Citation: ZHONG Di-Chang, LU Wen-Guan. Syntheses and Characterization of Two Three-Dimensional Layered-Pillared Inorganic-Organic Hybrid Materials Constructed from Inorganic Cadmium Sulfate Layers and in situ Generated Organic 5-(Pyridyl)tetrazolate Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1177-1184. doi: 10.11862/CJIC.2015.144 shu

Syntheses and Characterization of Two Three-Dimensional Layered-Pillared Inorganic-Organic Hybrid Materials Constructed from Inorganic Cadmium Sulfate Layers and in situ Generated Organic 5-(Pyridyl)tetrazolate Ligands

ZHONG Di-Chang ¹ ,
LU Wen-Guan ^2,,

1.
1 College of Chemistry and Chemical Engineering, Gannan Normal University, Ganzhou, Jiangxi 341000, China;
2.
2 Department of Chemistry, Shaoguan University, Shaoguan, Guangdong 512005, China

Corresponding author: LU Wen-Guan,
Received Date: 1 February 2014
Available Online: 18 March 2015
Fund Project: 国家自然科学基金资助项目(No.21071099,21363001) (No.21071099,21363001)广东省普通高校特色创新(自然科学类)项目(No.2014KTSCX169)。 (自然科学类)项目(No.2014KTSCX169)

Hydrothermal reactions of CdSO₄ and NaN₃ with 4-cyanopyridine or 3-cyanopyridine yielded two three-dimensional layered-pillared inorganic-organic hybrid materials based on mixed ligands of sulfate and in situ synthesized 5-(4-pyridyl)tetrazolate(4-ptz^-) or 5-(3-pyridyl)tetrazolate(3-ptz^-), respectively, namely, [Cd₂(H₂O)(OH)(SO₄)(4-ptz)]_n (1) and [Cd₂(OH)(SO₄)(3-ptz)]_n (2), which have been structurally characterized by elemental analysis (EA), infrared spectroscopy (IR), thermogravimetric analysis (TGA), single-crystal and powder X-ray diffraction. In 1 and 2, each Cd(Ⅱ) ion is six-coordinated with a distorted octahedral coordination geometry, which are connected through SO₄^2- and OH^-, leading to an infinite two-dimensional cation layer structure of [Cd₂(H₂O)(OH)(SO₄)]_nⁿ⁺(1) or [Cd₂(OH)(SO₄)]_nⁿ⁺(2). These adjacent two-dimensional cation layers are further linked by 4-ptz^- (1) or 3-ptz^- (2) pillared ligands to form infinite three-dimensional layered-pillared inorganic-organic hybrid frameworks architecture of 1 and 2, respectively. In addition, the results of photoluminescent measurements in the solid state at room temperature indicate that 1 and 2 all exhibit intense fluorescent emissions at λ_max=481 nm and 489 nm when excited at 350 nm, respectively.
- organic-inorganic hybrid materials;5-(pyridyl)tetrazole;mixed-ligand;crystal structure;fluorescence
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