Citation: LI Ting, LI Xin, ZHOU Shang-Yong, TIAN Li. Copper(Ⅱ) Complexes Based on 5-Sulfoisophthalate and Bis(1,2,4-triazol-1-yl)alkanes: Syntheses, Structures, and Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1215-1223. doi: 10.11862/CJIC.2015.145 shu

Copper(Ⅱ) Complexes Based on 5-Sulfoisophthalate and Bis(1,2,4-triazol-1-yl)alkanes: Syntheses, Structures, and Properties

1.
Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education, College of Chemistry, Tianjin Normal University, Tianjin 300387, China

Received Date: 3 January 2015
Available Online: 14 March 2015
Fund Project: 国家自然科学基金(No.21371133) (No.21371133)天津市自然科学基金(No.12JCZDJC27600)资助项目。 (No.12JCZDJC27600)

The reaction of copper(Ⅱ) nitrate with flexible bis(1,2,4-triazol-1-yl)alkanes and rigid ligand 5-sulfoisophthalic acid monosodium salt (NaH₂sip) affords three complexes [Cu_0.5(btm)(H₂O)](H₂sip)·H₂O}_n (1, btm=bis(1,2,4-triazol-1-yl)methane), {[Cu(btp)₂(H₂sip)(H₂O)](NO₃)·4H₂O}_n (2, btp=1,3-bis(1,2,4-triazol-1-yl)propane), and {[Cu(btb)₂(Hsip)]_n (3, btb=1,4-bis(1,2,4-triazol-1-yl)butane). Compound 1 contains one-dimensional (1D) double-strained chains. Compound 2 contains two-dimensional (2D) rectangular networks with (4,4) topology, in which the 2D planar nanogrid networks stacked in a step stacking fashion.3 is also 2D layers, in which double-strained chains [Cu(btb)]_n are connected into 2D layer architectures by the μ₂-Hsip^2- linkers. The three compounds also are characterized by Elemental analysis, EPR, and thermal stability.
- bis(1,2,4-triazol-1-yl)methane;1,3-bis-(1,2,4-triazol-1-yl)propane;1,4-bis(1,2,4-triazol-1-yl)butane;5-sulfoisophthalic acid monosodium salt;supramolecular structure;hydrogen-bond interaction
1. [1]
  [1] Ishikava N, Sugita M, Ishikawa T, et al. J. Am. Chem. Soc., 2003,125:8694-8695
2. [2]
  [2] Zhang J P, Lin Y Y, Zhang W X, et al. J. Am. Chem Soc., 2005,127:14162-14163
3. [3]
  [3] Biradha K, Sarkar M, Rajput L. Chem. Commun., 2006,11: 4169-4179
4. [4]
  [4] Wu C D, Lin W B. Angew. Chem. Int. Ed., 2007,46:1075-1078
5. [5]
  [5] Wu S T, Wu Y R, Kang Q Q, et al. Angew. Chem. Int. Ed., 2007,46:8475-8479
6. [6]
  [6] Zhang J, Chen S M, Valle H, et al. J. Am. Chem. Soc., 2007, 129:14168-14169
7. [7]
  [7] Liu Y, Xu X, Zheng F K, et al. Angew. Chem. Int. Ed., 2008,47:4538-4541
8. [8]
  [8] Morris W, Doonan C J, Furukawa H, et al. J. Am. Chem. Soc., 2008,130:12626-12627
9. [9]
  [9] Ockwig N W, Delgado-Friedrichs O, OKeeffe M, et al. Acc. Chem. Res., 2005,38:176-182
10. [10]
  [10] Biradha K, Sarkar M, Rajput L. Chem. Commun., 2006,11: 4169-4179
11. [11]
  [11] Ye B H, Tong M L, Chen X M. Coord. Chem. Rev., 2005, 249:545-565
12. [12]
  [12] Hu S, Chen J C, Tong M L, et al. Angew. Chem. Int. Ed., 2005,44:5471-5475
13. [13]
  [13] Sun D F, Collins D J, Ke Y X, et al. Chem. Eur. J., 2006, 12:3768-3776
14. [14]
  [14] Huang Y G, Yuan D Q, Pan L, et al. Inorg. Chem., 2007,46: 9609-9615
15. [15]
  [15] Hesham A H, Joaquin S, Christoph J. Dalton Trans., 2008, 37:1734-1744
16. [16]
  [16] Habib H A, Hoffmann A, Hppe H A, et al. Dalton Trans., 2009,21:1742-1751
17. [17]
  [17] Tian A X, Ying J, Peng J, et al. Cryst. Growth Des., 2008,8: 3717-3724
18. [18]
  [18] Chen Z F, Zhang S F, Luo H S, et al. CrystEngComm, 2007, 9:27
19. [19]
  [19] Tian L, Zhang Z J, Yu A, et al. Cryst. Growth Des., 2010, 10:3847-3849
20. [20]
  [20] Ma L F, Han M L, Qin J H, et al. Inorg. Chem., 2012,51: 9431-9442
21. [21]
  [21] Ma L F, Zhao J W, Han M L, et al. Dalton Trans., 2012,41: 2078-2083
22. [22]
  [22] Sun D F, Cao R, Sun Y Q, et al. Inorg. Chem., 2003,42: 7512-7518
23. [23]
  [23] Li B, Zhu X, Zhou J, et al. Polyhedron, 2004,23:3133-3141
24. [24]
  [24] Wang X, Li B, Zhu X, et al. Eur. J. Inorg. Chem., 2005: 3277-3286
25. [25]
  [25] Wu C D, Lin W B. Angew. Chem. Int. Ed., 2005,44:1958-1961
26. [26]
  [26] Yi L, Yang X, Lu T B, et al. Cryst. Growth Des., 2005,5: 1215-1219
27. [27]
  [27] Zhu X, Ge H, Zhang Y, et al. Polyhedron, 2006,25:1875-1883
28. [28]
  [28] Torres J, Lavandera J L, Cabildo P, et al. J. Heterocycl. Chem., 1988,25:771-782
29. [29]
  [29] Sheldrick G M. SHELXS 97, Program for Crystal Structure Solution, University of Göttingen, Germany, 1997.
30. [30]
  [30] Sheldrick G M. SHELXL 97, Program for Crystal Structure Refinement, University of Göttingen, Germany, 1997.
31. [31]
  [31] Tian L, Niu Z, Yang N. Inorg. Chim. Acta, 2011,370:230-235
32. [32]
  [32] Tian L,Yang N, Zhao G Y. Inorg. Chem. Commun., 2010,13: 1497-1500
33. [33]
  [33] Tian L, Chen Z. Inorg. Chem. Commun., 2011,14:1302-1305
34. [34]
  [34] Tian L, Zhou S Y. J. Coord. Chem., 2013,66:2863-2874
1. [1]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
2. [2]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
3. [3]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
4. [4]
  Yinglian LI , Chengcheng ZHANG , Xinyu ZHANG , Xinyi WANG . Spin crossover in [Co(pytpy)₂]²⁺ complexes modified by organosulfonate anions. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1162-1172. doi: 10.11862/CJIC.20240087
5. [5]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
6. [6]
  Yujia LI , Tianyu WANG , Fuxue WANG , Chongchen WANG . Direct Z-scheme MIL-100(Fe)/BiOBr heterojunctions: Construction and photo-Fenton degradation for sulfamethoxazole. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 481-495. doi: 10.11862/CJIC.20230314
7. [7]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
8. [8]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
9. [9]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
10. [10]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
11. [11]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
12. [12]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
13. [13]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
14. [14]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
15. [15]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
16. [16]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
17. [17]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
18. [18]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
19. [19]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
20. [20]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(313)
HTML views(21)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142