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Citation: WANG Li-Zhen, XU Yong, FANG Hua, GAO Hai-Li. Effect of Glucose on the Performance of Li1.2Ni0.13Co0.13Mn0.54O2 Synthesized by Sol-Gel Method[J]. Chinese Journal of Inorganic Chemistry, ;2015, (5): 873-879. doi: 10.11862/CJIC.2015.140 shu

Effect of Glucose on the Performance of Li1.2Ni0.13Co0.13Mn0.54O2 Synthesized by Sol-Gel Method

  • 1.

    1 Zhengzhou Institute of Light Industry, Zhengzhou 450002, China;

  • 2.

    2 Key Lab of Surface and Interface Science, Zhengzhou 450002, China

  • Corresponding author: WANG Li-Zhen, 
  • Received Date: 25 December 2014
    Available Online: 5 March 2015

    Fund Project: 国家自然科学基金面上项目(No.21471135) (No.21471135)河南省基础与前沿技术研究重点项目(No.112300413216)资助。 (No.112300413216)

  • The cathode material Li1.2Ni0.13Co0.13Mn0.54O2 was synthesized by sol-gel method modified by glucose as carbon source. The structure, morphology and electrochemical performances of the as-prepared sample was studied by methods of XRD, SEM, EDS, BET, Laser Particle Size Analysis, cyclic voltammetry, galvanostatic charge-discharge and AC impedance. Test results showed that the distribution of particles became uniform and the sizes became smaller for the modification by glucose. The D50 decreased from 11.56 to 9.94 μm. The specific surface area nearly doubled. The initial discharge specific capacity at 0.2C reached 183.4 mAh·g-1 and 211.6 mAh·g-1 after been activated by 0.05C for blank and compared groups, respectively. The capacity at 2C retained 62.2% and 77.6% of that at 0.2C for the two samples, respectively. After 50 cycles at 1C, the discharge specific capacities retained 133.3 mAh·g-1 and 173.6 mAh·g-1, and the capacity retention rates were 95.1% and 100% for the two samples, respectively. The initial irreversible capacity loss was reduced for the modification by glucose. The rate performance and cycle stability were obviously improved. The impedance of charge transfer and Warburg, and dispersion effect of the electric double layer were decreased. The crystal structure of the sample stayed unchanged.
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    1. [1]

      [1] DU Ke(杜柯), HU Guo-Rong(胡国荣). Chin. Sci. Bull.(科学 通报), 2012,57(10):794-804

    2. [2]

      [2] LI Jie-Bing(李节宾), XU Yon-Long(徐友龙), DONG Xin(董 鑫), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28 (06):1125-1130

    3. [3]

      [3] WANG Sui-Jun(王绥军), ZHAO Yu-Juan(赵煜娟), ZHAO Chun-Song(赵春松), et al. Chem. J. Chinese Universities(高 等学校化学学报), 2009,30(12):2358-2362

    4. [4]

      [4] ZHAO Yu-Juan(赵煜娟), ZHAO Chun-Song(赵春松), SUN Zhao-Qing(孙召琴), et al. Acta Chim. Sinica(化学学报), 2011,69(2):117-121

    5. [5]

      [5] Kim J H, Park C, Sun Y K. Solid State Ionics, 2003,164(1): 43-49

    6. [6]

      [6] Lafond V, Mutin P H, Vioux A. Chem. Mater., 2004,16(25): 5380-5386

    7. [7]

      [7] JIA Ming-Jun(贾明君), LIU Gang(刘钢), ZHANG Min(张敏), et al. J. Nat. Sci. Heilongjiang Univ.(黑龙江大学自然科学 学报), 2008,25:759-764

    8. [8]

      [8] West W, Soler J, Ratnakumar B. J. Power Sources, 2012, 204:200-204

    9. [9]

      [9] Robert A A, Michael H, Petr N, et al. J. Am. Chem. Soc., 2006,128(26):8694-8698

    10. [10]

      [10] LIU Jing(刘景), WEN Zhao-Yin(温兆银), WU Mei-Mei(吴 梅梅), et al. J. Inorg. Mater.(无机材料学报), 2002,39(6): 1721

    11. [11]

      [11] ZHAO Yu-Juan(赵煜娟), FENG Hai-Lan(冯海兰), ZHAO Chun-Song(赵春松), et al. J. Inorg. Mater.(无机材料学报), 2011,26(7):673-679

    12. [12]

      [12] Kang S H, Kempgens P, Greenbaum S, et al. J. Mater. Chem., 2007,17(20):2069-2077

    13. [13]

      [13] Thackeray M M, Kang S H, Johnson C S, et al. Electrochem. Commun., 2006,8:1531-1538

    14. [14]

      [14] Yoon W S, Iannopollo S, Grey C P, et al. Electrochem. Solid-State Lett., 2004,7(7):A167-A171

    15. [15]

      [15] TANG Zhi-Yuan(唐致远), JIAO Yan-Feng(焦延峰), CHEN Yu-Hong(陈玉红), et al. J. Power Sources(电源技术), 2007, 31(10):786-789

    16. [16]

      [16] Yabuuchi N, Yoshii K, Myung S T, et al. J. Am. Chem. Soc., 2011,133(12):4404-4419

    17. [17]

      [17] Lu Z H, Beaulieu L Y, Donaberger R A, et al. J. Electrochem. Soc., 2002,149(7):A815-A822

    18. [18]

      [18] JIA Zheng(贾铮), DAI Chang-Song(戴长松), CHEN-Ling(陈 玲). Electrochemical Measurements(电化学测量方法). Beijing: Chemical Industry Press, 2006:166-168

    19. [19]

      [19] WU Xiao-Biao(吴晓彪), DONG Zhi-Xin(董志鑫), ZHENG Jian-Ming(郑建明), et al. J. Xiamen Univ.(厦门大学学报), 2009,47(A02):224-227

    20. [20]

      [20] CAO Chu-Nan(曹楚南), ZHANG Jian-Qing(张鉴清). An Introduction to Electrochemical Impedance Spectroscopy(电 化学阻抗谱导论). Beijing: Science Press, 2002:25-28

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