fund Project: 国家自然科学基金(No.51302069,51372073) (No.51302069,51372073)高等学校博士学科点专项科研基金(No.20132301110002) (No.20132301110002)

LaBiMn₂O₆(LBM) cathode for IT-SOFCs (intermediate temperature solid oxide fuel cells) has been prepared by solid state reaction and studied by XRDand EISspectrum,respectively. The results show that LBM has no reaction with Ce_0.7Bi_0.3O_1.85(CBO) electrolyte at 1000 ℃ for 12 h. AC impedance spectroscopy and DC polarization measurements are used to study the electrode performances. The polarization resistance decreases with temperature and reaches 0.71 Ω·cm² at 700 ℃ in air. Oxygen partial pressure study indicated that charge transfer process is the major rate limiting step for LaBiMn₂O₆ cathode from 600 to 700 ℃. The LaBiMn₂O₆ cathode exhibits the lowest overpotential of 85 mVunder current density of 216 mA·cm^-2 at 700 ℃ in air. This preliminary work showes that LaBiMn₂O₆ material may be potential cathodes for IT-SOFCs.
- intermediate temperature solid oxide fuel cells (IT-SOFCs);cathode material;LaBiMn₂O₆;electrode reaction
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Preparation and Electrochemical Properties of LaBiMn₂O₆ Cathode for IT-SOFCs