Citation: QIAN Yan-Tao, PENG Ye-Dong, ZHANG Wen-Wei. Syntheses, Structures and Properties of Metal-Organic Frameworks Based on Imidazolyl-Aromatic Multi-Carboxylate Acid Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, (5): 857-864. doi: 10.11862/CJIC.2015.148 shu

Syntheses, Structures and Properties of Metal-Organic Frameworks Based on Imidazolyl-Aromatic Multi-Carboxylate Acid Ligands

1.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Corresponding author: ZHANG Wen-Wei,
Received Date: 27 January 2015
Available Online: 27 March 2015
Fund Project: 国家自然科学基金(No.51173075)资助项目。 (No.51173075)

Three metal-organic frameworks, namely [PrL(HL)(H₂O)₂]·H₂O (1), Er(H_0.5L)₂ (2), and [CoL(H₂O)₂]·H₂O (3) (H₂L=5-(1H-imidazol-1-yl)isophthalic acid), have been synthesized under hydrothermal condition. Single crystal X-ray diffraction indicates that all the three complexes belong to the monoclinic space group P2₁/c. The Pr³⁺ ions in 1 are nine-coordinated, while the Er³⁺ ions in 2 and Co²⁺ ions in 3 are both six-coordinated. In the lanthanide complex 1 and 2, the nitrogen atom does not coordinate with any metal ions. Complex 1 shows a 2D folding framework, while complex 2 exhibits a 3D network. In the transition metal complex 3, the nitrogen atom coordinates with Co²⁺, which helps to form a flat 2D framework. Complex 1 and 3 are further packed into 3D framework by the intermolecular π-π interactions. All the three complexes display good thermal stability.
- metal-organic framework;transition metal;lanthanide;hydrothermal synthesis;crystal structure
1. [1]
  [1] (a)Zheng B S, Bai J F, Duan J G, et al. J. Am. Chem. Soc., 2011,133:748-751
2. [2]
  (b)Lu Z Z, Zhang R, Li Y Z, et al. J. Am. Chem. Soc., 2011, 133:4172-4174
3. [3]
  (c)Kim M, Cahill J F, Fei H H, et al. J. Am. Chem. Soc., 2012,134:18082-18088
4. [4]
  (d)Kumar R, Kumar S, Kulandainathan M. Microporous Mesoporous Mater., 2013,168:57-64
5. [5]
  (e)Mishra P, Edubilli S, Mandal B, et al. Microporous Mesoporous Mater., 2013,169:75-80
6. [6]
  [2] (a)Zhang J P, Huang X C, Chen X M. Chem. Soc. Rev., 2009,38:2385-2396
7. [7]
  (b)Hu Y X, Ma H B, Zheng B, et al. Inorg. Chem., 2012,51: 7066-7074
8. [8]
  (c)Chen M, Bai Z S, Liu Q, et al. CrystEngComm, 2012,14: 8642-8648
9. [9]
  [3] (a)Kawano M, Kawamichi T, Haneda T, et al. J. Am. Chem. Soc., 2007,129:15418-15419
10. [10]
  (b)Wang Y T, Fan H H, Wang H Z, et al. Inorg. Chem., 2005, 44:4148-4150
11. [11]
  (c)Carlucci L, Ciani G, Proserpio D, et al. New J. Chem., 2003,27:483-489
12. [12]
  (d)Shin D M, Lee I S, Cho D, et al. Inorg. Chem., 2003,42: 7722-7724
13. [13]
  [4] (a)Mahata P, Sundaresan A, Natarajan S. Chem. Commun., 2007:4471-4473
14. [14]
  (b)Zhang J J, Wojtas L, Larsen R, et al. J. Am. Chem. Soc., 2009,131:17040-17041
15. [15]
  (c)Wu S T, Long L S, Huang R B, et al. Cryst. Growth Des., 2007,7:1746-1752
16. [16]
  (d)Zhu X, Sun P P, Ding J G, et al. Cryst. Growth Des., 2012,12:3992-3997
17. [17]
  (e)Qin L, Hu J, Zhang M, et al. Cryst. Growth Des., 2013,13: 2111-2117
18. [18]
  [5] (a)Chen S S, Chen M, Takamizawa S, et al. Chem. Commun., 2011,47:4902-4904
19. [19]
  (b)Liu W, Yu J, Jiang J, et al. CrystEngComm, 2011,13:2764-2773
20. [20]
  (c)Zhang J, Cheng S, Wang X, et al. CrystEngComm, 2013, 15:6074-6082
21. [21]
  [6] (a)Li S L, Tan K, Lan Y Q, et al. Cryst. Growth Des., 2010, 10:1699-1705
22. [22]
  (b)Cui P, Ren L J, Chen Z, et al. Inorg. Chem., 2012,51: 2303-2310
23. [23]
  (c)Jiang H L, Tatsu Y, Lu Z H, et al. J. Am. Chem. Soc., 2010,132:5586-5587
24. [24]
  (d)Zhang Q A, Zhang J Y, Yu Q Y, et al. Cryst. Growth Des., 2010,10:4076-4084
25. [25]
  [7] (a)Eddaoudi M, Li H, Yaghi O M. J. Am. Chem. Soc., 2000, 122:1391-1397
26. [26]
  (b)Eddaoudi M, Kim J, Rosi N, et al. Science, 2002,295: 469-472
27. [27]
  (c)Chae H, Siberio-Pérez D, Kim J, et al. Nature, 2004,427: 523-527
28. [28]
  (d)Millward A, Yaghi O M. J. Am. Chem. Soc., 2005,127: 17998-17999
29. [29]
  [8] (a)Chen B, Ockwig N, Millward A, et al. Angew. Chem. Int. Ed., 2005,44:4745-4749
30. [30]
  (b)Zhang J P, Chen X M. J. Am. Chem. Soc., 2008,130: 6010-6017
31. [31]
  (c)Hu Y X, Xiang S C, Zhang W W, et al. Chem. Commun., 2009:7551-7553
32. [32]
  (d)Tian D, Pang Y, Zhou Y H, et al. CrystEngComm, 2011, 13:957-966
33. [33]
  (e)Wang L F, Kang L C, Zhang W W, et al. Dalton Trans., 2011,40:9490-9497
34. [34]
  [9] (a)Chen S S, Lü G C, Fan J, et al. Cryst. Growth Des., 2011, 11:1082-1090
35. [35]
  (b)Chen S S, Zhao Y, Fan J, et al. CrystEngComm, 2012,14: 3564-3576
36. [36]
  [10] Cui K H, Yao S Y, Li H Q, et al. CrystEngComm, 2011,13: 3432-3437
37. [37]
  [11] Software Packages SMART and SAINT, Siemens Analytical X-ray Instrument Inc., Madison: WI, 1996.
38. [38]
  [12] Sheldrick G M. SHELX-97, Program for the Refinement of Crystal Structure, University of Göttingen, Göttingen, Germany, 1997.
39. [39]
  [13] Carter K, Pope S, Cahill C. CrystEngComm, 2014,16:1873-1884
40. [40]
  [14] Zhou X Y, Guo Y L, Shi Z H, et al. Dalton Trans., 2012,41: 1765-1775
1. [1]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
2. [2]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
3. [3]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
4. [4]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
5. [5]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
6. [6]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
7. [7]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
8. [8]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
9. [9]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
10. [10]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
11. [11]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
12. [12]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
13. [13]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
14. [14]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
15. [15]
  Geyang Song , Dong Xue , Gang Li . Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides. University Chemistry, 2024, 39(2): 321-329. doi: 10.3866/PKU.DXHX202308030
16. [16]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
17. [17]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
18. [18]
  Aiai WANG , Lu ZHAO , Yunfeng BAI , Feng FENG . Research progress of bimetallic organic framework in tumor diagnosis and treatment. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1825-1839. doi: 10.11862/CJIC.20240225
19. [19]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
20. [20]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(334)
HTML views(63)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142