Citation: LI Ting, LI Xin, ZHOU Shang-Yong, TIAN Li. Copper(Ⅱ) Complexes Based on 5-Sulfoisophthalate and Bis(1,2,4-triazol-1-yl)alkanes: Syntheses, Structures, and Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1215-1223. doi: 10.11862/CJIC.2015.145 shu

Copper(Ⅱ) Complexes Based on 5-Sulfoisophthalate and Bis(1,2,4-triazol-1-yl)alkanes: Syntheses, Structures, and Properties

1.
Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education, College of Chemistry, Tianjin Normal University, Tianjin 300387, China

Received Date: 3 January 2015
Available Online: 14 March 2015
Fund Project: 国家自然科学基金(No.21371133) (No.21371133)天津市自然科学基金(No.12JCZDJC27600)资助项目。 (No.12JCZDJC27600)

The reaction of copper(Ⅱ) nitrate with flexible bis(1,2,4-triazol-1-yl)alkanes and rigid ligand 5-sulfoisophthalic acid monosodium salt (NaH₂sip) affords three complexes [Cu_0.5(btm)(H₂O)](H₂sip)·H₂O}_n (1, btm=bis(1,2,4-triazol-1-yl)methane), {[Cu(btp)₂(H₂sip)(H₂O)](NO₃)·4H₂O}_n (2, btp=1,3-bis(1,2,4-triazol-1-yl)propane), and {[Cu(btb)₂(Hsip)]_n (3, btb=1,4-bis(1,2,4-triazol-1-yl)butane). Compound 1 contains one-dimensional (1D) double-strained chains. Compound 2 contains two-dimensional (2D) rectangular networks with (4,4) topology, in which the 2D planar nanogrid networks stacked in a step stacking fashion.3 is also 2D layers, in which double-strained chains [Cu(btb)]_n are connected into 2D layer architectures by the μ₂-Hsip^2- linkers. The three compounds also are characterized by Elemental analysis, EPR, and thermal stability.
- bis(1,2,4-triazol-1-yl)methane;1,3-bis-(1,2,4-triazol-1-yl)propane;1,4-bis(1,2,4-triazol-1-yl)butane;5-sulfoisophthalic acid monosodium salt;supramolecular structure;hydrogen-bond interaction
1. [1]
  [1] Ishikava N, Sugita M, Ishikawa T, et al. J. Am. Chem. Soc., 2003,125:8694-8695
2. [2]
  [2] Zhang J P, Lin Y Y, Zhang W X, et al. J. Am. Chem Soc., 2005,127:14162-14163
3. [3]
  [3] Biradha K, Sarkar M, Rajput L. Chem. Commun., 2006,11: 4169-4179
4. [4]
  [4] Wu C D, Lin W B. Angew. Chem. Int. Ed., 2007,46:1075-1078
5. [5]
  [5] Wu S T, Wu Y R, Kang Q Q, et al. Angew. Chem. Int. Ed., 2007,46:8475-8479
6. [6]
  [6] Zhang J, Chen S M, Valle H, et al. J. Am. Chem. Soc., 2007, 129:14168-14169
7. [7]
  [7] Liu Y, Xu X, Zheng F K, et al. Angew. Chem. Int. Ed., 2008,47:4538-4541
8. [8]
  [8] Morris W, Doonan C J, Furukawa H, et al. J. Am. Chem. Soc., 2008,130:12626-12627
9. [9]
  [9] Ockwig N W, Delgado-Friedrichs O, OKeeffe M, et al. Acc. Chem. Res., 2005,38:176-182
10. [10]
  [10] Biradha K, Sarkar M, Rajput L. Chem. Commun., 2006,11: 4169-4179
11. [11]
  [11] Ye B H, Tong M L, Chen X M. Coord. Chem. Rev., 2005, 249:545-565
12. [12]
  [12] Hu S, Chen J C, Tong M L, et al. Angew. Chem. Int. Ed., 2005,44:5471-5475
13. [13]
  [13] Sun D F, Collins D J, Ke Y X, et al. Chem. Eur. J., 2006, 12:3768-3776
14. [14]
  [14] Huang Y G, Yuan D Q, Pan L, et al. Inorg. Chem., 2007,46: 9609-9615
15. [15]
  [15] Hesham A H, Joaquin S, Christoph J. Dalton Trans., 2008, 37:1734-1744
16. [16]
  [16] Habib H A, Hoffmann A, Hppe H A, et al. Dalton Trans., 2009,21:1742-1751
17. [17]
  [17] Tian A X, Ying J, Peng J, et al. Cryst. Growth Des., 2008,8: 3717-3724
18. [18]
  [18] Chen Z F, Zhang S F, Luo H S, et al. CrystEngComm, 2007, 9:27
19. [19]
  [19] Tian L, Zhang Z J, Yu A, et al. Cryst. Growth Des., 2010, 10:3847-3849
20. [20]
  [20] Ma L F, Han M L, Qin J H, et al. Inorg. Chem., 2012,51: 9431-9442
21. [21]
  [21] Ma L F, Zhao J W, Han M L, et al. Dalton Trans., 2012,41: 2078-2083
22. [22]
  [22] Sun D F, Cao R, Sun Y Q, et al. Inorg. Chem., 2003,42: 7512-7518
23. [23]
  [23] Li B, Zhu X, Zhou J, et al. Polyhedron, 2004,23:3133-3141
24. [24]
  [24] Wang X, Li B, Zhu X, et al. Eur. J. Inorg. Chem., 2005: 3277-3286
25. [25]
  [25] Wu C D, Lin W B. Angew. Chem. Int. Ed., 2005,44:1958-1961
26. [26]
  [26] Yi L, Yang X, Lu T B, et al. Cryst. Growth Des., 2005,5: 1215-1219
27. [27]
  [27] Zhu X, Ge H, Zhang Y, et al. Polyhedron, 2006,25:1875-1883
28. [28]
  [28] Torres J, Lavandera J L, Cabildo P, et al. J. Heterocycl. Chem., 1988,25:771-782
29. [29]
  [29] Sheldrick G M. SHELXS 97, Program for Crystal Structure Solution, University of Göttingen, Germany, 1997.
30. [30]
  [30] Sheldrick G M. SHELXL 97, Program for Crystal Structure Refinement, University of Göttingen, Germany, 1997.
31. [31]
  [31] Tian L, Niu Z, Yang N. Inorg. Chim. Acta, 2011,370:230-235
32. [32]
  [32] Tian L,Yang N, Zhao G Y. Inorg. Chem. Commun., 2010,13: 1497-1500
33. [33]
  [33] Tian L, Chen Z. Inorg. Chem. Commun., 2011,14:1302-1305
34. [34]
  [34] Tian L, Zhou S Y. J. Coord. Chem., 2013,66:2863-2874
1. [1]
  Huiying Xu , Minghui Liang , Zhi Zhou , Hui Gao , Wei Yi . Application of Quantum Chemistry Computation and Visual Analysis in Teaching of Weak Interactions. University Chemistry, 2025, 40(3): 199-205. doi: 10.12461/PKU.DXHX202407011
2. [2]
  Xue Wu , Yupeng Liu , Bingzhe Wang , Lingyun Li , Zhenjian Li , Qingcheng Wang , Quansheng Cheng , Guichuan Xing , Songnan Qu . Rationally assembling different surface functionalized carbon dots for enhanced near-infrared tumor photothermal therapy. Acta Physico-Chimica Sinica, 2025, 41(9): 100109-0. doi: 10.1016/j.actphy.2025.100109
3. [3]
  Tianlong Zhang , Rongling Zhang , Hongsheng Tang , Yan Li , Hua Li . Online Monitoring and Mechanistic Analysis of 3,5-diamino-1,2,4-triazole (DAT) Synthesis via Raman Spectroscopy: A Recommendation for a Comprehensive Instrumental Analysis Experiment. University Chemistry, 2024, 39(6): 303-311. doi: 10.3866/PKU.DXHX202312006
4. [4]
  Aidang Lu , Yunting Liu , Yanjun Jiang . Comprehensive Organic Chemistry Experiment: Synthesis and Characterization of Triazolopyrimidine Compounds. University Chemistry, 2024, 39(8): 241-246. doi: 10.3866/PKU.DXHX202401029
5. [5]
  Jin Yan , Chengxia Tong , Yajie Li , Yue Gu , Xuejian Qu , Shigang Wei , Wanchun Zhu , Yupeng Guo . Construction of a “Dual Support, Triple Integration” Chemical Safety Practical Education System. University Chemistry, 2024, 39(7): 69-75. doi: 10.12461/PKU.DXHX202405008
6. [6]
  Linghua Chen . 基于双联动“三学”模式的食品专业分析化学教学改革. University Chemistry, 2025, 40(8): 78-91. doi: 10.12461/PKU.DXHX202409095
7. [7]
  Yutong Liu , Xuemin Jing . Research Progress on the Catalytic Conversion of Methane in the Context of the “Dual Carbon” Goals. University Chemistry, 2025, 40(10): 101-113. doi: 10.12461/PKU.DXHX202412018
8. [8]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
9. [9]
  Jichao XU , Ming HU , Xichang CHEN , Chunhui WANG , Leichen WANG , Lingyi ZHOU , Xing HE , Xiamin CHENG , Su JING . Construction and hydrogen peroxide-activated chemodynamic activity of ferrocene?benzoselenadiazole conjugate. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1495-1504. doi: 10.11862/CJIC.20250144
10. [10]
  Yinuo Wang , Siran Wang , Yilong Zhao , Dazhen Xu . Selective Synthesis of Diarylmethyl Anilines and Triarylmethanes via Multicomponent Reactions: Introduce a Comprehensive Experiment of Organic Chemistry. University Chemistry, 2024, 39(8): 324-330. doi: 10.3866/PKU.DXHX202401063
11. [11]
  Shahua Huang , Xiaoming Guo , Lin Lin , Guangping Chang , Sheng Han , Zuxin Zhou . Application of “Integration of Industry and Education” in Engineering Chemistry: Improvement of the Pesticide Fipronil Production. University Chemistry, 2024, 39(3): 199-204. doi: 10.3866/PKU.DXHX202309064
12. [12]
  Shuhui Li , Rongxiuyuan Huang , Yingming Pan . Electrochemical Synthesis of 2,5-Diphenyl-1,3,4-Oxadiazole: A Recommended Comprehensive Organic Chemistry Experiment. University Chemistry, 2025, 40(5): 357-365. doi: 10.12461/PKU.DXHX202407028
13. [13]
  Zhiwen HUANG , Qi LIU , Jianping LANG . W/Cu/S cluster-based supramolecular macrocycles and their third-order nonlinear optical responses. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 79-87. doi: 10.11862/CJIC.20240184
14. [14]
  Lifang HE , Wenjie TANG , Yaoze LUO , Mingsheng LIANG , Jianxin TANG , Yuxuan WU , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two dialkyltin complexes constructed based on 2, 2′-bipyridin-6, 6′-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1601-1609. doi: 10.11862/CJIC.20250012
15. [15]
  Yuanyuan Ping , Wangqing Kong . 光催化碳氢键官能团化合成1-苯基-1,2-乙二醇. University Chemistry, 2025, 40(6): 238-247. doi: 10.12461/PKU.DXHX202408092
16. [16]
  Yinglian LI , Chengcheng ZHANG , Xinyu ZHANG , Xinyi WANG . Spin crossover in [Co(pytpy)₂]²⁺ complexes modified by organosulfonate anions. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1162-1172. doi: 10.11862/CJIC.20240087
17. [17]
  Yanfen PENG , Xinyue WANG , Tianbao LIU , Xiaoshuo WU , Yujing WEI . Syntheses and luminescence of four Cd(Ⅱ)/Zn(Ⅱ) complexes constructed by 1,3‐bis(4H‐1,2,4‐triazole)benzene. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1416-1426. doi: 10.11862/CJIC.20250018
18. [18]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
19. [19]
  Fengmiao Yu , Yang Sheng , Chanyue Li , Bao Li . The Three Lives of Aspirin. University Chemistry, 2024, 39(9): 115-121. doi: 10.12461/PKU.DXHX202402033
20. [20]
  Yujie WANG , Laobang WANG , Zheng ZHANG , Qi LIU , Jianping LANG . Construction of W/Cu/S cluster-based supramolecular compounds via alkynyl/sulfur cycloaddition and their third-order nonlinear optical properties. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2069-2077. doi: 10.11862/CJIC.20250129

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(524)
HTML views(41)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142